LCI (LUCIER CHEMICAL INDUSTRIE -- SODIUM FLUOROSILICATE
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Material Safety Data Sheet
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NIIN: 00-978-7201
MSDS Num: BZPJM
MSDS NAME: SODIUM FLUOROSILICATE
Responsible Party
Name: LCI (LUCIER CHEMICAL INDUSTRIES) LTD
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Info Phone: 904-241-1200
Emergency Phone Number: 904-241-1200
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Item Description Information
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Item Manager: S9G
Item Name: SODIUM SILICOFLUORIDE,TECHNICAL
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: DR
Quantitative Expression: 00000000125LB
UI Container Qty: 0
Type of Container: DRUM
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Ingredients
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Cas: 16893-85-9
RTECS #: VV8410000
Name: SODIUM FLUOROSILICATE
% Wt: 99
OSHA PEL: 2.5 MG/M3 AS F
ACGIH TLV: 2.5 MG/M3 AS F
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Name: WATER
% Wt: 0.5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Name: NAFHF
% Wt: 0.50
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL, RAT) IS 125 MG/KG.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: FLUORIDE DUST MAY CAUSE IRRITATION TO EYES AND
RESPIRATORY TRACT. SWALLOWING FLUORIDE DUST MAY CAUSE NAUSEA, VOMITING,
ABDOMINAL PAIN OR BURNING, DIARRHEA, SHORTNESS OF BREATH, DIFFICULTY IN SP
EAKING, THIRST, WEAKNESS OF PULSE, DISTURBED COLOR VISION, MUSCULAR WEAKNESS,
CONVULSIONS, LOSS OF CONSCIOUSNESS AND DEATH. KIDNEY INJURY AND BLEEDING FROM
INJURY MAY OCCUR. CHRONIC: REPEATED EXPOSUR E ABOVE PEL OR TLV TO FLUORIDE
DUST MAY CAUSE EXCESSIVE CALCIFICATION OF LIGAMENTS OF THE RIBS, PELVIS AND
SPINAL COLUMN. SOLEROSIS OF CHANGES OF BONES AND LIGAMENTS CAN BE SEEN BY
X-RAY. ENZYME SYSTE M EFFECTS AND (CONTD. SEE TOXICOLOGICAL)
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: ACUTE: IRRITATION, NAUSEA, VOMITING,
ABDOMINAL PAIN OR BURNING, DERMATITIS, DIARRHEA, WEAKNESS OF PULSE, SHORTNESS
OF BREATH, DIFFICULTY SPEAKING, THIRST, DISTURBED COLOR VISION, MUSCULAR
WEAKNESS. CO NVULSIONS. LOSS OF CONSCIOUSNESS, DEATH. CHRONIC: EXCESSIVE
CALCIFICATION OF LIGAMENTS OF RIBS, PELVIS, SPINAL COLUMN, SCLEROSIS OF
CHANGES OF BONES AND LIGAMENTS CAN BE SEEN BY X-RAY. ENZYME SYSTEM A ND
PULMONARY FIBROSIS ARE REPORTED. STIFFNESS AND LIMITATION OF MOTIONS MAY
RESULT. EYE, SKIN AND MUCOUS MEMBRANE IRRITATION, LOSS OF WEIGHT, ANOXEXIA,
ANEMIA, WASTING, CACHEXIA, AND DENTAL DEFECTS. S KIN RASH.
Medical Cond Aggravated By Exposure: PRE-EXISTING RESPIRATORY DISEASES
INCLUDING ASTHMA AND EMPHYSEMA.
First Aid: INHALTION: IF PERSON BREATHES CHEMICAL DUST, MOVE TO FRESH AIR. IF
NOT BREATHING, PERFORM ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULT,
ADMINISTER OXYGEN BY AUTHORIZED INDIVIDUAL. KEEP VICTIM WARM A ND AT REST.
GET PROMPT MEDICAL ATTENTION. EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER,
LIFTING UPPER AND LOWER LIDS AT PERIODIC INTERVALS. GET MEDICAL ATTENTION.
SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER.
GET MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER.
DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF MILK FOR ITS SOOTHING EFFECT.
GET MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: EMPLOYEES SHOULD BE TRAINED IN SAFETY PROCEDURES FOR
STORAGE AND HANDLING THIS PRODUCT. WEAR NIOSH APPROVED PROTECTIVE CLOTHING
AND BREATHING APPARATUS. ISOLATE PRODUCT SPILL AREA. CAREFULLY SHOVEL M
ATERIAL AND PLACE IN CLEAN, DRY CONTAINER AND COVER. REMOVE CONTAINER FROM
SPILL SITE AND DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. CONTACT CHEMTREC AT 1-800-424-9300.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL
REGULATIONS. CONTACT CHEMTREC AT 1-800-424-9300 FOR 24 HOUR EMERGENCY
ASSISTANCE. HAZARDOUS WASTE NUMBER: NOT LISTED.
