**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 95-57-8 |2-Chlorophenol | >98.0% | 202-433-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 20/21/22 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Toxic
to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation and possible burns. Causes redness and
pain.
Skin:
Harmful if absorbed through the skin. Causes redness and pain. May
cause skin irritation and possible burns. May cause contact
dermatitis.
Ingestion:
May cause irritation of the digestive tract. Poison by ingestion.
May cause liver and kidney damage. May cause central nervous system
depression. May cause burning sensations, coughing, wheezing,
laryngitis, shortness of breath and headache.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema. May
cause burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea, and vomiting. Overexposure produces central
nervous system depression.
Chronic:
Repeated exposure may cause central nervous system damage. Prolonged
exposure can injure liver, kidneys and lungs.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Do not get on skin or in eyes.
Do not ingest or inhale. Use with adequate ventilation. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 95-57-8:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light amber
Odor: penetrating odor - unpleasant odor
pH: Weakly acidic
Vapor Pressure: 1.3 mbar @ 12 C
Viscosity: 4.11 CP@ 25.0 C
Boiling Point: 173.0 - 175.0 deg C
Freezing/Melting Point: 8 deg C
Autoignition Temperature: 550 deg C ( 1,022.00 deg F)
Flash Point: 85 deg C ( 185.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >300 deg C
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.262g/cm3
Molecular Formula: C6H5ClO
Molecular Weight: 128.56
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Acid anhydrides, acid chlorides, aluminum, copper.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 95-57-8: SK2625000
LD50/LC50:
CAS# 95-57-8: Oral, mouse: LD50 = 345 mg/kg; Oral, mouse: LD50 = 345
mg/kg; Oral, mouse: LD50 = 345 mg/kg; Oral, rat: LD50 = 40 mg/kg;
Oral, rat: LD50 = 670 mg/kg.
Carcinogenicity:
2-Chlorophenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: 2,580 ug/l; 96 hour; Not specifiedFish: Fathead Minnow:
11,630 ug/l; 96 hour; Static, unmeasured bioassayFish: Fathead
Minnow: 20,170 ug/l; 96 hour; Static, unmeasured bioassayFish:
Bluegill/Sunfish: 6,590 ug/l; 96 hour; Static, unmeasured bioassay
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROPHENOLS, LIQUID
Hazard Class: 6.1
UN Number: 2021
Packing Group: III
IMO
Shipping Name: CHLOROPHENOLS, LIQUID
Hazard Class: 6.1
UN Number: 2021
Packing Group: III
RID/ADR
Shipping Name: CHLOROPHENOLS, LIQUID
Hazard Class: 6.1
UN Number: 2021
Packing group: III
USA RQ: CAS# 95-57-8: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 95-57-8: 2
Canada
CAS# 95-57-8 is listed on Canada's DSL List.
CAS# 95-57-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 95-57-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/03/1998 Revision #3 Date: 11/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-CYANONAPHTHALENE, TECH.
| 86-53-3 |
|
1,4-DICYANO-2-BUTENE, 97%
| 1119-85-3 |
|
4-METHOXY-2-METHYLANILINE, 98%
| 102-50-1 |
|
Perchloromethyl mercaptan, 97%
| 594-42-3 |
|
2,4,5-Trichloroaniline, tech., 97%
| 636-30-6 |
|
2,4,6-Trimethylphenol, 99%
| 527-60-6 |
|
n-Undecyl cyanide, 94%
| 2437-25-4 |
|
2-Methoxy-5-methylaniline, 95%
| 120-71-8 |
|
4-Chloro-o-phenylenediamine, 96%
| 95-83-0 |
|
2-[4-(4-Dimethylaminophenyl)-1,3-butadieny
| 8903-71-1 |
|
Hexachloro-1,3-butadiene, 98%
| 87-68-3 |
|
p-Nitrosophenol
| 104-91-6 |
|
STEARONITRILE TECHN. 90+%
| 638-65-3 |
|
Fumaronitrile, 98%
| 764-42-1 |
|
2-Thiopheneacetonitrile, tech., 94%
| 20893-30-5 |
|
Bis(carboxymethyl) trithiocarbonate, 98%
| 6326-83-6 |
|
5-METHOXY-1,3,4-TRIPHENYL-4,5-DIHYDRO-1H-1,2,4-TRIAZOLIN
| 0-01-1 |
|
3,3'-Thiodipropionitrile
| 111-97-7 |
|
Methylenaminoacetonitrile, 98%
| 109-82-0 |
|
2,2,4,4,6,8,8-Heptamethylnonane, 98%
| 4390-04-9 |
|
N-(2-Aminoethyl)pyrrolidine, 99%
| 7154-73-6 |
|
4-Chloro-2-methoxy-5-methylaniline, tech., 85%
| 6376-14-3 |
|
3-Chloro-4-nitroaniline, 97%
| 825-41-2 |
|
2-Chloro-1,3,2-dioxaphospholane, 97%
| 822-39-9 |
|
Tetraisopropylthiuram disulfide, 98%
| 4136-91-8 |
|
6-Hydroxyflavone
| 6665-83-4 |
|
7-Hydroxyflavone
| 6665-86-7 |
|
2-Chloro-1,4-benzoquinone, 95%
| 695-99-8 |
|
2,6-Dimethoxy-1,4-benzoquinone, 97%
| 530-55-2 |
|
2'-Hydroxy-5'-methoxyacetophenone, 99%
| 705-15-7 |
|
6-NITROINDOLINE
| 19727-83-4 |
|
2-Chlorophenol, 98+%
| 95-57-8 |
|
3,4,5,6-TETRACHLOROPHTHALIMIDE
| 1571-13-7 |
|
Diethyl(phthalimidomethyl)phosphonate, 97%
| 33512-26-4 |
|
4-Butoxy-2-nitroaniline, 99%
| 3987-86-8 |
|
4-Chloro-1,2-phenylenediamine, 97%
| 95-83-0 |
|
Silica gel, 3-6 mm, pore diameter ca. 9 nm
| 7631-86-9 |
|
Ethylenediaminetetraacetic acid dicopper salt, tetrahydrate, 98%
| 39208-15-6 |
|
Diphenylselenium dichloride, 97%
| 2217-81-4 |
|
2-Bromostearonitrile
| 0-01-1 |
|
4-Chlorophenyl methyl sulfide, 98%
| 123-09-1 |
|
N-Cyclohexylaniline, 98%
| 1821-36-9 |
|
3-Amino-4-chlorobenzenesulfonic acid hydrate, 97%
| 98-36-2 |
|
2-Hexenedinitrile
| 13042-02-9 |
|
4-Methylsulphonylbenzyl bromide, tech, 75-80%
| 53606-06-7 |
|
L-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid, 98%
| 74163-81-8 |
|
Titanium(III) chloride, Al reduced, 98%
| 12003-13-3 |
|
Ethyl-3-Indoleacetate, 99%
| 778-82-5 |
|
1-Acetylindole, 98%
| 576-15-8 |
|
5-Fluoroindole-2-carboxylic acid, 98%
| 399-76-8 |
|
|