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MSDS  : Iron carbonyl
CAS  : 13463-40-6
SYNONYMS  : * FER pentacarbonyle * Iron, pentacarbonyl- * Iron pentacarbonyl * Pentacarbonyliron
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : NO4900000
CHEMICAL NAME : Iron carbonyl
CAS REGISTRY NUMBER : 13463-40-6
OTHER CAS REGISTRY NOS. : 37220-42-1
LAST UPDATED : 199712
DATA ITEMS CITED : 34
MOLECULAR FORMULA : C5-Fe-O5
MOLECULAR WEIGHT : 195.90
WISWESSER LINE NOTATION : FE C-O*4
COMPOUND DESCRIPTOR : Organometallic
SYNONYMS/TRADE NAMES :
* FER pentacarbonyle
* Iron, pentacarbonyl-
* Iron pentacarbonyl
* Pentacarbonyliron

*** HEALTH HAZARD DATA ***

** ACUTE TOXICITY DATA **

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 25 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides
and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
Washington, DC 20460) History unknown. Volume(issue)/page/year:
8EHQ-0591-1177

TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 910 mg/m3/30M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60.
For publisher information, see AEHLAU. Volume(issue)/page/year: 19,11,1959

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 62 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and
Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
V.1-36, 1957-1992. For publisher information, see MTPEEI
Volume(issue)/page/year: 26(6),52,1982

TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 2190 mg/m3/30M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60.
For publisher information, see AEHLAU. Volume(issue)/page/year: 19,11,1959

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 60 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides
and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
Washington, DC 20460) History unknown. Volume(issue)/page/year:
8EHQ-0591-1177

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Mammal - cat
DOSE/DURATION : 100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides
and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
Washington, DC 20460) History unknown. Volume(issue)/page/year:
8EHQ-0591-1177

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 12 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA)
V.18-31, 1936-49. For publisher information, see AEHLAU.
Volume(issue)/page/year: 25,415,1943

TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 250 ppm/45M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
Academic Press, Inc., 1969 Volume(issue)/page/year: -,335,1969

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Administration onto the skin
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 240 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
Academic Press, Inc., 1969 Volume(issue)/page/year: -,335,1969

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 240 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA)
V.18-31, 1936-49. For publisher information, see AEHLAU.
Volume(issue)/page/year: 25,415,1943

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intravenous
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 11 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA)
V.18-31, 1936-49. For publisher information, see AEHLAU.
Volume(issue)/page/year: 25,415,1943

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 22 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA)
V.18-31, 1936-49. For publisher information, see AEHLAU.
Volume(issue)/page/year: 25,415,1943

TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 140 ppm/30M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides
and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
Washington, DC 20460) History unknown. Volume(issue)/page/year:
8EHQ-0591-1177

** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 15 ppm/6H/2D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - chronic pulmonary edema
Lungs, Thorax, or Respiration - cyanosis
Related to Chronic Data - death
REFERENCE :
BJIMAG British Journal of Industrial Medicine. (British Medical Journal,
Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year:
27,1,1970

*** REVIEWS ***

ACGIH TLV-STEL 0.45 mg/m3 (0.2 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

ACGIH TLV-TWA 0.23 mg/m3 (0.1 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

TOXICOLOGY REVIEW
AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St.,
NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year:
23,373,1971

*** U.S. STANDARDS AND REGULATIONS ***

MSHA STANDARD-air:TWA 0.01 ppm (0.08 mg/m3)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
3,137,1971

*** OCCUPATIONAL EXPOSURE LIMITS ***

OEL-AUSTRALIA:TWA 0.1 ppm (0.8 mg/m3);STEL 0.2 ppm (1.6 mg/m3) JAN 1993

OEL-BELGIUM:TWA 0.1 ppm (0.23 mg/m3);STEL 0.2 ppm (0.45 mg/m3) JAN 1993

OEL-DENMARK:TWA 0.1 ppm (0.8 mg/m3) JAN 1993

OEL-FINLAND:STEL 0.01 ppm (0.08 mg/m3) JAN 1993

OEL-FRANCE:TWA 0.1 ppm (0.8 mg/m3) JAN 1993

OEL-GERMANY:TWA 0.1 ppm (0.8 mg/m3) JAN 1993

OEL-THE NETHERLANDS:TWA 0.01 ppm (0.08 mg/m3) JAN 1993

OEL-RUSSIA:STEL 0.1 mg/m3;Skin JAN 1993

OEL-SWITZERLAND:TWA 0.1 ppm (0.8 mg/m3);STEL 0.2 ppm (1.6 mg/m3) JAN 1993

OEL-UNITED KINGDOM:TWA 0.01 ppm (0.08 mg/m3) JAN 1993

OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV

OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO IRON PENTACARBONYL (as Fe)-air:TWA 0.1 ppm;STEL 0.2 ppm
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - X6270
No. of Facilities: 7 (estimated)
No. of Industries: 1
No. of Occupations: 1
No. of Employees: 1822 (estimated)
No. of Female Employees: 272 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY

EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998


*** END OF RECORD ***
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NAMECAS
2-Indolinone,1-methyl-3-(5-phenyl-1,3,4-oxadiazol-2-ylimino)- 84640-83-5
Iron,bis(1,2-benzenediamine-N,N')(ethanedioato(2-)-O,O')-,(OC-6-22)- 75079-27-5
Iron,bis(1,2-ethanediamine-N,N')(ethanedioato(2-)-O,O')-,(OC-6-22)- 67537-95-5
Iron(2+), bis(1,2-ethanediamine-N,N')-,(T-4)-tetrakis(thiocyanato-N)mercurate(2-) (1:1),homopolymer 80732-92-9
Iron(II), bis(N-ethylidenethreoninato)diaquo- 15339-50-1
Iron, bis(mu-(methanethiolato))tetranitrosyldi-,(Fe-Fe) 16071-96-8
Iron,bis(3-methylbenzenamine)(ethanedioato(2-)-O,O')- 74910-19-3
Iron,bis(3-((phenylamino)methyl)-2(3H)-benzoxazolone-N(supN(sup 3),O(sup 2))bis (thiocyanato-N))- 82489-95-0
Iron,bis(1,2,3,6-tetrahydro-2,6-dioxo-4-pyrimidinecarboxylato-N(sup 3),O(sup 4))- 85187-45-7
Iron, (1,3-butadiene)tricarbonyl- 12078-32-9
Iron carbonyl 13463-40-6
2-Indolinone,5-methyl-3-(5-phenyl-1,3,4-oxadiazol-2-ylimino)- 84640-91-5
Iron(II) chloride (12) 7758-94-3
Iron(3+) chloride, hexahydrate 10025-77-1
Iron(2+) chloride, tetrahydrate 13478-10-9
Iron dextran glycerol glycoside 13478-10-9
Iron-dextrin complex 9004-51-7
Iron, diammine(ethanedioato(2-)-O,O')-, (T-4)- 67619-85-6
Iron, dicarbonyl-pi-cyclopentadienyl-, iodide 12078-28-3
Iron, (dihydrogen3,7,12,17-tetramethyl-8,13-divinyl-2,18-porphinedipropionato(2-))-hydroxy- 15489-90-4
Iron(3+),(N1-(3-(dimethylsulfonio)propyl)bleomycinamidato)- 72028-04-7
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2-Indolinone, 3-(2-nitro-1-nitrosoethylidene)- 72028-04-7
Iron, (ethanedioato(2-)-O,O')bis(1-butanamine)- 80660-60-2
Iron, (ethanedioato(2-)-O,O')bis(methanamine)- 80660-61-3
Iron,(ethanedioato(2-)-O,O')bis(3-methoxybenzenamine-N)- 80660-63-5
Iron,(ethanedioato(2-)-O,O')bis(4-methoxybenzenamine-N)- 80660-63-5
Iron,(ethanedioato(2-)-O,O')bis(1-methylpiperazine-N(sup1),N(sup 4))- 75079-26-4
Iron,(ethanedioato(2-)-O,O')bis(1,10-phenanthroline-N(sup1),N(sup 10))-, (OC-6-22)- 14783-55-2
Iron,(ethanedioato(2-)-O,O')bis(3-((phenylamino)methyl)-2(3H)-benzoxazolone- N(sup N(sup 3),O(sup 2))- 82489-96-1
Iron,(ethanedioato(2-)-O,O')bis(1-phenylpiperazine-N(sup1),N(sup 4))- 75079-25-3
Iron, (ethanedioato(2-)-O,O')bis(pyridine1-oxide-O)-, (T-4)- 74167-27-4
Iron, (ethanedioato(2-)-O,O')tetrakis(piperidine)-,(OC-6-22)- 80660-62-4
2-Indolinone, 3-(phenylimino)- 33828-98-7
Iron fluoride 7783-50-8
Iron, (hydrogen(ethylenedinitrilo)tetraacetato)- 17099-81-9
Iron(III)hydroxide-polymaltose 17099-81-9
Iron, ion(Fe 2+) 15438-31-0
Iron(1+), (isonicotinic acid hydrazide)-, sulfate,dihydrate 15438-31-0
Iron magnesium manganese oxide 37187-66-9
Iron manganese zinc oxide 12645-49-7
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Iron nickel zinc oxide 12645-50-0
Iron(II) nitrate hexahydrate (126) 13520-68-8
2-Indolinone, 3-(5-phenyl-1,3,4-oxadiazol-2-ylimino)- 84640-80-2
Iron(III) nitrate, nonahydrate (139) 7782-61-8
Iron, (nitrilotriacetato)- 16448-54-7
Iron, nitrosotris(dimethyldithiocarbamato)-, mixedwith bis(dimethylthiocarbamoyl)disulfideSUBSTANCE DEFINITION :58.5% main component, 6.5% secondary componentREFERENCE :NTIS** National Technical Information Service. (Springfield, VA 22161)Formerly U.S. Clearinghouse for Scientific & Technical Information. 16448-54-7
Iron ore, respirable dust 16448-54-7
Iron(III) oxide 1309-37-1

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