**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 99-91-2 |4'-Chloroacetophenone | 95 | 202-800-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 36/37/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. May cause
sensitization by skin contact.Lachrymator (substance which increases
the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May cause contact dermatitis.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause burns to the gastrointestinal tract.
Inhalation:
Causes respiratory tract irritation. May cause burns to the
respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
allergic skin reaction in some individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Contact with metals may evolve
flammable hydrogen gas. Containers may explode when heated.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation. Wash
clothing before reuse. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 99-91-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: none reported
pH: Not available.
Vapor Pressure: .51 mm Hg @ 25C
Viscosity: Not available.
Boiling Point: 232 deg C @ 760.00mmHg
Freezing/Melting Point: 20 deg C
Autoignition Temperature: Not available.
Flash Point: 90 deg C ( 194.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.1920g/cm3
Molecular Formula: C8H7ClO
Molecular Weight: 154.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, metals, excess heat,
oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 99-91-2: KM5600000
LD50/LC50:
CAS# 99-91-2: Inhalation, mouse: LC50 = 1752 mg/m3/15M; Oral, mouse:
LD50 = 1207 mg/kg.
Carcinogenicity:
4'-Chloroacetophenone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 99-91-2: No information available.
Canada
CAS# 99-91-2 is listed on Canada's DSL List.
CAS# 99-91-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 99-91-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/10/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Trimethyl phosphite
| 121-45-9 |
|
Lithium Hexafluorophosphate, 98%
| 7732-18-5 |
|
Methyl-1-benzyl-4-oxo-3-piperidine carboxylate hydrochloride, 97%
| 3939-01-3 |
|
4-Methyl-2-pyrazolin-5-one, 98%
| 13315-23-6 |
|
1-Bromo-3,4-difluorobenzene, 98%
| 348-61-8 |
|
17-alpha-Hydroxy-16 beta-methylpregnenolone
| 13900-61-3 |
|
4-Hydroxy-2-Mercapto-6-Methylpyrimidine, 98%
| 56-04-2 |
|
alpha-Bromo-2,3,4,5,6-pentafluorotoluene, 97%
| 1765-40-8 |
|
Phloroglucide, 95+%
| 491-45-2 |
|
3,4-Methylenedioxycinnamic Acid, 99%, Predominantly Trans
| 2373-80-0 |
|
3-(2-Methoxyphenyl)-Propionic Acid 98%
| 6342-77-4 |
|
Ethyl diphenylphosphinite, 99%
| 719-80-2 |
|
2,3-Dichlorophenoxyacetic Acid
| 2976-74-1 |
|
Antipyrine, 99%
| 60-80-0 |
|
1,3,5,7-Cyclooctatetraene, 98% stabilzed with 0.1% hydroquinon
| 629-20-9 |
|
2',4',6'-Trimethylacetophenone, 98%
| 1667-01-2 |
|
n-Butyl phenyl ether, 99%
| 1126-79-0 |
|
4-Bromo-3,5-Dimethylphenol, 99%
| 7463-51-6 |
|
tert-Butyl isocyanide, 97% (gc)
| 7188-38-7 |
|
2',5'-Dichloroacetoacetanilide, 98% (uv-vis)
| 2044-72-6 |
|
L-(-)-Glucose, 98%
| 921-60-8 |
|
1-Hydroxy-N-(2-tetradecyloxyphenyl)-2- naphthalenecarboxamide, 98%
| 39163-92-3 |
|
2,3,4,5,6 -Pentafluorobenzamide, 99%
| 652-31-3 |
|
2-Chloro-6-Fluorobenzyl Alcohol, 97%
| 56456-50-9 |
|
2,2-Dimethyl-5-Phenyl-1,3-Dioxane-4,6-Dione, 98%
| 15231-78-4 |
|
Dl-alpha-aminocaprylic acid, 99% (titr.)
| 644-90-6 |
|
2,2-Dimethylbutane, 98%
| 75-83-2 |
|
N,N-Dimethyl-5-Methoxytryptamine, 99%
| 1019-45-0 |
|
Isobutylbenzene, 99.5%
| 538-93-2 |
|
4'-Chloroacetophenone, 95% (GC)
| 99-91-2 |
|
1-Methylnaphthalene, 97%
| 90-12-0 |
|
Ethyl chloroformate
| 541-41-3 |
|
Remazol Brilliant Blue R
| 2580-78-1 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptane-Dionato)Ytterbium, 99+%
| 15492-52-1 |
|
Histamine, 96% (titr.)
| 51-45-6 |
|
Dl-valine, 99+%
| 516-06-3 |
|
2,3,6-Trichlorophenol, 99%
| 933-75-5 |
|
(2R)-(-)-Glycidyl Tosylate, 99+%
| 113826-06-5 |
|
6-Chloro-1-Hexanol, 90% (GC)
| 2009-83-8 |
|
2-Nitrophenylselenocyanate, 99%
| 51694-22-5 |
|
Alizarin Yellow GG
| 584-42-9 |
|
1,2-Dipiperidinoethane, 98%
| 1932-04-3 |
|
Succinaldehyde Disodium Bisulfite
| 5450-96-4 |
|
(+)-Griseofulvin, 97%
| 126-07-8 |
|
N-Allylrhodanine
| 1457-47-2 |
|
Acid Blue 92
| 3861-73-2 |
|
2,3,5-Trimethylpyrazine, 99%
| 14667-55-1 |
|
1,3-Cyclohexadiene, 99% (GC)
| 592-57-4 |
|
4-Chlorothiophenol, 98%
| 106-54-7 |
|
Trans-2-Aminomethyl-1-Cyclohexanol
| 5691-09-8 |
|
|