LUCAS-MILHAUPT INC -- SILVER-COPPER-NICKEL-ZINC BRAZING ALLOYS, BRA
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Material Safety Data Sheet
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NIIN: 01-388-4564
MSDS Num: BZNXD
MSDS NAME: SILVER-COPPER-NICKEL-ZINC BRAZING ALLOYS, BRAZE 403
Responsible Party
Name: LUCAS-MILHAUPT INC
Address: 5656 S PENNSYLVANIA AVE
City: CUDAHY WI 53110-2453
Info Phone: 800-558-6003 JIM BACH/414-769-6000
Emergency Phone Number: 800-424-9300(CHEMTREC)
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Address: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI 53110
Phone: 414-769-6000
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Item Description Information
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Item Manager: S9G
Specification Number: UNKNOWN
Unit of Issue: CL
Quantitative Expression: 00000000016OZ
UI Container Qty: 0
Type of Container: COIL, WIRE
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Ingredients
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Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER (SARA 313) (CERCLA)
% Wt: 20-54
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 0.1MG/M3 FUME/1 DUST
ACGIH TLV: 0.2 MG/M3 FUME; 9596
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7440-02-0
RTECS #: QR5950000
Name: NICKEL (SARA 313) (CERCLA)
% Wt: 1-5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3; 9596
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Cas: 7440-22-4
RTECS #: VW3500000
Name: SILVER (SARA 313) (CERCLA)
% Wt: 1.5-54
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 0.01 MG/M3
ACGIH TLV: 0.1 MG/M3; 9596
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 7440-66-6
RTECS #: ZG8600000
Name: ZINC (SARA 313) (CERCLA)
% Wt: 5-44
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: UNKNOWN
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: INHAL OF COMPONENTS/RX BYPROD DOES NOT POSE SIGNIFICANT
RISK TO HEALTH WHEN USED ACCORDING TO INSTRUCTIONS & W/APPROPRIATE PROT
MEASURES.AG:CHRONIC EXPO-ARGYRIA.CU:ACUTE EXPO-RESP TRACT IRRIT,FEVER,MU SCLE
ACHE,CHILLS,COUGH,WEAK,METALLIC TASTE.CHRONIC EXPO-DMG TO
LIVER,KIDNEY,SPLEEN,PANCREAS,BRAIN.NI:ACUTE-HEAD(SUPPLEM)
Explanation Of Carcinogenicity: PER MSDS:NI CLASSIFIED AS POT HUMAN CARC BY
IARC/NIOSH/NTP.AG/CU/ZN NOT CLASSIFIED AS POT/DEMO HUMAN CARC.
Signs And Symptions Of Overexposure: SKIN:CONTACT W/SOLID NOT KNOWN TO BE
HAZ.FINELY-DIVIDED PROD LOC IRRIT,DISCOLOR,ARGYRIA,ALLERGIC
DERM.EYE:FINELY-DIVIDED PROD LOC ARGYRIA,IRRIT,CONJ,ULCERATION OF
CORNEA.INGEST:FINELY-DIVIDED PROD GAS TRIC IRRIT,VOMIT,ABD
PAIN,HEMORR,DIARR.DMG TO LIVER,KIDNEY,SPLEEN,PANCREAS,MUSCULOSKELETAL
SYS,BLOOD-FORM ORGANS,CNS.
Medical Cond Aggravated By Exposure: PRE-EXIST PULM
DISEASES(BRONCHITIS,EMPHYSEMA)MAY BE AGGRAVATED BY INHAL EXPO,PARTICULARLY AS
FUME.NI EXPO BY INHAL/INGEST MAY AGGRAVATE PRE-EXISTING DISEASES OF
KIDNEY/HEMATOPOETIC SYS,CNS,MUSCULSKELE
First Aid: INHAL:SIGNS/SYMPTOMS OF TOXICITY OBSERVED REMOVE FROM AREA.ADMIN
OXY.SEEK MED ATTN.KEEP SUBJ WARM/@REST.BREATH STOP PERFORM ART RESP.
SKIN:REMOVE CONTAMIN CLOTH.WASH AREA W/LG QUANT OF WATER FOR @LEAS T
5MINS.SEEK MED ATTN IF NECESSARY. EYE:FLUSH AREA W/WATER FOR @LEAST
15MINS.SEEK MED ASSIST IF NECESSARY. INGEST:IF CONSC INDUCE
VOMIT.UNCONSC/CONVULSIVE SEEK IMMED MED ASSIST.
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Handling and Disposal
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Spill Release Procedures: CLEAN UP SPILLED MATL SO AS TO MINIMIZE DISPERSION OF
DUST.WET SWEEPING OR VACUUMING USING HEPA FILTRATION ARE RECOMMENDE METHODS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: RETURN TO MFG FOR RECLAIM.CONTAINS SARA TITLE III SEC
313 REPORTING
CHEMS:CU(20.0-54.0),NI(1.0-5.0),AG(1.5-54.0),ZN(5.0-44.0).RQ:AG(1000LBS),NI(1
LB),CU(5000LBS),ZN(1000LBS).NI TPQ=10000LBS.
Handling And Storage Precautions: DO NOT STORE IN PROXIMITY TO INCOMP MATLS.
