LABCHEM INC -- ACETIC ACID SOLUTION, 0.1%-50% V/V, LC10150
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Material Safety Data Sheet
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MSDS Num: BYWZS
MSDS NAME: ACETIC ACID SOLUTION, 0.1%-50% V/V, LC10150
Responsible Party
Name: LABCHEM INC
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Info Phone: 412-826-5230
Emergency Phone Number: 412-826-5230
Preparer's Name: AL BERANEK
Published: Y
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Contractor Summary
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Name: LABCHEM INC
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Phone: 412-826-5230
Name: LABCHEM, INC.
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Phone: 412-826-5230
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Ingredients
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Cas: 64-19-7
RTECS #: AF1225000
Name: ACETIC ACID; (ACETIC ACID SOLUTIONS, 0.1-50% V/V) (CERCLA)
% Wt: 80.05
OSHA PEL: 10 PPM
ACGIH TLV: 10 PPM; 15 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: 18
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Name: SUPDAT: AZIDOTETRAZOLE, PHOSPHOROUS ISOCYANATE, POTASSIUM HYDROXIDE,
HYDROGEN PEROXIDE, ACETIC ANHYDRIDE.
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Name: EFTS OF OVEREXP: EROSION, TOOTH DISCOLORIZATION, JAW NECROSIS, NASAL
ULCERATION, LARYNGITIS, BRONCH, PNEUM &
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Name: ING 4: GASTROINTESTINAL DISTURBS CAN OCCUR. EYE CONJUNCTIVITIS FROM
PROLONGED EXPOSURE MAY OCCUR.
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Name: FIRST AID PROC: OCCAS (AT LEAST 15-20 MIN) UNTIL NO EVID OF CHEM REMAINS.
FOR BURNS, APPLY STERILE NON-MEDICATED
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Name: ING 6: BANDAGE LOOSELY. GET MEDICAL AID AT ONCE. INGEST: GIVE CONSCIOUS
VICTIM LARGE QTYS OF WATER (TO DILUTE
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Name: ING 7: ACID). DO NOT INDUCE VOMITING. GET MEDICAL AID AT ONCE.
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Name: EYE PROT: AND FULL LENGTH FACESHIELD (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL, RAT) 3310 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EXPOS TO 50PPM INTOLERABLE TO MOST INDIVIDUALS.
RESP IRRIT, COUGH, CHOKING, HDCH, DIZZ, WEAK CAN OCCUR. DELAYED SYMPS INCL
LUNG FLUID, CHEST PAINS, FROTHY SPUTUM, CYANOSIS, RALES & HYPOTENSION.
SKIN CNTCT MAY RSLT IN IRRIT, PAIN, BURNS, BLISTERS & BROWN/YELLOW
STAINS. EYE CNTCT MAY RSLT IN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: SWELL, IRRIT, DMG TO CORNEA
& CONJ RSLTG IN BLURRED/PARTIAL LOSS OF VISION. INGEST MAY RSLT IN SEV
BURNS OF MOUTH, THROAT & STOM; VOMIT & DIARR OF DARK BLOOD. ASPHYXIA
FROM THROAT SWELL CAN OCCUR, PERFORATIONS OF ESOPHAGUS & STOMCAN OCCUR.
CHRONIC: HAZS: SENSIT DERM FROM PRLNG EXPOS CAN OCCUR. DENTAL
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL: MOVE TO FRESH AIR, GIVE ARTF RESP IF NEC. MAINTAIN AIRWAY,
GIVE OXYGEN (MED TRAINED ONLY), MAINTAIN BLOOD PRESS. GET MED AID IMMED.
SKIN: REMOVE CONTAMD CLTHG. WASH W/SOAP & WATER, FLUSH W/LG A MTS OF
WATER (15-20 MIN) UNTIL NO EVID OF CHEM REMAINS. FOR BURNS, APPLY STERILE
BANDAGE (SECURE NOT TIGHT). GET MED AID IMMED. EYES: WASH EYES W/LG AMTS OF
WATER, LIFTING UPPER/LOWER LIDS
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Handling and Disposal
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Spill Release Procedures: ABSORB LIQ W/INERT OR NEUT SUBSTANCE SUCH AS FULLER'S
EARTH, CEMENT PWDR, FLY ASH, SAND. SCOOP MATL INTO SUITABLE (PLASTIC/GLASS)
CNTNR, LABEL FOR DISP. CAUSTIC SODA MAY BE USED TO NEUT. SHUT OFF IGNI T
SOURCE, AVOID VAPS. ISOLATE, VENT SPILL AREA.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
LAWS.