Handling And Storage Precautions: STORAGE: STORE IN COOL, DRY, VENTILATED PLACE
AWAY FROM ACIDS. HANDLING: USE ONLY WITH ADEQUATE VENTILATION, DUST MASK OR
SELF-CONTAINED BREATHING APPARATUS. PROTECTIVE CLOTHING SHOULD ALWAYS BE
WORN. KEEP CONTAINER CLOSED WHEN NOT IN USE. AVOID BREATHING DUST OR MIST.
AVOID CREATING DUST.
Other Precautions: DO NOT GET IN EYES, ON SKIN OR CLOTHING. WASH OFF WITH
WATER. AVOID INHALATION OF DUST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH
OF CHILDREN. OBEY HAZARD WARNING LABEL. FOR LABORATORY USE ONLY. KEEP
SEPERATED FROM STRONG ACIDS AND ALKALIS.
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Fire and Explosion Hazard Information
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Flash Point Text: NON-FLAMMABLE
Extinguishing Media: THIS CHEMICAL IS NOT FLAMMABLE, BUT FOR FIRES IN AREA
WHERE THIS CHEMICAL IS STORED, USE FOAM, DRY CHEMICALS, OR CARBON DIOXIDE.
Fire Fighting Procedures: WHEN THIS PRODUCT IS HEATED TO DECOMPOSITION (550C),
IT WILL GENERATE HIGHLY TOXIC GASES SUCH AS HYDROGEN FLUORIDE.
Unusual Fire/Explosion Hazard: EXTREME TEMPERATURES, SUCH AS FIRES, WILL CAUSE
DECOMPOSITION AND FORMATION OF FLUORINE. FIREFIGHTERS SHOULD AVOID ALL BODILY
CONTACT, WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARA
TUS.
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Control Measures
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Respiratory Protection: A NIOSH APPROVED RESPIRATOR SHOULD BE WORN.
SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED WHEN CHEMICAL IS HEATED TO
DECOMPOSITION OR IN A SPILL AREA.
Ventilation: ADEQUATE VENTILATION TO MAINTAIN FLUORIDE CONCENTRATIONS BELOW
APPLICABLE STANDARDS
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: SPLASH-PROOF GOGGLES AND 8-INCH FACE SHIELD IF DANGER OF
SPLASHING.
Other Protective Equipment: PROTECTIVE IMPERVIOUS CLOTHING SHOULD BE WORN IN
PRESENCE TO PREVENT CONTACT WITH SKIN (COVERALLS, BOOTS, ETC).
Work Hygienic Practices: PROTECT OPEN WOUNDS. HEATING TO DECOMPOSITION REQUIRES
FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS.
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Physical/Chemical Properties
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HCC: T4
NRC/State LIC No: NOT RELEVANT
Boiling Point: =500.C, 932.F
B.P. Text: DECOMPOSES @ 500C.
Melt/Freeze Pt: =500.C, 932.F
M.P/F.P Text: DECOMPOSES
Decomp Temp: =500.C, 932.F
Spec Gravity: 2.679 (BULK= 90 LBS/FT3)
PH: 3.1
Solubility in Water: 0.76 G/100ML H20@25C
Appearance and Odor: SOLID, GRANULES. WHITE, ODORLESS, GRANULAR, CRYSTALLINE
MATERIAL.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH STRONG ACIDS AND ALKALIS, SUCH
CONTACT WILL CAUSE FORMATION OF HYDROGEN FLUORIDE GAS.
Materials To Avoid: STRONG ACIDS, STRONG BASES SUCH CONTACT WILLCAUSE FORMATION
OF HYDROGEN FLUROIDE GAS.
Hazardous Decomposition Products: TEMPERATURES ABOVE 500C, SUCH AS FIRES, WILL
CAUSE DECOMPOSITION AND FORMATION OF HYDROFLUORIC ACID AND FLUORINE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: (CONTD FROM HEALTH HAZARDS, CHRONIC) PULMONARY
FIBROSIS ARE REPORTED. STIFFNESS AND LIMITATION OF MOTIONS MAY RESULT. COMMON
FINDINGS ARE EYES, SKIN, AND MUCOUS MEMBRANE IRRITATION, LOSS OF WEIGHT, AN
OREXIA, WASTING, CACHEXIA, AND DENTAL DEFECTS. REPEATED OR PROLONGED EXPOSURE
TO THE SKIN MAY CAUSE SKIN RASH.
