**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 80-56-8 |Alpha-Pinene | ca 100 | 201-291-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes severe skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May cause central nervous system
effects. Human fatalities have been reported from acute poisoning.
Inhalation:
Causes respiratory tract irritation. Irritation may lead to chemical
pneumonitis and pulmonary edema. Vapors may cause dizziness or
suffocation.
Chronic:
May cause kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. May polymerize explosively when
involved in a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. For large fires, use water
spray, fog or alcohol-resistant foam. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 80-56-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: turpentine
pH: Not available.
Vapor Pressure: 4.75 mm Hg @ 25C
Viscosity: Not available.
Boiling Point: 156 deg C
Freezing/Melting Point: -62.5 deg C
Autoignition Temperature: Not available.
Flash Point: 32 deg C ( 89.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8590g/cm3
Molecular Formula: C10H16
Molecular Weight: 136.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Nitric acid (explosive reaction), sulfuric acid, strong oxidizing
agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 80-56-8: DT7000000
LD50/LC50:
CAS# 80-56-8: Draize test, rabbit, skin: 500 mg/24H Moderate; Oral,
rat: LD50 = 3700 mg/kg.
Carcinogenicity:
Alpha-Pinene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: alpha-PINENE
Hazard Class: 3
UN Number: 2368
Packing Group: III
IMO
Shipping Name: alpha-PINENE
Hazard Class: 3.3
UN Number: 2368
Packing Group: III
RID/ADR
Shipping Name: alpha-PINENE
Hazard Class: 3
UN Number: 2368
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 80-56-8: No information available.
Canada
CAS# 80-56-8 is listed on Canada's DSL List.
CAS# 80-56-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 80-56-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/19/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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Triethylborane, 1M solution in THF
| 97-94-9 |
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cis-4-Methyl-2-pentene, 99%
| 691-38-3 |
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4-Bromoisophthalic Acid, 97%
| 6939-93-1 |
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9,10-Dihydroanthracene, techn. 90%
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| 4202-38-4 |
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Nickel on Silica/Alumina, Catalyst, 64% Ni Reduced and Stabilized
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Ethyl(ethoxymethylene)cyanoacetate, 98%
| 94-05-3 |
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Nicotinamide Adenine Dinucleotide Trihydrate, 98% (UV-Vis)
| 53-84-9 |
|
DL-Methionine, 99%
| 59-51-8 |
|
3',4'-(Didecyloxy)benzaldehyde, 96%
| 118468-34-1 |
|
p-Xylene
| 106-42-3 |
|
3,4-Difluoroanisole, 98+%
| 115144-40-6 |
|
1-Phenylethyl propionate, 98+%
| 120-45-6 |
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| 7647-10-1 |
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| 1849-01-0 |
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| 8049-47-6 |
|
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| 30525-89-4 |
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| 0-00-1 |
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1-Pentadecanol, 99+%
| 629-76-5 |
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| 37566-53-3 |
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Sulfuric Acid-D2, 97% +/- 1% Solution in D2O, 99.5+ Atom % D
| 7789-20-0 |
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trans-3-Hexene, 99+%
| 13269-52-8 |
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1,1-Diethoxy-2-Cyanoethane, 95%
| 2032-34-0 |
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| 770-05-8 |
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| 2688-48-4 |
|
4-Propoxyphenol, 96%
| 18979-50-5 |
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(-)-Carvyl Acetate, Mixture of Isomers, 98+%
| 97-42-7 |
|
4-Bromobenzenesulfonyl Chloride, 98%
| 98-58-8 |
|
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| 9067-32-7 |
|
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| 2439-04-5 |
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Poly(4-Chlorostyrene)
| 24991-47-7 |
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(r)-(-)-2-Phenylpropionic acid, 99%
| 7782-26-5 |
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| 2149-70-4 |
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| 3564-14-5 |
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