Other Precautions: INCOMP MATL:AZIDES,ETHANOL,ETHYLENE IMINE,CLF3,INORG/ORG
PEROXIDES,PEROXYFORMIC ACID,CL2/FL2,PERMONOSULFURIC ACID,CRO3,MN/CA
CHLORIDES,CS2,HYDRAZINE MONOMITRATE,NITROBENZENE,FE(CO)5,SELENINYL BROMIDE.
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Fire and Explosion Hazard Information
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Extinguishing Media: USE DRY POWDER. DO NOT USE WATER.
Fire Fighting Procedures: USE SELF-CONTAINED BREATHING APPARATUS
W/FULL-FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard: FINELY-DIVIDED FORM MATL MAY IGNITE WHEN EXP TO
FLAME/RX W/INCOMPATIBLE MATLS.FIRE/EXPLO INVOLVING THESE MATLS MAY RELASED
POT TOXIC EMISSIONS OF METAL/(SUPPLE)
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Control Measures
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Respiratory Protection: IF EXPO LEVEL EXCEEDS OSHA PEL WEAR NIOSH/MSHA APPROVED
RESP HAVING CONFIGURATION(CLASS,TYP OF FCPIECE,FIL MEDIA,ASSIGN PROT
FACTOR,ETC)APPROPRIATE TO CONCEN FO CONTAMIN GENERATED.SELECTION GUIDANCE/P
ROPER USE SEE ANSI Z99.2-1992.
Ventilation: USE MECH LOC EXHAU VENTI ADEQUATE TO MAINTAIN AIRBORNE CONCEN OF
ALL COMPONENTS/THEIR DECOMP PROD TO W/IN RESPECTIVE PEL
Protective Gloves: APPROPRIATE PROTECTIVE GLOVES.
Eye Protection: SAF GLASS,DUST-PROOF GOGG,(SEE OTH PROT)
Other Protective Equipment: EYE:PLASTIC-FRAME SPECTACLES W/SIDESHIELDS/FIL
LENSE(SHADE#3/#4).APPROP PROT CLOTH.AVOID FLAMM FABRICS.
Work Hygienic Practices: WASH CONTAMIN CLOTH BEF REUSE.TO AVOID MATL INGEST
WASH HANDS/FACE BEF EAT/DRINK/CONSUMPTION OF TOBACCO.
Supplemental Safety and Health: FIRE/EXPLO:METAL OXIDE FUMES. HEALTH
HAZ:NAU,VERTIGO,ASTHMA,PULM FIBROSIS,PULM EDEMA.CHRONIC-INCR CANCER RISK TO
NASOPHARYGIAL REGION,LUNGS,PROSTATE,KIDNEY.ZN:ACUTE-RESP TRACT IRRIT,METAL
FUME FEVER.
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Physical/Chemical Properties
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HCC: N1
M.P/F.P Text: >1220F,>660
Solubility in Water: INSOLUBLE
Appearance and Odor: NO ODOR,WHITE TO LIGHT YELLOW
METALS,FORM:WIRE,ROD,STRIP,POWDER,GRAIN,PREF SHAP
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AG/CU FORM EXPLO ACETYLIDES UPON CONTACT W/UNCOMB
ACETYLEN.STRONG OXIDIZERS,SE,TE,MG,CHLORATES,NH3,HNO3,(OTHER PRECAUT)
Hazardous Decomposition Products: HEATING TO ELEVATED TEMPS MAY LIBERATE
METAL/METAL OXIDE FUME.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 132866
MSDS NAME: SILVER-COPPER-NICKEL-ZINC BRAZING ALLOYS, BRAZE 403
MSDS Prepared Date: 05/17/1995
Review Date: 07/03/1996
Net Unit Weight: 5 TROY OZ
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CL
Container QTY: 0
Type Of Container: COIL, WIRE
Additional Data: PER MSDS:SHIPPING INFO:HAZ CLASS:NOT CONTROLLED BY
DOT,IATA,ICAO,IMO REGS.
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: SILVER-COPPER-NICKEL-ZINC BRAZING ALLOYS, BRAZE 403
Company: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Street: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI
Zipcode: 53110
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 07/03/1996
Status Code: C
Label Date: 07/03/1996
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: INHAL OF COMPONENTS/RX BYPROD DOES NOT POSE SIGNIFICANT
RISK TO HEALTH WHEN USED ACCORDING TO INSTRUCTIONS & W/APPROPRIATE PROT
MEASURES.AG:ARGYRIA.CU:RESP TRACT IRRIT,FEVER,MUSCLE ACHE,CHILLS,COUGH,W
EAK,METALLIC TASTE.DMG TO
LIVER,KIDNEY,SPLEEN,PANCREAS,BRAIN.NI:HEAD,NAU,VERTIGO,ASTHMA,PULM
FIBROSIS,PULM EDEMA.ZN:IRRIT RESP TRACT,METAL FUME
FEVER.1STAID:INHAL:SIGNS/SYMPT REMOVE FRM AREA.GIVE OXY. GET MED ATTN.BREATH
STOP GIVE ART RESP.SKIN:REMOVE CONTAMIN CLOTH.WASH W/LG LOTS OF WATER @LEAST
5MINS.GET MED ATTN IF NECESSARY.EYE:FLUSH W/WATER @LEAST 15MINS.GET MED ATTN
IF NECESSARY.INGEST:CONSC INDUCE VOMIT.UNCONSC/CONVULSIVE GET IMMED MED ATTN
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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