Handling And Storage Precautions: STORE IN ACID CONTAINMENT AREA, PROTECTED
FROM HEAT & IGNITION SOURCES. KEEP AWAY FROM OXIDIZERS, OTHER
INCOMPATIBLE MATERIALS.
Other Precautions: VAPORS HEAVIER THAN AIR. USE ADEQUATE VENTILATION. KEEP OUT
OF SEWERS AND DRAINS.
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Fire and Explosion Hazard Information
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Flash Point Text: >102F,>39C
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP
N). FLAMM CLASS II FOR GLACIAL ACETIC ACID. MOVE CNTNR IF POSS; COOL W/WATER.
AVOID BRTHG CORR VAPS, (SUPDAT)
Unusual Fire/Explosion Hazard: UNKNOWN FIRE AND EXPLOSION HAZARD AT LOWER
CONCENTRATIONS.
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Control Measures
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Respiratory Protection: >100PPM - NIOSH/MSHA APPRVD SCBAF:PD,PP;
SAF:PD,PP,CF. 500PPM - NIOSH/MSHA APPRVD CCROVF/GMOV/SAF/SCBAF. 1000PPM -
NIOSH/MSHA APPRVD SAF:PD,PP,CF. ESCAPE - NIOSH/MSHA APPRVD GMOV/SCBA. (RESP
CODES: DH EW (NIOSH) PUB NO 78-210).
Ventilation: PROVIDE LOCAL EXHAUST VENTILATION TO MEET PERMISSABLE EXPOSURE
LIMITS (PEL).
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: ANSI APPROVED EMERGENCY EYE WASH FOUNTAIN & DELUGE
SHOWER (FP N). WEAR CLOTHING IMPERVIOUS TO ACID.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRE FIGHT PROC: KNOCK DOWN W/WATER SPRAY. VAPS
HVR/AIR, MAY TRAVEL CONSIDERABLE DIST & FLASH BACK FROM SOURCE OF IGNIT.
KEEP OUT OF SEWERS & DRAINS. MATL TO AVOID: CARBINOL & OZONE, NITRIC
ACID, NITR IC ACID & ACETONE, PERCHLORIC ACID, PERMANGANATES, PHOSPHOROUS
TRICHLORIDE, SODIUM PEROXIDE, N-XYLENE,
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Physical/Chemical Properties
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B.P. Text: >212F,>100C
M.P/F.P Text: >32F,>0C
Vapor Pres: 11-14 @20C
Vapor Density: 0.7-2.1
Spec Gravity: 1.0-1.4
PH: ACID
Solubility in Water: MISCIBLE
Appearance and Odor: COLORLESS LIQUID WITH MILD TO PUNGENT VINEGAR-LIKE ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: DANGEROUS IN CONTACT WITH OXIDIZERS. ATTACKS MOST
METALS, INCLUDING STAINLESS STEEL AND ZINC.
Materials To Avoid: EXPLO/VIOLENT RXNS W/BROMINE PENTAFLUORIDE, CHLORINE
TRIFLUORIDE, CHROMIC ACID OR ANHYDRIDE, DIALLYL METHYL (SUPDAT)
Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY RELEASE TOXIC
OXIDES OF CARBON.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: ACETIC ACID SOLUTION, 0.1%-50% V/V, LC10150
Assigned IND: Y
Company: LABCHEM INC
Street: 200 WILLIAM PITT WAY
City: PITTSBURGH PA
Zipcode: 15238
Health Emergency Phone: 412-826-5230
Label Required IND: Y
Date Of Label Review: 09/11/1995
Status Code: C
Label Date: 09/11/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: INHAL: RESPIRATORY IRRIT, COUGHING,
CHOKING, HEADACHE, DIZZINESS, WEAKNESS. DELAYED SYMPS INCL LUNG FLUID, CHEST
PAINS, FROTHY SPUTUM, CYANOSIS, RALES & HYPOTENSION. SKIN: IRRIT, P AIN,
BURNS, BLISTERS & BROWN/YELLOW SKIN. EYES: SWELLING, IRRIT, DMG TO CORNEA
& CONJUNCTIVA WITH BLURRED/PARTIAL LOSS OF VISION. INGEST: SEV BURNS OF
MOUTH, THROAT & STOMACH, VOMIT & DIARRHEA OF DARK BLOOD. ASPHYXIA
FROM THROAT SWELLING, PERFORATIONS OF ESOPHAGUS & STOMACH. CHRONIC:
SENSITIZATION DERMATITIS. DENTAL EROSION, TOOTH DISCOLORATION, JAW NECROSIS,
NASAL ULCERATION, LARYNGITIS, BRONCHIT IS, PNEUMONIA & GI DISTURBS, EYE
CONJUNCTIVITIS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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