**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 691-38-3 |cis-4-Methyl-2-pentene | 99 | 211-721-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Extremely flammable liquid and vapor. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Will be easily ignited by heat,
sparks or flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. This material is lighter than
water and insoluble in water. The fire could easily be spread by the
use of water in an area where the water cannot be contained. Use
agent most appropriate to extinguish fire. Do NOT use straight
streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Ground and bond containers when transferring
material. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat, sparks
and flame. Avoid ingestion and inhalation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 691-38-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 399 mm Hg @ 37.7 deg C
Viscosity: Not available.
Boiling Point: 57 - 58 deg C @ 760.00 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: -28 deg C ( -18.40 deg F)
Explosion Limits, lower: 1.20 vol %
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 0.6710g/cm3
Molecular Formula: C6H12
Molecular Weight: 84.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Acids, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 691-38-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
cis-4-Methyl-2-pentene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 691-38-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 691-38-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 691-38-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Methylalanine, 97% (titr.)
| 62-57-7 |
|
2,2'-Biquinoline, 98%
| 119-91-5 |
|
Zinc cyclohexanebutyrate dihydrate
| 38582-18-2 |
|
d-(+)-Mannose, 99+%
| 3458-28-4 |
|
N-Benzylidenemethylamine, 99%
| 622-29-7 |
|
p-Nitrophenol
| 100-02-7 |
|
3-Endo-Aminobicyclo??2.2.1??Heptane-2-Endo-Carboxylic Acid Monohydrate,
| 104308-53-4 |
|
2-Naphthyl-beta-D-galactopyranoside
| 33993-25-8 |
|
Triethylborane, 1M solution in THF
| 97-94-9 |
|
cis-4-Methyl-2-pentene, 99%
| 691-38-3 |
|
4-Bromoisophthalic Acid, 97%
| 6939-93-1 |
|
9,10-Dihydroanthracene, techn. 90%
| 613-31-0 |
|
Dodecyl isocyanate, 99%
| 4202-38-4 |
|
Nickel on Silica/Alumina, Catalyst, 64% Ni Reduced and Stabilized
| |
|
Trans-(-)-1,4-Di-O-Tosyl-2,3-0-Isopropylidene-L-Threitol, 97%
| 37002-45-2 |
|
Ethyl(ethoxymethylene)cyanoacetate, 98%
| 94-05-3 |
|
Nicotinamide Adenine Dinucleotide Trihydrate, 98% (UV-Vis)
| 53-84-9 |
|
DL-Methionine, 99%
| 59-51-8 |
|
3',4'-(Didecyloxy)benzaldehyde, 96%
| 118468-34-1 |
|
p-Xylene
| 106-42-3 |
|
3,4-Difluoroanisole, 98+%
| 115144-40-6 |
|
1-Phenylethyl propionate, 98+%
| 120-45-6 |
|
Palladium (II) Chloride
| 7647-10-1 |
|
1-Methyl-2-benzimidazolinone, 98%
| 1849-01-0 |
|
Pancreatin
| 8049-47-6 |
|
Paraformaldehyde
| 30525-89-4 |
|
Biphenyldimethylsilyl Chloride, 99%
| 0-00-1 |
|
1-Pentadecanol, 99+%
| 629-76-5 |
|
4-(Ethoxyfluorophosphinyloxy)-Tempo, Free Radical
| 37566-53-3 |
|
Sulfuric Acid-D2, 97% +/- 1% Solution in D2O, 99.5+ Atom % D
| 7789-20-0 |
|
trans-3-Hexene, 99+%
| 13269-52-8 |
|
1,1-Diethoxy-2-Cyanoethane, 95%
| 2032-34-0 |
|
Dl-Octopamine Hydrochloride, 98%
| 770-05-8 |
|
2,5-Dihydroxyphenylacetic Acid Gamma-Lactone, 97%
| 2688-48-4 |
|
4-Propoxyphenol, 96%
| 18979-50-5 |
|
(-)-Carvyl Acetate, Mixture of Isomers, 98+%
| 97-42-7 |
|
4-Bromobenzenesulfonyl Chloride, 98%
| 98-58-8 |
|
Sodium Hyaluronate, 85%
| 9067-32-7 |
|
5-Hydroxyisoquinoline, tech., 90%
| 2439-04-5 |
|
Poly(4-Chlorostyrene)
| 24991-47-7 |
|
(r)-(-)-2-Phenylpropionic acid, 99%
| 7782-26-5 |
|
Nitro-L-Arginine, 99+%(E.E.)
| 2149-70-4 |
|
Dl-serine, 99%
| 302-84-1 |
|
N, N-Bis-(2,2-=Diethoxyethyl)-Methylamine, 97%
| 6948-86-3 |
|
Eriochrome Blue Black B
| 3564-14-5 |
|
D-Alanine, 99+%
| 338-69-2 |
|
Pinene (Pract)
| 80-56-8 |
|
2-Acetylcyclopentanone, 99%
| 1670-46-8 |
|
1-Benzyl-3-Carbethoxy-4-Piperidone Hydrochloride 97% (TLC)
| 1454-53-1 |
|
1,2-Propanediamine, 97% (titr.)
| 78-90-0 |
|
|