**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 620-42-8 |Tri-P-Tolyl Phosphite | 90% | 210-639-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract. May cause cardiac disturbances. May cause corrosion
and permanent tissue destruction of the esophagus and digestive
tract. May cause central nervous system effects. May cause systemic
effects.
Inhalation:
Causes chemical burns to the respiratory tract. May cause abdominal
pain, nausea, vomiting, and inflammation of the gums and mouth.
Aspiration may lead to pulmonary edema. May cause cardiac
abnormalities. May cause systemic effects. Inhalation at high
concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Wash mouth out with
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Combustible liquid. Can form explosive
mixtures at temperatures above the flashpoint. Use water spray to
keep fire-exposed containers cool. Combustible liquid. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Containers may explode when heated. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 620-42-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 238 deg C @ 7.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 93 deg C ( 199.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with acetone, alcohol, benzene,
Specific Gravity/Density: 1.1150g/cm3
Molecular Formula:
Molecular Weight: 352.36
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, oxides of phosphorus, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 620-42-8: TH1100000
LD50/LC50:
Not available.
Carcinogenicity:
Tri-P-Tolyl Phosphite -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 620-42-8: No information available.
Canada
CAS# 620-42-8 is listed on Canada's NDSL List.
CAS# 620-42-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 620-42-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tris-(2-Chloroethyl) Phosphate, 97%
| 115-96-8 |
|
6-Methylcoumarin, 99+%
| 92-48-8 |
|
Polystyrene: 1% Divinylbenzene Copolymer Beads, 200-400 Mesh
| 1321-74-0 |
|
Tri-P-Tolyl Phosphite, Tech., 90% (GC)
| 620-42-8 |
|
3-(3-(2-Bromoacetamido)propylcarbamoyl)- proxyl, free radical
| 100900-11-6 |
|
1,3-Dicyanobenzene 98%
| 626-17-5 |
|
Sulfabenzamide, 98.5%
| 127-71-9 |
|
2,4-Dinitro-N-Ethylaniline, 97%
| 3846-50-2 |
|
Citraconic Anhydride 98%
| 616-02-4 |
|
1-Chloro-2-Iodobenzene, 99%
| 615-41-8 |
|
Acid Alizarin Violet N
| 2092-55-9 |
|
8-Azaxanthine Monohydrate, 98%
| 1468-26-4 |
|
Sec-Butyl Acetate, 97% (gc)
| 105-46-4 |
|
AMINODIPHENYLMETHANE, TECH., 90%
| 91-00-9 |
|
D(+)-Tryptophan, 99+%
| 153-94-6 |
|
3-Fluorostyrene, 97%
| 350-51-6 |
|
4-Octyne, 99%
| 1942-45-6 |
|
Lawesson's Reagent, 99%
| 19172-47-5 |
|
Benzimidazo(1,2-c)quinazoline-6-thiol, 98%
| 24192-82-3 |
|
Piperylene, tech., 60%, cis and trans isomers
| 504-60-9 |
|
3,3'-Diaminodipropylamine, 99% (GC)
| 56-18-8 |
|
Chlorophenol Red, water soluble
| 123333-64-2 |
|
Cadmium carbonate, 99.999%
| 513-78-0 |
|
1,3-Dimethyl-5-Pyrazolone, 97%
| 2749-59-9 |
|
Aluminum sulfate hexadecahydrate, p.a.
| 10043-01-3 |
|
4,4'-bis(4-amino-1-naphthylazo)-2,2'- stilbenedisulfonic acid,
| 5463-64-9 |
|
5-Chloro-2-Hydroxyaniline, 97%
| 95-85-2 |
|
2-(2-Nitrophenyl)Malondialdehyde, 95+% (NMR)
| 53868-44-3 |
|
4-Methylbenzyl Cyanide, 98%
| 2947-61-7 |
|
2',5'-Dichloroacetophenone, 96%
| 2476-37-1 |
|
Iron atomic absorption standard solution, 1 mg/ml Fe in 2% HNO3
| 7439-89-6 |
|
Phenylselenol, 98% (gc)
| 645-96-5 |
|
8-Hydroxyquinoline sulfate monohydrate, 98%
| 207386-91-2 |
|
6-Amino-3,4-Methylenedioxyacetophenone 99+% (GC)
| 28657-75-2 |
|
2-Mercapto-1-methylimidazole, 98%
| 60-56-0 |
|
1,2-(Methylenedioxy)-4-Nitrobenzene, 98%
| 2620-44-2 |
|
beta-Butyrolactone, 98+%
| 3068-88-0 |
|
Aluminum acetylacetonate, 97+%
| 13963-57-0 |
|
3-Amino-4-chlorobenzoic acid, 98%
| 2840-28-0 |
|
4-Amino-2-chlorobenzoic acid, 97%
| 2457-76-3 |
|
Calcium hypochlorite tetrahydrate, reagent (crystals), 98% (titr.)
| 13477-32-2 |
|
2-Nitro-1-Naphthol,98%
| 607-24-9 |
|
DL-Leucine, 98% (Titr.)
| 328-39-2 |
|
n-Acetyl-l-alanyl-l-alanyl-l-alanine
| 19245-85-3 |
|
Xylitol, 99+%(gc)
| 87-99-0 |
|
Coumarin 102, Laser Grade, 99% (UV-VIS)
| 41267-76-9 |
|
Dexamethasone, 96%
| 50-02-2 |
|
2,2-Dichlorohexanoic acid, 93%
| 18240-70-5 |
|
2,2-Diethoxyacetonitrile, 98%
| 6136-93-2 |
|
3,4,5-Triethoxybenzoic Acid, 97+%
| 6970-19-0 |
|
|