**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 645-96-5 |Phenylselenol | 98.0 | 211-457-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with
plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustible liquid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 645-96-5:
United Kingdom, WEL - TWA: (listed as selenium compounds): 0.1 mg
TWA (except hydrogen selenide, as Se)
United Kingdom, WEL - STEL: (listed as selenium compounds): 0.3 m
STEL (except hydrogen selenide, as Se)
United States OSHA: 0.2 mg/m3 TWA (as Se) (listed under Selenium
compounds).
Belgium - TWA: (listed as selenium compounds): 0.2 mg/m3 VLE (as
Japan: (listed as selenium compounds): 0.1 mg/m3 OEL (except SeH2
SeF6, as Se)
Malaysia: (listed as selenium compounds): 0.2 mg/m3 TWA (as Se)
Netherlands: (listed as selenium compounds): 0.1 mg/m3 MAC (as Se
Spain: (listed as selenium compounds): 0.1 mg/m3 VLA-ED (except
hydrogen selenide, as Se)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 183.6 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 70 deg C ( 158.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4865
Molecular Formula: C6H6Se
Molecular Weight: 157.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, selenium/selenium oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 645-96-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Phenylselenol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 645-96-5: No information available.
Canada
CAS# 645-96-5 is listed on Canada's NDSL List.
CAS# 645-96-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 645-96-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tris-(2-Chloroethyl) Phosphate, 97%
| 115-96-8 |
|
6-Methylcoumarin, 99+%
| 92-48-8 |
|
Polystyrene: 1% Divinylbenzene Copolymer Beads, 200-400 Mesh
| 1321-74-0 |
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Tri-P-Tolyl Phosphite, Tech., 90% (GC)
| 620-42-8 |
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3-(3-(2-Bromoacetamido)propylcarbamoyl)- proxyl, free radical
| 100900-11-6 |
|
1,3-Dicyanobenzene 98%
| 626-17-5 |
|
Sulfabenzamide, 98.5%
| 127-71-9 |
|
2,4-Dinitro-N-Ethylaniline, 97%
| 3846-50-2 |
|
Citraconic Anhydride 98%
| 616-02-4 |
|
1-Chloro-2-Iodobenzene, 99%
| 615-41-8 |
|
Acid Alizarin Violet N
| 2092-55-9 |
|
8-Azaxanthine Monohydrate, 98%
| 1468-26-4 |
|
Sec-Butyl Acetate, 97% (gc)
| 105-46-4 |
|
AMINODIPHENYLMETHANE, TECH., 90%
| 91-00-9 |
|
D(+)-Tryptophan, 99+%
| 153-94-6 |
|
3-Fluorostyrene, 97%
| 350-51-6 |
|
4-Octyne, 99%
| 1942-45-6 |
|
Lawesson's Reagent, 99%
| 19172-47-5 |
|
Benzimidazo(1,2-c)quinazoline-6-thiol, 98%
| 24192-82-3 |
|
Piperylene, tech., 60%, cis and trans isomers
| 504-60-9 |
|
3,3'-Diaminodipropylamine, 99% (GC)
| 56-18-8 |
|
Chlorophenol Red, water soluble
| 123333-64-2 |
|
Cadmium carbonate, 99.999%
| 513-78-0 |
|
1,3-Dimethyl-5-Pyrazolone, 97%
| 2749-59-9 |
|
Aluminum sulfate hexadecahydrate, p.a.
| 10043-01-3 |
|
4,4'-bis(4-amino-1-naphthylazo)-2,2'- stilbenedisulfonic acid,
| 5463-64-9 |
|
5-Chloro-2-Hydroxyaniline, 97%
| 95-85-2 |
|
2-(2-Nitrophenyl)Malondialdehyde, 95+% (NMR)
| 53868-44-3 |
|
4-Methylbenzyl Cyanide, 98%
| 2947-61-7 |
|
2',5'-Dichloroacetophenone, 96%
| 2476-37-1 |
|
Iron atomic absorption standard solution, 1 mg/ml Fe in 2% HNO3
| 7439-89-6 |
|
Phenylselenol, 98% (gc)
| 645-96-5 |
|
8-Hydroxyquinoline sulfate monohydrate, 98%
| 207386-91-2 |
|
6-Amino-3,4-Methylenedioxyacetophenone 99+% (GC)
| 28657-75-2 |
|
2-Mercapto-1-methylimidazole, 98%
| 60-56-0 |
|
1,2-(Methylenedioxy)-4-Nitrobenzene, 98%
| 2620-44-2 |
|
beta-Butyrolactone, 98+%
| 3068-88-0 |
|
Aluminum acetylacetonate, 97+%
| 13963-57-0 |
|
3-Amino-4-chlorobenzoic acid, 98%
| 2840-28-0 |
|
4-Amino-2-chlorobenzoic acid, 97%
| 2457-76-3 |
|
Calcium hypochlorite tetrahydrate, reagent (crystals), 98% (titr.)
| 13477-32-2 |
|
2-Nitro-1-Naphthol,98%
| 607-24-9 |
|
DL-Leucine, 98% (Titr.)
| 328-39-2 |
|
n-Acetyl-l-alanyl-l-alanyl-l-alanine
| 19245-85-3 |
|
Xylitol, 99+%(gc)
| 87-99-0 |
|
Coumarin 102, Laser Grade, 99% (UV-VIS)
| 41267-76-9 |
|
Dexamethasone, 96%
| 50-02-2 |
|
2,2-Dichlorohexanoic acid, 93%
| 18240-70-5 |
|
2,2-Diethoxyacetonitrile, 98%
| 6136-93-2 |
|
3,4,5-Triethoxybenzoic Acid, 97+%
| 6970-19-0 |
|
|