BOUGHT ACCORDING TO SPECIFICAT -- SODIUM HYDROXIDE
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Material Safety Data Sheet
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NIIN: 00-270-8177
MSDS Num: BPBVK
MSDS NAME: SODIUM HYDROXIDE
Responsible Party
Name: BOUGHT ACCORDING TO SPECIFICATION
City: N/P VA 00000
Info Phone: 804-279-4371
Emergency Phone Number: 804-279-3131
Preparer's Name: DGSC-SSH
Review Ind: Y
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Name: MILITARY SPECIFICATIONS PROMULGATED BY MILITARY
Address: DEPTS/AGENCIES UNDER AUTH OF DEF STD
Box: MANUAL
City: 4120 3-M NK 00000
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Contractor Summary
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Name: MILITARY SPECIFICATIONS PROMULGATED BY MILITARY
Address: DEPTS/AGENCIES UNDER AUTH OF DEF STD
Box: MANUAL
City: 4120 3-M NK 00000
Phone: 804-279-4371 DSN 695-4371
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Item Description Information
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Item Manager: GSA
Item Name: SODIUM HYDROXIDE,TECHNICAL
Unit of Issue: CO
Quantitative Expression: 00000000500GM
UI Container Qty: G
Type of Container: CONTAINER
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Ingredients
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Cas: 1310-73-2
RTECS #: WB4900000
Name: SODIUM HYDROXIDE
% Wt: 96 MIN
Other REC Limits: NONE SPECIFIED
OSHA PEL: 2 MG/M3
ACGIH TLV: C 2 MG/M3; 9293
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: ORAL, RAT, LD50 = 500 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES:CORROSIVE,IRRITATION,BURNS,BLINDNESS;
SKIN:CORROSIVE,IRRITATION,BURNS,SCARRING;INHALATION:SEVERE IRRITATION, DAMAGE
OF UPPER RESPIRATORY TRACT. SEVERE PNEUMONITIS MAY OCCUR. INGESTION:
CORROSIVE, BURNING OF MOUTH,THROAT,STOMACH, DEATH.CHRONIC:DERMATITIS,
CORNEAL,NASAL,BRONCHIAL AND GASTRIC ULCERATION, CONJUCTIVITI
Explanation Of Carcinogenicity: PRODUCT CONTAINS NO INGREDIENTS CURRENTLY
CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Signs And Symptions Of Overexposure: IRRITATION TO SEVERE BURNS OF SKIN AND
EYES. , ABDOMINAL PAIN, BLOODY VOMITING AND DIARRHEA., SOAR THOAT, COUGHING
AND DYSPNEA.
Medical Cond Aggravated By Exposure: SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED
RESPIRATORY FUNCTION.
First Aid: EYES:FLUSH WITH WATER FOR AT LEAST 15 MIN. GET IMMED MEDICAL HELP.
SKIN:WASH WITH WATER AND REMOVE CONTAMINATED CLOTHES & SHOES. SEE DOCTOR
IMM. INHALATION:REMOVE TO FRESH AIR. IF NOT BREATHING GIVE C PR. IF BREATHING
IS DIFFICULT, GIVE OXYGEN. GET MEDICAL HELP. INGESTION:DO NOT INDUCE
VOMITING. GIVE WATER/MILK, FOLLOWED BY CITRUS FRUIT JUICE. NOTHING BY MOUTH
IF UNCONSCIOUS.SEE DOCTOR IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: CLEAN UP PERSONNEL REQUIRE PROTECTIVE CLOTHNG &
RESP PROTECTION FROM DUST. SWEEP,SCOOP OR PICK UP SPILLED MATERIAL. AVOID
DUSTNG. TRANSFER WASTE TO A CLOSED CONTAINER FOR DISPOSAL. DO NOT FLUSH TO
THE SEWER. NEUTRALIZE RESIDUE WITH 5% ACETIC ACID.
Neutralizing Agent: 5% ACETIC ACID
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: STORE IN COOL,DRY WELL VENTED LOW FIRE RISK
AREA. PROTECT FROM HEAT,SHOCK,FRICTION. KEEP CONTAINERS CLOSED.
