SHELL OIL CO -- EPI-CURE CURING AGENT 9470
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Material Safety Data Sheet
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MSDS Num: BXSKK
MSDS NAME: EPI-CURE CURING AGENT 9470
Responsible Party
Name: SHELL OIL CO
Box: 4320
City: HOUSTON TX 77210
Info Phone: 713-241-4819
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Preparer's Name: J.C. WILLETT
Proprietary Ind: Y
Published: Y
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Contractor Summary
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Name: SHELL OIL CO
Box: 4320
City: HOUSTON TX 77210-5000
Phone: 713-473-9461/713-241-2252
Name: SHELL OIL COMPANY
Box: 2463
City: HOUSTON TX 77210
Phone: 800-231-6950
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: MAY BE SEV IRRIT. SKIN: MAY BE SEV IRRIT. MAY CAUSE
SKIN SENSIT (ALLERGY) EVID BY RASHES, ESP HIVES. MAY BE TOX IF ABSORBED THRU
SKIN. INHAL: MAY CAUSE IRRIT TO NOSE, THROAT & RESP TRACT, ESP IF HEATED
OR IF MISTS ARE PRDCED. MAY CAUSE RESP TRACT SENSIT (E.G. ALLERGY, ASTHMA)
EVID BY WHEEZ WITH (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: SHORTNESS OF BREATH & COUGH.
INGEST: MAY BE TOX. ING 1 HAS CAUSED CANCER & PANCREATIC TOX IN LAB
ANIMALS IN 1 ORAL BIOASSAY. IT HAS CAUSED INCR INCIDENCE OF LIVER, THYROID
& PITUITARY TUMORS IN 2 YR STUDY IN RATS DOSED UP TO 70PPM DAILY. NOEL
WAS 35 PPM. PANCREATIC TOX ALSO OBSERVED IN THIS STUDY.
Medical Cond Aggravated By Exposure: PREEXISTING EYE, SKIN & RESP DISORDERS
MAY BE AGGRAVATED BY EXPOS TO PROD. PREEXISTING SKIN/LUNG ALLERGIES MAY INCR
CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOS TO PROD. IMPAIRED
First Aid: EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN WHILE
HOLDING LIDS OPEN. GET MED ATTN. SKIN: IMMED REMOVE CONTAMD CLTHG/SHOES. WIPE
EXCESS FROM SKIN & FLUSH W/PLENTY OF WATER FOR AT LEAST 15 M IN. USE SOAP
IF AVAIL OR FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE CLTHG UNTIL
THORO CLEANED. GET MED ATTN. CONTAMD LEATHER ARTICLES, INCL SHOES, CANNOT BE
DECONTAMD & SHOULD BE DESTROYED
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Handling and Disposal
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Spill Release Procedures: MAY BURN ALTHOUGH NOT READILY IGNIT. USE CAUTIOUS
JUDGMENT WHEN CLEANING UP LG SPILLS. LG SPILLS:WEAR NIOSH/MSHA APPRVD RESP
& PROT CLTHG AS APPROP. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE
& CO NTAIN. REMOVE W/VACUUM TRUCKS OR PUMP TO
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY PLACE WITH ADEQUATE
VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES.
Other Precautions: HEATING THIS CURING AGENT IN PRESENCE OF AIR MAY CAUSE
THERMAL & OXIDATIVE DECOMP W/SOME EPOXY RESINS. IT MAY PRDCE EXOTHERMIC
RXNS WHICH IN LG MASSES CAN CAUSE RUNAWAY POLYM & CHARRING OF REACTANTS.
FUMES & VAPS FROM THESE THERMAL
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: >230F,>110C
Extinguishing Media: USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR CARBON
DIOXIDE.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). MATERIAL WILL NOT BURN UNLESS PREHEATED. COOL FIRE EXPOSED
CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard: RAPID & HAZ POLYM MAY OCCUR UNDER FIRE
CNDTNS. CNTNRS EXPOS TO INTENSE HEAT FROM FIRES SHOULD BE COOLED W/WATER TO
PVNT VAP PRESS BUILDUP WHICH COULD (SUPDAT)
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Control Measures
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Respiratory Protection: AVOID BRTHG VAPORS/MISTS. IF EXPOS MAY OR DOES EXCEED
OCCUP EXPOS LIMITS, USE NIOSH/MSHA APPRVD RESP TO PVNT OVEREXP. IN ACCORD
W/29 CFR 1910.134 USE EITHER FULL-FACE, ATMOSPHERE-SUPPLYING RESP OR AIR
-PURIFYING RESP FOR ORGANIC VAPORS.
Ventilation: USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS.
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: AVOID CONTACT W/EYES, SKIN & CLTHG. WEAR PROT
CLTHG. EYE WASH FOUNTAINS & SAFETY SHOWERS SHOULD BE AVAIL FOR EMER USE.
Work Hygienic Practices: WASH W/SOAP & WATER BEFORE EATING, DRINKING, SMKNG,
APPLYING COSMETICS OR USING TOILET FACILITIES. LAUNDER
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). EXPLO HAZ: RSLT IN CNTNR RUPTURE. CNTNR AREAS
EXPOS TO DIRECT FLAME CNTCT SHOULD BE COOLED W/LG QTYS OF WATER AS NEEDED TO
PVNT WEAKENING OF CNTNR STRUCTURE. DELAYED LUNG DMG (PULM EDEMA) CAN BE
EXPERIENCED AFTER EXPOS TO COMBUST
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Physical/Chemical Properties
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Solubility in Water: SLIGHT
Appearance and Odor: BROWN LIQUID.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID HEAT AND FLAME.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS SUCH AS
PEROXIDES. AVOID IRON, RUST & OXYGEN DEFICIENT ATMOSPHERES.
Hazardous Decomposition Products: NITROGEN OXIDES, CARBON MONOXIDE &
UNIDENTIFIED ORG CMPDS MAY BE FORMED DURING THERMAL OR OXIDATIVE DECOMP OR
COMBUST.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: AVOID HEAT, FLAME & CNTCT W/STRONG
OXIDIZING AGENTS SUCH AS PEROXIDES. AVOID IRON, RUST & OXYGEN DEFICIENT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: EPI-CURE CURING AGENT 9470
Assigned IND: Y
Company: SHELL OIL CO
PO Box: 4320
City: HOUSTON TX
Zipcode: 77210-5000
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 05/18/1995
Status Code: C
Label Date: 05/18/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: COMBUSTIBLE. EXOTHERMIC REACTIONS IN LARGE MASSES.
ACUTE: EYES: MAY BE SEVERELY IRRITATING. SKIN: MAY BE SEVERELY IRRITATING.
MAY CAUSE SENSITIZATION WITH RASHES, ESPECIALLY HIVES. MAY BE TOXIC IF ABS
ORBED THROUGH THE SKIN. INHALATION: MAYCAUSE IRRITATION TO NSOE, THROAT &
RESPIRATORY TRACT. MAY CAUSE RESPIRATORY TRACT SENSITIZATION EVIDENCED BY
WHEEZING WITH SHORTNESS OF BREATH AND COUGH. INGEST ION: MAY BE TOXIC IF
SWALLOWED. CHRONIC: DIETHYLTOLUENEDIAMINE HAS CAUSED CANCER AND PANCREATIC
TOXICITY IN LAB ANIMALS. ANIMAL STUDIES ALSO SHOW EFFECTS TO LIVER, THYROID,
PITUITARY, SPLEEN, KIDNEY, BONE MARROW, LYMPH SYSTEM.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.