**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 27176-10-9 |Phosphoric acid, tripotassium salt, mo| >95 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation. Depending on the intensity and duration of
exposure, effects may vary from irritation to burns.
Skin:
Causes skin irritation and possible severe skin irritation
especially if the skin is wet or moist.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Inhalation of dust causes
severe irritation of the nose and throat.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately wipe away excess material with a dry
cloth while removing contaminated clothing and shoes. Under safety
shower, wash affected areas thoroughly with large amounts of water,
and soap if available, for at least 15 minutes.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid breathing dust. Do not get in
eyes. Avoid contact with skin and clothing.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7778-53-2:
CAS# 27176-10-9:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: Odorless
pH: 12.5-14 (aq soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 1340 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 2.5
Molecular Formula: K3O4P.H2O
Molecular Weight: 230.28
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Oxides of phosphorus, dipotassium oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7778-53-2: TC8450000
CAS# 27176-10-9 unlisted.
LD50/LC50:
CAS# 7778-53-2: Draize test, rabbit, eye: 10 mg Moderate; Skin,
rabbit: LD50 = >4640 mg/kg.
CAS# 27176-10-9.
Eye contact: Extremely irrtating (rabbit). Source: FMC report
I86-0925, 1986.
Carcinogenicity:
Potassium phosphate, tribasic, anhydrous, K3PO4 -
Not listed by ACGIH, IARC, or NTP.
Phosphoric acid, tripotassium salt, monohydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7778-53-2: 1
CAS# 27176-10-9: No information available.
Canada
CAS# 7778-53-2 is listed on Canada's DSL List.
CAS# 7778-53-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 27176-10-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7778-53-2 is listed on the TSCA inventory.
CAS# 27176-10-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 12/12/1997 Revision #4 Date: 3/25/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Allyldimethylchlorosilane, 97%
| 4028-23-3 |
|
Isopropylmethyldichlorosilane, 97%
| 18236-89-0 |
|
Potassium dichromate, 99.5%
| 7778-50-9 |
|
Allyl ether, 99%
| 557-40-4 |
|
N-Decanoic Anhydride, 98%
| 2082-76-0 |
|
2,2-Dimethyl-1,3-Dioxolane, 99%
| 2916-31-6 |
|
Methylene Blue (Pract), 75% (Titr.)
| 61-73-4 |
|
Diethyl 3,3-Dimethylcyclopent-1-Enylphosphonate, 98%
| 0-01-1 |
|
Ammonium molybdate tetrahydrate, certified ACS, crystalline
| 12027-67-7 |
|
Tris(6,6,7,7,8,8,8-Heptafluoro-2,2-
| 18323-96-1 |
|
(3,3-Dimethylcyclopent-1-enylmethyl)trimethylsilane, 97%
| 0-01-1 |
|
2,4-Dimethoxy-1-Nitrobenzene, 98%
| 4920-84-7 |
|
2-Methylpropyl 3,5-Diamino-4-Chlorobenzoate
| 32961-44-7 |
|
Phthalic Acid Monopotassium Salt, 99+% (Titr.)
| 877-24-7 |
|
Ammonium nitrate
| 6484-52-2 |
|
Diethyl 3,3-Dimethylcyclohex-1-Enylphosphonate, 98%
| 109467-69-8 |
|
4-Amino-N,N-Diethyl-m-Toluidine Hydrochloride, 98%
| 148-71-0 |
|
(3,3-Dimethylcyclohex-1-enylmethyl)trimethylsilane, 98%
| 0-01-1 |
|
2-Phenylmercaptomethylbenzoic Acid, 98%
| 1699-03-2 |
|
Rhein, Tech. 90%
| 478-43-3 |
|
Potassium hydroxide, pellets, p.a.
| 1310-58-3 |
|
Salicylideneaniline, 98%
| 779-84-0 |
|
2,6-Diaminopurine
| 1904-98-9 |
|
N-Alpha-Carbobenzyloxy-L-Arginine, 98%
| 1234-35-1 |
|
Methylphenylvinylsilane
| 17878-39-6 |
|
Potassium Iodate, P.A.
| 7758-05-6 |
|
Potassium Metabisulfite
| 16731-55-8 |
|
Potassium Nitrite, Reagent ACS (Crystals), 96+% (Titr.)
| 7758-09-0 |
|
Dimethylmethoxy-n-octylsilane
| 93804-29-6 |
|
Potassium oxalate monohydrate, reagent ACS
| 583-52-8 |
|
Dodecamethylpentasiloxane, 97%
| 141-63-9 |
|
Potassium periodate (meta), 99+% (titr.)
| 7790-21-8 |
|
(4-Nitrophenyl)Octyl Ether, 99%
| 49562-76-7 |
|
1-Methoxy-1-methylamino-2-nitroethylene, 98%
| 110763-36-5 |
|
3-Hydroxy-1,2,3-Benzotriazin-4(3H)-One, 98%
| 28230-32-2 |
|
Strontium peroxide, 90-95%
| 1314-18-7 |
|
1,1,3,3,5,5-Hexamethyltrisiloxane, 97%
| 1189-93-1 |
|
Phosphorus pentachloride
| 10026-13-8 |
|
Potassium Permanganate, P.A.
| 7722-64-7 |
|
Astaxanthin
| 471-53-4 |
|
Thapsigargin
| 67526-95-8 |
|
Wortmannin
| 19545-26-7 |
|
AMT.hydrochloride
| 1121-91-1 |
|
Potassium Persulfate, Reagent ACS (Crystals), 99+% (Titr.)
| 7727-21-1 |
|
3-Bromo-7-nitroindazole
| 74209-34-0 |
|
Potassium phosphate tribasic monohydrate
| 7778-53-2 |
|
Methyl 4-aminobenzoate, 98%
| 619-45-4 |
|
Carboxy-PTIO
| 148819-94-7 |
|
1,4-Dibromobutane, 97%
| 110-52-1 |
|
tert-Butylhydroquinone, 97%
| 1948-33-0 |
|
|