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Ecological Information
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MSDS Transport Information
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Transport Information: DOT PROPER SHIPPING NAME: SODIUM FLUOROSILICATE; PACKING
GROUP: I I I; HAZARD CLASS: 6.1 (POISON); SUBSIDERARY HAZARD CLASS: N/A; UN
2674; REPORTABLE QUANTITY: N/A; PLACARDING REQUIREMENT: KEEP AWAY FROM FOOD;
IMDG PLACARDING REQUIREMENT: TOXIC. FOR INTERNATIONAL TRANSPORTATION, SODIUM
FLUOROSILICATE IS REGULATED BY INTERNATIONAL MARITIME ORGANIZATION (IMO) AND
INTERNATIONAL AIR TRANSPORT ASSOCIA TION (IATA) FOR VESSEL AND AIR MOVEMENT
AS CLASS 6.1 TOXIC, NOT MARKED AS MARINE POLLUTANT, (IMDG PG. 6250).
PACKING, MARKING, LABELING, SHIPPING PAPER DESCRIPTIONS MUST PRECISELY
REFLECT THE REGULAT ION FOR EXPORT MOVEMENT.
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Regulatory Information
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Sara Title III Information: NOT LISTED. NO RQ.
Federal Regulatory Information: RCRA STATUS OF UNUSED MATERIAL IF DISCARDED:
NOT LISTED. HAZARDOUS WASTE NUMBER: NOT LISTED. WASTE DISPOSAL METHOD:
DISPOSER MUST COMPLY WITH FEDERAL, STATE, AND LOCAL DISPOSAL OR DISCHARGE
LAWS. EPA HAZARDOUS SUBSTANCE: NO. TOXIC SUBSTANCES CONTROL ACT INVENTORY OF
SUBSTANCES (TSCA): YES, LISTED.I
State Regulatory Information: NEW JERSEY "RIGHT TO KNOW" LAWS: LISTED.
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Other Information
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Other Information: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (W): YES,
LISTED.
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Transportation Information
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Trans ID NO: 96163
MSDS NAME: SODIUM FLUOROSILICATE
MSDS Prepared Date: 03/01/1999
Review Date: 11/30/2000
Net Unit Weight: 125 LBS
Multiple KIT Number: 0
Unit Of Issue: DR
Container QTY: 0
Type Of Container: DRUM
Additional Data: TRANSPORTATION DATA PER MANUFACTURER'S MSDS.
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Detail DOT Information
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DOT PSN Code: NFM
DOT Proper Shipping Name: SODIUM FLUOROSILICATE
Hazard Class: 6.1
UN ID Num: UN2674
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Packaging Exception: 153
Non Bulk Pack: 213
Bulk Pack: 240
Max Qty Pass: 100 KG
Max Qty Cargo: 200 KG
Vessel Stow Req: A
Water/Ship/Other Req: 26
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Detail IMO Information
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IMO PSN Code: NWX
IMO Proper Shipping Name: SODIUM SILICOFLUORIDE
IMDG Page Number: SEE 6250
UN Number: 2674
UN Hazard Class: 6.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 6.1-04
MED First Aid Guide NUM: 750
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Detail IATA Information
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IATA PSN Code: WQL
IATA UN ID Num: 2674
IATA Proper Shipping Name: SODIUM FLUOROSILICATE
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 619
Max Quant Pass: 100KG
Max Quant Cargo: 200KG
Packaging Note Cargo: 619
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Detail AFI Information
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AFI PSN Code: WQL
AFI Proper Shipping Name: SODIUM FLUOROSILICATE
AFI Hazard Class: 6.1
AFI UN ID NUM: UN2674
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A10.6
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HAZCOM Label
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MSDS NAME: SODIUM FLUOROSILICATE
Company: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Street: 415 PABLO AVE N
PO Box: 49000
City: JACKSONVILLE BEACH FL
Zipcode: 32240-9000
Health Emergency Phone: 904-241-1200
Label Required IND: Y
Date Of Label Review: 11/30/2000
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 11/30/2000
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS:EYE, SKIN, RESPIRATORY, GI TRACTS. ACUTE:
FLUORIDE DUST MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT. SWALLOWING
MAY CAUSE ABDOMINAL PAIN/BURNING. CHRONIC: SKIN RASH, PULMONARY FIB ROSIS.
STORE AWAY FROM INCOMPATIBLES. SWEEP UP AND PLACE IN SUITABLE CONTAINER FOR
DISPOSAL. FIRST AID: GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO
FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. E YES:FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP ANDWATER. ORAL:IF CONSCIOUS,
DRINK SEVERAL GLASSES OF MILK (CALCIUM) OR LARGE AMOUNT OF WATER. GET MEDICAL
ATTENTION IMMEDIA TELY. DO NOT INDUCE VOMITING.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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