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MSDS  : Acetonitrile, phenyl-
CAS  : 140-29-4
SYNONYMS  : * Benzeneacetonitrile * Benzyl cyanide * Benzylkyanid * Benzyl nitrile * (Cyanomethyl)benzene * alpha-Cyanotoluene * omega-Cyanotoluene * Phenylacetonitrile * 2-Phenylacetonitrile * Phenyl acetyl nitrile * Toluene, alpha-cyano- * alpha-Tolunitrile * USAF KF-21
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : AM1400000
CHEMICAL NAME : Acetonitrile, phenyl-
CAS REGISTRY NUMBER : 140-29-4
LAST UPDATED : 199710
DATA ITEMS CITED : 21
MOLECULAR FORMULA : C8-H7-N
MOLECULAR WEIGHT : 117.16
WISWESSER LINE NOTATION : NC1R
COMPOUND DESCRIPTOR : Primary Irritant
SYNONYMS/TRADE NAMES :
* Benzeneacetonitrile
* Benzyl cyanide
* Benzylkyanid
* Benzyl nitrile
* (Cyanomethyl)benzene
* alpha-Cyanotoluene
* omega-Cyanotoluene
* Phenylacetonitrile
* 2-Phenylacetonitrile
* Phenyl acetyl nitrile
* Toluene, alpha-cyano-
* alpha-Tolunitrile
* USAF KF-21

*** HEALTH HAZARD DATA ***

** SKIN/EYE IRRITATION DATA **

TYPE OF TEST : Standard Draize test
ROUTE OF EXPOSURE : Administration onto the skin
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 500 mg/24H
REACTION SEVERITY : Mild
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House,
Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year:
20,803,1982

** ACUTE TOXICITY DATA **

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 270 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
Lungs, Thorax, or Respiration - dyspnea
Liver - other changes
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O
Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936-
Volume(issue)/page/year: 32(8),20,1967

TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 430 mg/m3/2H
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex)
Behavioral - muscle contraction or spasticity
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA.
(Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year:
32(7-9),176,1967

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Administration onto the skin
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House,
Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year:
20,803,1982

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 74982 ug/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
Behavioral - excitement
Behavioral - changes in motor activity (specific assay)
REFERENCE :
TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE
Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 10,265,1982

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 45500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000
Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year:
55,47,1984

TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 100 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
GKNT, 1982 Volume(issue)/page/year: -,25,1982

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 10 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: AD277-689

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 32 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4-
1898- Volume(issue)/page/year: 12,447,1904

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Administration onto the skin
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 270 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House,
Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year:
20,803,1982

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 50 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - spastic paralysis with or without sensory
change
Behavioral - ataxia
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4-
1898- Volume(issue)/page/year: 5,161,1899

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 10 mg/kg
TOXIC EFFECTS :
Behavioral - general anesthetic
Behavioral - somnolence (general depressed activity)
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: OTS0570995

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Administration onto the skin
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 5 mL/kg
TOXIC EFFECTS :
Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: OTS0570995

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Intramuscular
SPECIES OBSERVED : Bird - pigeon
DOSE/DURATION : 120 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House,
Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year:
20,803,1982

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Amphibian - frog
DOSE/DURATION : 1100 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - spastic paralysis with or without sensory
change
Behavioral - ataxia
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4-
1898- Volume(issue)/page/year: 5,161,1899

** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 60 mg/m3/2H/4W-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea
or bronchi
Liver - other changes
Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O
Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936-
Volume(issue)/page/year: 32(8),20,1967

*** OCCUPATIONAL EXPOSURE LIMITS ***

OEL-RUSSIA:STEL 0.8 mg/m3;Skin JAN 1993

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - 83175
No. of Facilities: 41 (estimated)
No. of Industries: 2
No. of Occupations: 3
No. of Employees: 705 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - 83175
No. of Facilities: 28 (estimated)
No. of Industries: 2
No. of Occupations: 10
No. of Employees: 5911 (estimated)
No. of Female Employees: 1005 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY

EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998


*** END OF RECORD ***
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ALL Chemical Property And Toxicity Analysis PAGES IN THIS GROUP
NAMECAS
Acetonitrile,(6-(beta-D-glucopyranosyloxy)-2-hydroxy-3,4-dimethoxycyclohexylidene)-, (1Z,2-alpha,3-beta,4-beta,6-beta)- 51771-52-9
Acetohydroxamic acid,2-(5-methoxy-2-methyl-3-indolyl)- 34024-41-4
Acetonitrile,((4-hydrazino-6-(4-morpholinyl)-1,3,5-triazin-2-yl)oxy)- 137522-79-3
Acetonitrile, hydroxy- 107-16-4
Acetonitrile,((2-(((3-beta,5-alpha,17-beta)-3-hydroxyandrostan-17-yl)methylamino)ethyl) amino)-, dihydrochloride 126054-51-1
Acetonitrile,(((3-beta,5-alpha,17-beta)-3-hydroxyandrostan-17-yl)methylamino)-, monohydrochloride 126054-50-0
Acetonitrile,(4-(5-(hydroxymethyl)-2-oxo-3-oxazolidinyl)phenoxy)- 64589-74-8
Acetonitrile, (p-hydroxyphenyl)- 14191-95-8
Acetonitrile, iminodi- 628-87-5
Acetonitrile, 3-indolyl- 771-51-7
Acetonitrile,((1-((4-methoxy-3-nitrophenyl)methyl)-2-methyl-4-nitro-1H-imidazol-5-yl)th io)- 77952-82-0
Acetonitrile, (p-methoxyphenyl)- 104-47-2
Acetohydroxamic acid,2-(2-(p-methoxyphenyl)acetamido)- 76968-89-3
Acetonitrile,((4-(((2-methoxyphenyl)methylene)hydrazino)-6-(4-morpholinyl)-1,3,5-triazi n- 2-yl)oxy)- 137522-80-6
Acetonitrile,((2-(((methylamino)carbonyl)oxy)phenyl)thio)- 52174-02-4
Acetonitrile, methylamino-, sulfate 33986-15-1
Acetonitrile, 2-(2-(N-methylanilino)acetyl)-2-phenyl- 73663-78-2
Acetonitrile,N-methyl-N-((2-methyldiphenylmethoxy)ethyl)amino-,hydrochloride 18552-83-5
Acetonitrile,((1-methyl-4-nitro-1H-imidazol-5-yl)thio)- 110579-01-6
Acetonitrile,((2-methyl-5-nitro-1H-imidazol-4-yl)thio)- 110579-00-5
Acetonitrile, 2(N-methyl-N-nitroso)amino- 3684-97-7
Acetonitrile, ((alpha-methylphenethyl)amino)phenyl- 17590-01-1
Acetonitrile,(5-(4-methylphenyl)-3-oxo-2(3H)-furanylidene)- 97180-86-4
Acetohydroxamic acid, N-methyl- 13115-24-7
Acetonitrile, morpholinocarbonyl- 15029-32-0
Acetonitrile,2,2'-((6-(4-morpholinyl)-1,3,5-triazine-2,4-diyl)bis(oxy))bis- 137522-82-8
Acetonitrile, (1-naphthyl)- 132-75-2
Acetonitrile, 2,2',2''-nitrilotris- 7327-60-8
Acetonitrile, (m-nitrophenyl)- 621-50-1
Acetonitrile, (o-nitrophenyl)- 610-66-2
Acetonitrile, (p-nitrophenyl)- 555-21-5
Acetonitrile, 2,2'-(N-nitrosoimino)di- 16339-18-7
Acetonitrile, (3-oxo-5-phenyl-2(3H)-furanylidene)- 97180-85-3
Acetonitrile, (m-phenoxyphenyl)- 51632-29-2
Acetohydroxamic acid, N-(2'-methylbiphenyl-4-yl)- 70786-71-9
Acetonitrile, (m-phenoxyphenyl)oxo- 61775-25-5
Acetonitrile, phenyl- 140-29-4
Acetonitrile, phenylamino- 3009-97-0
Acetonitrile, m-phenylenedi- 626-22-2
Acetonitrile, 2-phenyl-2-piperidino- 5766-79-0
Acetonitrile, (phenylthio)- 5219-61-4
Acetonitrile, piperidino- 3010-03-5
Acetonitrile, (purin-6-ylthio)- 5443-91-4
Acetonitrile,((1,4,5,6-tetrahydro-4,6-dioxo-1,3,5-triazin-2-yl)oxy)-, dihydrate 137522-78-2
Acetonitrile, m-toluidino- 28354-22-5
Acetohydroxamic acid, 2-(4-methylvaleramido)- 73912-96-6
Acetonitrile, o-toluidino- 16728-83-9
Acetonitrile, o-tolyl- 22364-68-7
Acetonitrile,2,2',2''-(1,3,5-triazine-2,4,6-triyltris(oxy))tris- 891-64-5
Acetonitrile, trichloro- 545-06-2

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