**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6046-93-1 |Copper (II) Acetate Monohydrate | >98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver damage. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic exposure may cause liver damage. Individuals with Wilson's
disease are unable to metabolize copper. Thus, copper accumulates in
various tissues and may result in liver, kidney, and brain damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 6046-93-1:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: (listed as copper): 1 mg/m3 TWA (dust)
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: dark green
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 464 deg F
Freezing/Melting Point: 239 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 464 F
Solubility in water: 7.2% in cold water.
Specific Gravity/Density: 1.88
Molecular Formula: Cu(C2H3O2)2.H2O
Molecular Weight: 199.599
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, oxides of copper.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6046-93-1: AG3500000
LD50/LC50:
CAS# 6046-93-1: Oral, rat: LD50 = 710 mg/kg.
Carcinogenicity:
Copper (II) Acetate Monohydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6046-93-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6046-93-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6046-93-1 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/12/1998 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Acetyl-4-methyl-2,5-dihydro-1h-pyrrol-2-one, 97%
| 34581-92-5 |
|
Ethyl 4-acetyl-3,5-dimethyl-1h-pyrrole-2-carboxylate, 97%
| 2386-26-7 |
|
N2,N2-Diethyl-3,4,5-trimethyl-1H-pyrrole-2-carboxamide, 97%
| 58803-92-2 |
|
2-Methyl-2-[(7-methyl-2,3-dihydro-1H-inden-4-yl)oxy]propanoic acid,
| 175136-07-9 |
|
Triphosphopyridine Nucleotide, Sodium Salt Hydrate
| 1184-16-3 |
|
5-Bromo-4-methoxy-7-methylindane, 97%
| 175136-09-1 |
|
4-Methoxy-7-methylindane-5-carbonitrile, 97%
| 175136-10-4 |
|
2-[(7-Methyl-2,3-dihydro-1H-inden-4-yl)oxy]pyridin-3-amine, 97%
| 175136-11-5 |
|
7-Methyl-2,3-dihydro-1h-inden-4-yl acetate, 97%
| 175136-12-6 |
|
2-Bromo-3-chloro-5-(trifluoromethyl)pyridine, 97%
| 75806-84-7 |
|
Methyl 4-amino-2-methoxybenzoate, 95+%
| 27492-84-8 |
|
2-(4-Chloro-2-methylphenoxy)-3-nitropyridine, 97%
| 465514-31-2 |
|
2-(4-Chloro-3,5-dimethylphenoxy)-3-nitropyridine, 97%
| 246862-63-5 |
|
2-(2,3-Dimethylphenoxy)-3-nitropyridine, 95+%
| 76893-55-5 |
|
6,8-Dibromo-2-oxo-2h-chromene-3-carboxylic acid, 95+
| 3855-87-6 |
|
3-(5-Bromo-2-methyl-4-nitro-1H-imidazol-1-yl)propanenitrile, 97%
| 139975-78-3 |
|
Methyl 2-phenoxynicotinate, 97%
| 36701-88-9 |
|
5-Bromo-2-methyl-4-nitro-1h-imidazole, 97%
| 18874-52-7 |
|
4-(2-Methyl-4-nitro-1h-imidazol-1-yl)butan-2-one, 97%
| 126664-28-6 |
|
4-tert-Butylcatechol, 99%
| 98-29-3 |
|
3-(2-Oxocyclododecyl)propanoic acid, 97%
| 22575-75-3 |
|
2-Heptylcyclopentan-1-one oxime, 97%
| 165385-93-3 |
|
Benzo-12-crown-4, 99+%
| 14174-08-4 |
|
1-(4-Decylphenyl)ethan-1-one, 97%
| 37593-06-9 |
|
1-Bromo-4-butoxybenzene, 97%
| 39969-57-8 |
|
4-Pentylbenzene-1-sulfonyl chloride, 97%
| 73948-18-2 |
|
2-Phenyl ethyl acetate, 98+%
| 103-45-7 |
|
Norharman, 98%
| 244-63-3 |
|
Sodium iodide dihydrate, 99+%
| 13517-06-1 |
|
4-(4-Octylphenyl)-4-oxobutanoic acid, 97%
| 64779-10-8 |
|
Cupferron
| 135-20-6 |
|
4-Oxo-4-(4-propylphenyl)butanoic acid, 97%
| 57821-78-0 |
|
4-(Dihexylamino)benzoic acid, 97%
| 134690-32-7 |
|
4-Propoxybenzonitrile, 97%
| 60758-84-1 |
|
1-(4-Bromophenyl)octane, 97%
| 51554-93-9 |
|
1-(4-Bromophenyl)heptane, 97%
| 76287-49-5 |
|
1-Bromo-4-pentylbenzene, 97%
| 51554-95-1 |
|
2-Bromo-1-[3,5-di(tert-butyl)-4-hydroxyphenyl]ethan-1-one, 90+%
| 14386-64-2 |
|
3,5-Di(tert-butyl)-4-hydroxybenzonitrile, 97%
| 1988-88-1 |
|
1-Eth-1-ynyl-4-(hexyloxy)benzene, 97%
| 79887-17-5 |
|
1,3,5-Triisopropylbenzene, 97%
| 717-74-8 |
|
1-Chloro-2,6-Dibromo-4-Fluorobenzene, 99.5+%
| 0-00-1 |
|
1-Eth-1-ynyl-4-(pentyloxy)benzene, 97%
| 79887-16-4 |
|
1-Butoxy-4-eth-1-ynylbenzene, 97%
| 79887-15-3 |
|
Copper (II) Acetate Monohydrate
| 6046-93-1 |
|
1-Eth-1-ynyl-4-propoxybenzene, 97%
| 39604-97-2 |
|
Copper (II) Bromide
| 7789-45-9 |
|
1-Eth-1-ynyl-4-methoxybenzene, 97%
| 768-60-5 |
|
1-Ethynyl-4-heptylbenzene, 95%
| 79887-12-0 |
|
Copper (II) Carbonate Basic Monohydrate
| 12069-69-1 |
|
|