**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-43-6 |Pentacarboxymethyl diethylenetriamine | 40 % | 200-652-8 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 60 % | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin.Cancer suspect agent.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney failure. The toxicological properties of
this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. May cause effects similar to
those described for ingestion. The toxicological properties of this
substance have not been fully investigated.
Chronic:
May cause kidney injury. May cause cancer according to animal
studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Avoid contact with skin and eyes. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 67-43-6:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Miscible with water.
Specific Gravity/Density: 1.3
Molecular Formula: Mixture
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidants.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-43-6: MB8205000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Pentacarboxymethyl diethylenetriamine -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 67-43-6: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 67-43-6 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 67-43-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-43-6 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 12/12/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl alpha-chlorophenylacetate, 99%
| |
|
1,2-Dihydroxybenzene-3,5-disulfonic acid disodium salt
| 149-45-1 |
|
1,2-Dihydroxyethylene-Bisacrylamide
| 868-63-3 |
|
Di-(2-hydroxyphenylimino)-ethane
| 1149-16-2 |
|
3,4-Dihydro-2H-Pyran
| 110-87-2 |
|
Dimedone
| 126-81-8 |
|
2,3-Dimercapto propan-1-ol
| 59-52-9 |
|
9,10-Dimethoxyanthracene sulfonic acid sodium salt
| 67580-39-6 |
|
Diethylenetriaminepenta-acetic acid, sodium salt solution
| 67-43-6 |
|
2,7-Dihydroxynaphthalene, 97%
| 582-17-2 |
|
Dimethyl Acetylenedicarboxylate
| 762-42-5 |
|
Dimethylamine Solution (40 % in Water)
| 124-40-3 |
|
Dimethylamine borane
| 74-94-2 |
|
n-Methyloctadecylamine, 96% (titr.)
| 2439-55-6 |
|
4-Dimethylamino-Benzylidenerhodanine
| 536-17-4 |
|
4-Bromophenyl Isocyanate (Pract)
| 2493-02-9 |
|
3-Dimethylaminopropionitrile
| 1738-25-6 |
|
Dimethylammonium Chloride
| 506-59-2 |
|
Dimethyldichlorosilane
| 75-78-5 |
|
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline disulfonic acid,
| 52698-84-7 |
|
N,N-Dimethylformamide di-n-butyl acetal
| 18503-90-7 |
|
N,N-Dimethylformamide dimethyl acetal
| 4637-24-5 |
|
15-Crown-5, 98%
| 33100-27-5 |
|
1,3-Dimethyl-2-imidazolidinone
| 80-73-9 |
|
2,9-Dimethyl-1,10-phenanthroline
| 484-11-7 |
|
NN-Dimethyl-p-phenylenediamine sulfate
| 536-47-0 |
|
1,4-Di(2-methylstyryl)benzene
| 13280-61-0 |
|
3,5-Dinitrobenzoic acid
| 99-34-3 |
|
2,4-Dinitro-1-Fluorobenzene
| 70-34-8 |
|
Ni-(S)-BPB-GLy, 99%
| 96293-19-5 |
|
2,4-Dinitrophenol, damped with 15-20% water
| 51-28-5 |
|
2,4-Dinitrophenylhydrazine damped with 33% water
| 119-26-6 |
|
Di-iso-octyl phthalate
| 27554-26-3 |
|
Dimidium bromide-disulfine blue indicator
| 97-77-8 |
|
NA-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide
| 95713-52-3 |
|
Dimethylglyoxime Sodium Salt, octahydrate
| 75006-64-3 |
|
Chloropentafluorobenzene, 99%
| 344-07-0 |
|
Diphenyl ether
| 101-84-8 |
|
4,7-Diphenyl-1,10-Phenanthroline
| 1662-01-7 |
|
Di-iso-propyl naphthalene
| 38640-62-9 |
|
5,5'-Dithiobis(2-Nitrobenzoic Acid)
| 69-78-3 |
|
Dithio-oxamide
| 79-40-3 |
|
1-Dodecane sulfonic acid sodium salt
| 2386-53-0 |
|
Dodecan-1-ol
| 112-53-8 |
|
Dodecyl trimethyl ammonium bromide
| 1119-94-4 |
|
Dowfax 9N9
| 9016-45-9 |
|
Dulcitol
| 608-66-2 |
|
Eriochrome Blue-Black B
| 3564-14-5 |
|
Eriochrome Blue-Black R
| 2538-85-4 |
|
Eriochrome cyanine R
| 3564-18-9 |
|
|