**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-60-5 |Cacodylic acid | 98 | 200-883-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed.Hygroscopic.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Effects of contact may be delayed. Exposure
to arsenic compounds may produce hyperpigmentation of the skin and
hyperkeratoses of plantar and palmar surfaces as well as both primary
irritation and sensitization types.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of arsenical compounds may cause burning of the
lips, throat constriction, swallowing difficulties, severe abdominal
pain, severe nausea, projectile vomiting, and profuse diarrhea. May
be harmful if swallowed. Ingestion of arsenic compounds can produce
convulsions, coma, and possibly death within 24 hours.
Inhalation:
May cause respiratory tract irritation. Effects of inhalation may be
delayed. May cause irritation of the mucous membranes. Inhalation of
arsenic compounds may lead to irritation of the respiratory tract
and leading to possible nasal perforation. Long-term exposure to
arsenic compounds may produce impairment of peripheral circulation.
Chronic:
May alter genetic material.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is nonflammable. Containers may explode
when heated.
Extinguishing Media:
Do NOT use straight streams of water. For small fires, use dry
chemical, carbon dioxide, or water spray. Cool containers with
flooding quantities of water until well after fire is out. For large
fires, use water spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Wash clothing before reuse.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed. Store protected from
moisture. Do not store near fertilizers, seeds or insecticides.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Appearance: colourless
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 195 - 196 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C2H7AsO2
Molecular Weight: 138.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, aluminum, iron, zinc,
moisture.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, arsenic oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-60-5: CH7525000
LD50/LC50:
CAS# 75-60-5: Oral, mouse: LD50 = 1200 mg/kg; Oral, rat: LD50 = 644
mg/kg.
Carcinogenicity:
Cacodylic acid -
ACGIH: A1 - Confirmed Human Carcinogen (listed as ** undefined **
California: carcinogen; initial date 5/1/96
NIOSH: occupational carcinogen (listed as ** undefined **)
NTP: Known carcinogen (listed as ** undefined **).
OSHA: Possible select carcinogen (listed as ** undefined **).
IARC: Group 1 carcinogen (listed as ** undefined **).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CACODYLIC ACID
Hazard Class: 6.1
UN Number: 1572
Packing Group: II
IMO
Shipping Name: CACODYLIC ACID
Hazard Class: 6.1
UN Number: 1572
Packing Group: II
RID/ADR
Shipping Name: CACODYLIC ACID
Dangerous Goods Code: 6.1(51B)
UN Number: 1572
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-60-5: 3
United Kingdom Occupational Exposure Limits
Canada
CAS# 75-60-5 is listed on Canada's NDSL List.
CAS# 75-60-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 75-60-5: OEL-ARAB Republic of Egypt:TWA 0.2 mg(As)/m3
OEL-AUSTRALIA:TWA 0.05 mg(As)/m3;Carcinogen
OEL-BELGIUM:TWA 0.2 mg(As)/m3
OEL-CZECHOSLOVAKIA:TWA 0.2 mg(As)/m3;STEL 0.6 mg(As)/m3
OEL-DENMARK:TWA 0.05 mg(As)/m3
OEL-FINLAND;Carcinogen
OEL-FRANCE:TWA 0.2 mg(As)/m3
OEL-HUNGARY:STEL 0.5 mg(As)/m3;Carcinogen
OEL-INDIA:TWA 0.2 mg(As)/m3
OEL-THE PHILIPPINES:TWA 0.5 mg(As)/m3
OEL-POLAND:TWA 0.3 mg(As)/m3
OEL-SWEDEN:TWA 0.03 mg(As)/m3;Carcinogen
OEL-SWITZERLAND:TWA 0.1 mg(As)/m3;Carcinogen JAN9
OEL-THAILAND:TWA 0.5 mg(As)/m3
OEL-TURKEY:TWA 0.5 mg(As)/m3
OEL-UNITED KINGDOM:TWA 0.2 mg(As)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 75-60-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/18/1999 Revision #2 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Selenium sulfide
| 7488-56-4 |
|
Cacodylic acid, 98%
| 75-60-5 |
|
Zinc Chloride, 99.99%
| 7646-85-7 |
|
Phosphorus, Lump, Red, 99.999%
| 7723-14-0 |
|
Lead (II) Fluoride, Powder, ca. 5 Micron, 99+%
| 7783-46-2 |
|
Ammonium Iron (II) Sulfate Hexahydrate, 99.997%
| 7783-85-9 |
|
Aluminum iodide, 95%, tech.
