**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 628-20-6 |4-Chlorobutyronitrile | | 211-031-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. Poison by ingestion.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Combustible
liquid.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 628-20-6:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless to pale yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 195 - 197 deg C @ 760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 85 deg C ( 185.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: immiscible with water
Specific Gravity/Density: 1.15
Molecular Formula: C4H6ClN
Molecular Weight: 103.5017
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, strong
bases.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 628-20-6: ET9020000
LD50/LC50:
CAS# 628-20-6: Oral, mouse: LD50 = 53380 ug/kg.
Carcinogenicity:
4-Chlorobutyronitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRILES LIQUID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES LIQUID, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 628-20-6: No information available.
Canada
CAS# 628-20-6 is listed on Canada's NDSL List.
CAS# 628-20-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 628-20-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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2,4-Decadien-1-ol, Tech., 90%
| 14507-02-9 |
|
4,4'-Dimethoxy-2,2'-bipyridine, 97%
| 17217-57-1 |
|
Benzyl 4-Hydroxybenzoate, 98%
| 94-18-8 |
|
m-Tolyl isocyanate, 99%
| 621-29-4 |
|
Histamine dihydrochloride, 98.5 - 101.0% ( on the dried substance)
| 56-92-8 |
|
Xanthosine dihydrate, 99%
| 5968-90-1 |
|
1-Butyl-3-Methylimidazolium Tetrafluoroborate
| 174501-65-6 |
|
1-Hexyl-3-methylimidazolium tetrafluoroborate
| 244193-50-8 |
|
1-Butylpyridinium tetrafluoroborate
| 203389-28-0 |
|
1-Hexylpyridinium tetrafluoroborate
| 474368-70-2 |
|
Methyl isovalerate, 98%
| 556-24-1 |
|
1-Bromo-2-fluoro-4-iodobenzene, 98+% (gc)
| 136434-77-0 |
|
2-Butoxyethanol or ethylene glycol monobutyl ether
| 111-76-2 |
|
Diacetone acrylamide, 99%
| 2873-97-4 |
|
N-(n-Butyl)phthalimide
| 1515-72-6 |
|
Poly(isobutylene), approximate MW 2800
| 9003-27-4 |
|
Poly(isobutylene), approximate MW 85000
| 9003-27-4 |
|
Poly(isobutylene), approximate MW 1,700,000
| 9003-27-4 |
|
Brucine sulfate hydrate, p.a.
| 38741-38-7 |
|
2,3,5,6-Tetrafluoro-p-toluic acid, 98%
| 652-32-4 |
|
2,3,5,6-Tetrafluoro-4-methylbenzyl alcohol
| 79538-03-7 |
|
Methyl nitroacetate, 98%
| 2483-57-0 |
|
Grubb's second generation catalyst, 97%
| 246047-72-3 |
|
1,3-Bis(2,4,6-Trimethylphenyl)-4,5-Dihydroimidazolium Chloride, 95%
| 141556-45-8 |
|
1,3-Bis(2,4,6-Trimethylphenyl)-4,5-Dihydroimidazolium
| 245679-18-9 |
|
2-(Di-tert-butylphosphino)biphenyl, 99%
| 224311-51-7 |
|
2-(Dicyclohexylphosphino)biphenyl, 98%
| 247940-06-3 |
|
2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl, 97%
| 213697-53-1 |
|
3,4-Dimethoxytoluene, 98%
| 494-99-5 |
|
Dimethylol urea
| 140-95-4 |
|
1,2,4,5-Tetrabromobenzene, 97%
| 636-28-2 |
|
2-Acetyl-5-methylfuran, 98%
| 1193-79-9 |
|
4-n-Hexyloxybenzoic acid, 99%
| 1142-39-8 |
|
2-Methyl-2-Pentenoic Acid, 99%
| 3142-72-1 |
|
cis-4-Hepten-1-ol, 97%
| 6191-71-5 |
|
3,5-Dibromobenzoic Acid
| 618-58-6 |
|
8-Ethoxyquinoline-5-sulfonic acid
| 15301-40-3 |
|
6-Fluoro-2-methylquinoline
| 1128-61-6 |
|
2-(Cyanomethyl)benzimidazole, 99%
| 4414-88-4 |
|
(S)-(-)-2,2'-Diamino-1,1-Binaphthalene
| 18531-95-8 |
|
(R)-(+)-2,2'-Diamino-1,1-binaphthalene, 99%
| 18741-85-0 |
|
Tris(4-bromophenyl)aminium hexachloroantimonate, 95%
| 24964-91-8 |
|
4-Chloro-1-butanol, 85%, balance THF and HCl
| 928-51-8 |
|
2-Phenylimidazole, 95%
| 670-96-2 |
|
Calcium silicide, 99+%
| 12013-56-8 |
|
2-(4-Chloro-2-Nitrophenyl)malondialdehyde, 95+% (NMR)
| 0-00-1 |
|
Fast Blue B fluoroborate
| 3410-35-3 |
|
4-Chlorobutyronitrile, 90% Chloro-deriv., bal. bromo-deriv. +
| 628-20-6 |
|
1-Acetyl-5-Nitroindoline
| 33632-27-8 |
|
Xanthine, 98%
| 69-89-6 |
|
|