**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 96293-19-5 |Ni-(S)-BPB-GLy | 99 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 96293-19-5:
United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol
compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL
(as Ni)
Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA
(inhalable fraction, as Ni)
Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC
Ni)
Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: bordeux
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 219.00 - 222.00 deg C
Autoignition Temperature: > 250 deg C (> 482.00 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >250 deg C
Solubility in water: insoluble
Specific Gravity/Density: Not available.
Molecular Formula: C27H25N3NiO3
Molecular Weight: 498.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 96293-19-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ni-(S)-BPB-GLy -
California: carcinogen, initial date 5/7/04 (listed as Nickel compound
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 96293-19-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 96293-19-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96293-19-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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1,2-Dihydroxybenzene-3,5-disulfonic acid disodium salt
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1,2-Dihydroxyethylene-Bisacrylamide
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3,4-Dihydro-2H-Pyran
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Dimedone
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2,3-Dimercapto propan-1-ol
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9,10-Dimethoxyanthracene sulfonic acid sodium salt
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2,7-Dihydroxynaphthalene, 97%
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Dimethylamine Solution (40 % in Water)
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Dimethylamine borane
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| 1738-25-6 |
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|
Dimethyldichlorosilane
| 75-78-5 |
|
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline disulfonic acid,
| 52698-84-7 |
|
N,N-Dimethylformamide di-n-butyl acetal
| 18503-90-7 |
|
N,N-Dimethylformamide dimethyl acetal
| 4637-24-5 |
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15-Crown-5, 98%
| 33100-27-5 |
|
1,3-Dimethyl-2-imidazolidinone
| 80-73-9 |
|
2,9-Dimethyl-1,10-phenanthroline
| 484-11-7 |
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| 536-47-0 |
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| 13280-61-0 |
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3,5-Dinitrobenzoic acid
| 99-34-3 |
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2,4-Dinitro-1-Fluorobenzene
| 70-34-8 |
|
Ni-(S)-BPB-GLy, 99%
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|
2,4-Dinitrophenol, damped with 15-20% water
| 51-28-5 |
|
2,4-Dinitrophenylhydrazine damped with 33% water
| 119-26-6 |
|
Di-iso-octyl phthalate
| 27554-26-3 |
|
Dimidium bromide-disulfine blue indicator
| 97-77-8 |
|
NA-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide
| 95713-52-3 |
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Dimethylglyoxime Sodium Salt, octahydrate
| 75006-64-3 |
|
Chloropentafluorobenzene, 99%
| 344-07-0 |
|
Diphenyl ether
| 101-84-8 |
|
4,7-Diphenyl-1,10-Phenanthroline
| 1662-01-7 |
|
Di-iso-propyl naphthalene
| 38640-62-9 |
|
5,5'-Dithiobis(2-Nitrobenzoic Acid)
| 69-78-3 |
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Dithio-oxamide
| 79-40-3 |
|
1-Dodecane sulfonic acid sodium salt
| 2386-53-0 |
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Dodecan-1-ol
| 112-53-8 |
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Dodecyl trimethyl ammonium bromide
| 1119-94-4 |
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Dowfax 9N9
| 9016-45-9 |
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Dulcitol
| 608-66-2 |
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Eriochrome Blue-Black B
| 3564-14-5 |
|
Eriochrome Blue-Black R
| 2538-85-4 |
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Eriochrome cyanine R
| 3564-18-9 |
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