| 7784-23-8 |
|
Aluminum Iodide, Anhydrous, 99.999%
| 7784-23-8 |
|
Ursolic Acid,95%
| 77-52-1 |
|
Arsenic(iii)bromide, 99.9%
| 7784-33-0 |
|
Arsenic(III) iodide
| 7784-45-4 |
|
Bismuth(III) chloride, 99.999%
| 7787-60-2 |
|
Thallium (I) Bromide, 99.999%
| 7789-40-4 |
|
Antimony(iii)bromide, 99.99%
| 7789-61-9 |
|
Poly(acenaphthylene)
| 25036-01-5 |
|
Antimony Tribromide, 99%
| 7789-61-9 |
|
Calcium iodate, 98%
| 7789-80-2 |
|
Rubidium Iodide, 99.9%
| 7790-29-6 |
|
Manganese(II) Iodide, 99%
| 7790-33-2 |
|
Antimony Triiodide, 98%
| 7790-44-5 |
|
Calcium tungstate(VI)
| 7790-75-2 |
|
Calcium Pyrophosphate
| 7790-76-3 |
|
Thallium (I) Chloride, 99.999%
| 7791-12-0 |
|
Selenium (IV) Oxychloride, 97%
| 7791-23-3 |
|
Cobalt(II) Bromide Hydrate
| 85017-77-2 |
|
Dichlorophenylborane, 97%
| 873-51-8 |
|
alpha-Fluorophenylacetic acid, 99+%
| 1578-63-8 |
|
Trichloroethylgermane, 97%
| 993-42-0 |
|
Rac-Ethylenebis(Indenyl) Zirconium (IV) dichloride
| 100080-82-8 |
|
Aflatoxin b1, crystalline
| 1161-94-0 |
|
Iridium(III) Chloride
| 10025-83-9 |
|
Cyclooctatetraene Iron Tricarbonyl, 98%
| 12093-05-9 |
|
(cis, cis-1,5-cyclooctadiene)palladium(ii) chloride, 99%
| 12107-56-1 |
|
Vinylbenzyl Trimethylammonium Chloride (60:40 Para:Meta Mixture)
| 26616-35-3 |
|
Sodium Hexachloroosmate (IV) Hydrate
| 1307-81-9 |
|
Rhenium (VII) Oxide, 99.99%
| 1314-68-7 |
|
Gold (III) Chloride, 99%
| 13453-07-1 |
|
5,10,15,20-Tetraphenyl-21H,23H-porphine zinc, synthetic, 95%
| 14074-80-7 |
|
5,10,15,20-Tetraphenyl-21h,23h-porphine ni ckel(ii), synthetic
| 14172-92-0 |
|
Dirhenium Decacarbonyl, 98%
| 14285-68-8 |
|
5,10,15,20-Tetraphenyl-21h,23h-porphine va nadium(iv)oxide
| 14705-63-6 |
|
Sodium Hexachlororhodate (III) Hydrate
| 14972-70-4 |
|
Osmium (III) Chloride Hydrate
| 14996-60-2 |
|
Triosmium Dodecacarbonyl, 98%
| 15696-40-9 |
|
5,10,15,20-Tetraphenyl-21h,23h-porphine iron(iii)chloride, synthetic
| 16456-81-8 |
|
Potassium Hexacyanoplatinate (IV)
| 16920-94-8 |
|
(2S,5S)-(+)-Hexanediol, 99% (99% E.E.)
| 34338-96-0 |
|
Tris(dibenzylideneacetone)dipalladium(0)
| 51364-51-3 |
|
Potassium Tetracyanoplatinate (II)
| 562-76-5 |
|
5,10,15,20-Tetrakis(4-(trimethylammonio)-p henyl)-21h,23h-porphine
| 69458-20-4 |
|
|