**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-04-7 |Ethylamine, 70 wt. % solution in water| | 200-834-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F+
Risk Phrases: 12 36/37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Extremely flammable. Irritating to eyes and respiratory system.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Immediately flush eyes
with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower lids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes.
Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Do NOT induce vomiting. Allow the victim
to rinse his mouth and then to drink 2-4 cupfuls of water, and seek
medical advice.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable Liquid.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: health-3; flammability-4; reactivity-0
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Avoid contact with heat, sparks and flame. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Personal Protective Equipment
Eyes:
Wear chemical goggles. Wear safety glasses and
chemical goggles if splashing is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a
respirator's use. Wear a NIOSH/MSHA-approved (or
equivalent) full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Not available.
Appearance: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: 423 hPa @ 20 C
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: 16.6 deg C
Freezing/Melting Point: 0 deg C
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: .7100g/cm3
Molecular Formula: C2H7N
Molecular Weight: 45.07
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong acids - zinc - aluminum - copper,
copper alloys.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-04-7: KH2100000
LD50/LC50:
CAS# 75-04-7: Oral, rat: LD50 = 400 mg/kg; Skin, rabbit: LD50 = 390
uL/kg.
Carcinogenicity:
Ethylamine, 70 wt. % solution in water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Not regulated as a hazardous material.
IATA
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F+
Risk Phrases:
R 12 Extremely flammable.
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
WGK (Water Danger/Protection)
CAS# 75-04-7: 1
Canada
CAS# 75-04-7 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 75-04-7 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 75-04-7:. OEL-AUSTRALIA:TWA 10 ppm (18 mg/m3). OEL-BELGIUM:TWA 1
0 ppm (18 mg/m3). OEL-DENMARK:TWA 10 ppm (18 mg/m3). OEL-FINLAND:TWA 1
0 ppm (18 mg/m3);STEL 20 ppm (37 mg/m3);Skin. OEL-FRANCE:TWA 10 ppm (1
8 mg/m3);STEL 15 ppm (27 mg/m3). OEL-GERMANY:TWA 10 ppm (18 mg/m3);Ski
n. OEL-JAPAN:TWA 10 ppm (18 mg/m3). OEL-THE NETHERLANDS:TWA 10 ppm (18
mg/m3). OEL-THE PHILIPPINES:TWA 10 ppm (18 mg/m3). OEL-POLAND:TWA 3 m
g/m3. OEL-RUSSIA:TWA 10 ppm. OEL-SWEDEN:TWA 10 ppm (18 mg/m3);STEL 15
ppm (30 mg/m3);Skin. OEL-SWITZERLAND:TWA 10 ppm (18 mg/m3);STEL 20 ppm
(36 mg/m3). OEL-TURKEY:TWA 10 ppm (18 mg/m3). OEL-UNITED KINGDOM:TWA
10 ppm (18 mg/m3). OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGI
H TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 75-04-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/01/1994 Revision #2 Date: 8/24/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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