**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7789-45-9 |Copper bromide | 100.0 | 232-167-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause blood abnormalities. Ingestion of large amounts
of copper salts may cause bloody stools and vomit, low blood
pressure, jaundice and coma.
Inhalation:
Dust is irritating to the respiratory tract. May cause severe
irritation of the upper respiratory tract with pain, burns, and
inflammation.
Chronic:
May cause liver and kidney damage. Chronic ingestion may cause
bromism characterized by disturbances of the central nervous system,
skin and digestive tract.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
The use of Calcium disodium EDTA as a chelating agent should be
determined by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Avoid breathing dust, vapor, mist, or gas.
Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7789-45-9:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: (listed as copper): 1 mg/m3 TWA (dust)
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: gray blue
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 900 deg C
Freezing/Melting Point: 498 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 4.7700
Molecular Formula: Br2Cu
Molecular Weight: 223.354
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, potassium, and alkali metals.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen bromide, copper fumes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7789-45-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Copper bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, NOS
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, NOS
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, NOS
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7789-45-9: No information available.
Canada
CAS# 7789-45-9 is listed on Canada's DSL List.
CAS# 7789-45-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7789-45-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/06/1998 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Acetyl-4-methyl-2,5-dihydro-1h-pyrrol-2-one, 97%
| 34581-92-5 |
|
Ethyl 4-acetyl-3,5-dimethyl-1h-pyrrole-2-carboxylate, 97%
| 2386-26-7 |
|
N2,N2-Diethyl-3,4,5-trimethyl-1H-pyrrole-2-carboxamide, 97%
| 58803-92-2 |
|
2-Methyl-2-[(7-methyl-2,3-dihydro-1H-inden-4-yl)oxy]propanoic acid,
| 175136-07-9 |
|
Triphosphopyridine Nucleotide, Sodium Salt Hydrate
| 1184-16-3 |
|
5-Bromo-4-methoxy-7-methylindane, 97%
| 175136-09-1 |
|
4-Methoxy-7-methylindane-5-carbonitrile, 97%
| 175136-10-4 |
|
2-[(7-Methyl-2,3-dihydro-1H-inden-4-yl)oxy]pyridin-3-amine, 97%
| 175136-11-5 |
|
7-Methyl-2,3-dihydro-1h-inden-4-yl acetate, 97%
| 175136-12-6 |
|
2-Bromo-3-chloro-5-(trifluoromethyl)pyridine, 97%
| 75806-84-7 |
|
Methyl 4-amino-2-methoxybenzoate, 95+%
| 27492-84-8 |
|
2-(4-Chloro-2-methylphenoxy)-3-nitropyridine, 97%
| 465514-31-2 |
|
2-(4-Chloro-3,5-dimethylphenoxy)-3-nitropyridine, 97%
| 246862-63-5 |
|
2-(2,3-Dimethylphenoxy)-3-nitropyridine, 95+%
| 76893-55-5 |
|
6,8-Dibromo-2-oxo-2h-chromene-3-carboxylic acid, 95+
| 3855-87-6 |
|
3-(5-Bromo-2-methyl-4-nitro-1H-imidazol-1-yl)propanenitrile, 97%
| 139975-78-3 |
|
Methyl 2-phenoxynicotinate, 97%
| 36701-88-9 |
|
5-Bromo-2-methyl-4-nitro-1h-imidazole, 97%
| 18874-52-7 |
|
4-(2-Methyl-4-nitro-1h-imidazol-1-yl)butan-2-one, 97%
| 126664-28-6 |
|
4-tert-Butylcatechol, 99%
| 98-29-3 |
|
3-(2-Oxocyclododecyl)propanoic acid, 97%
| 22575-75-3 |
|
2-Heptylcyclopentan-1-one oxime, 97%
| 165385-93-3 |
|
Benzo-12-crown-4, 99+%
| 14174-08-4 |
|
1-(4-Decylphenyl)ethan-1-one, 97%
| 37593-06-9 |
|
1-Bromo-4-butoxybenzene, 97%
| 39969-57-8 |
|
4-Pentylbenzene-1-sulfonyl chloride, 97%
| 73948-18-2 |
|
2-Phenyl ethyl acetate, 98+%
| 103-45-7 |
|
Norharman, 98%
| 244-63-3 |
|
Sodium iodide dihydrate, 99+%
| 13517-06-1 |
|
4-(4-Octylphenyl)-4-oxobutanoic acid, 97%
| 64779-10-8 |
|
Cupferron
| 135-20-6 |
|
4-Oxo-4-(4-propylphenyl)butanoic acid, 97%
| 57821-78-0 |
|
4-(Dihexylamino)benzoic acid, 97%
| 134690-32-7 |
|
4-Propoxybenzonitrile, 97%
| 60758-84-1 |
|
1-(4-Bromophenyl)octane, 97%
| 51554-93-9 |
|
1-(4-Bromophenyl)heptane, 97%
| 76287-49-5 |
|
1-Bromo-4-pentylbenzene, 97%
| 51554-95-1 |
|
2-Bromo-1-[3,5-di(tert-butyl)-4-hydroxyphenyl]ethan-1-one, 90+%
| 14386-64-2 |
|
3,5-Di(tert-butyl)-4-hydroxybenzonitrile, 97%
| 1988-88-1 |
|
1-Eth-1-ynyl-4-(hexyloxy)benzene, 97%
| 79887-17-5 |
|
1,3,5-Triisopropylbenzene, 97%
| 717-74-8 |
|
1-Chloro-2,6-Dibromo-4-Fluorobenzene, 99.5+%
| 0-00-1 |
|
1-Eth-1-ynyl-4-(pentyloxy)benzene, 97%
| 79887-16-4 |
|
1-Butoxy-4-eth-1-ynylbenzene, 97%
| 79887-15-3 |
|
Copper (II) Acetate Monohydrate
| 6046-93-1 |
|
1-Eth-1-ynyl-4-propoxybenzene, 97%
| 39604-97-2 |
|
Copper (II) Bromide
| 7789-45-9 |
|
1-Eth-1-ynyl-4-methoxybenzene, 97%
| 768-60-5 |
|
1-Ethynyl-4-heptylbenzene, 95%
| 79887-12-0 |
|
Copper (II) Carbonate Basic Monohydrate
| 12069-69-1 |
|
|