Other Precautions: KEEP AWAY FROM INCOMPATIBLE MATERIALS. ALWAYS ADD THE
CAUSTIC TO WATER WHILE STIRRING;NEVER THE REVERSE.
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Fire and Explosion Hazard Information
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Flash Point Text: NONFLAMMABLE
Extinguishing Media: EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures: FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO
COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard: HOT OR MOLTEN MATERIAL CAN REACT VIOLENTLY WITH
WATER. CAN REACT WITH CERTAIN METALS SUCH AS ALUMINUM TO GENERAL FLAMMABLE
HYDROGEN GAS.
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Control Measures
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Respiratory Protection: IF TLV IS EXCEEDED,A DUST/MIST RESP. WITH CHEM. GOGGLES
MAY BE WORN,IN GENERAL UP TO 10 TIMES TLV. ALTERNATIVELY, USE A SUPPLIED AIR
FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD.
Ventilation: LOCAL EXHAUST TO ELIMINATE MISTS/FUMES/GASES.
Protective Gloves: IMPERVIOUS
Eye Protection: CHEM.SFTY GOGGLES AND/OR FULL FACESHIELD
Other Protective Equipment: IMPERVIOUS PROTECTIVE CLOTHING,INCLUDING BOOTS, LAB
COAT,APRON OR COVERALLS TO PREVENT SKIN CONTACT.EYE WASH&SFTY SHOWER
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. THIS SUBSTANCE IS
CLASSIFIED AS A POISON.
Supplemental Safety and Health: MTLS TO AVOID,CONT'D:CONTACT W.NITROMETHANE
& OTHER SIMILAR NITRO COMPDS CAUSES FORMATION OF SHOCK-SENSITIVE SALTS;
CONTACT W.METALS SUCH AS ALUMINUM,TIN,AND ZINC CAUSES FORMATION OF FLAMMABLE
HYDROGE N GAS. ADDING WATER TO CAUSTIC SOLUTIONGENERATES LARGE AMOUNTS OF
HEAT.
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Physical/Chemical Properties
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HCC: B1
B.P. Text: 2534F,1390C
M.P/F.P Text: 604F,318C
Decomp Text: UNKNOWN
Spec Gravity: 2.13
PH: 14.0
Solubility in Water: APPRECIABLE
Appearance and Odor: WHITE, HYGOSCOPIC PELLETS.
Corrosion Rate: UNKNOWN
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: VERY HYGROSCOPIC.CAN SLOWLY PICK UP MOISTURE FROM
AIR AND REACT WITH CO2 IN AIR TO FORM SODIUM CARBONATE.
Materials To Avoid: ACIDS,FLAMM LIQUIDS AND CHLORINATED ORGANIC COMPDS, ORGANIC
PEROXIDES-SEE SUPPL.
Hazardous Decomposition Products: SODIUM OXIDE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE. WILL NOT OCCUR.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 64516
MSDS NAME: SODIUM HYDROXIDE
MSDS Prepared Date: 10/22/1992
Review Date: 10/22/1992
Net Unit Weight: 500 GRAMS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CO
Container QTY: G
Type Of Container: CONTAINER
Additional Data: REPORTABLE QUANTITY = 1000 POUNDS.
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Detail DOT Information
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DOT PSN Code: NGU
DOT Proper Shipping Name: SODIUM HYDROXIDE, SOLID
Hazard Class: 8
UN ID Num: UN1823
DOT Packaging Group: II
Label: CORROSIVE
Packaging Exception: 154
Non Bulk Pack: 212
Bulk Pack: 240
Max Qty Pass: 15 KG
Max Qty Cargo: 50 KG
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: NSX
IMO Proper Shipping Name: SODIUM HYDROXIDE, SOLID
IMDG Page Number: 8225-1
UN Number: 1823
UN Hazard Class: 8
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 8-06
MED First Aid Guide NUM: 705
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Detail IATA Information
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IATA PSN Code: WSO
IATA UN ID Num: 1823
IATA Proper Shipping Name: SODIUM HYDROXIDE, SOLID
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 814
Max Quant Pass: 15KG
Max Quant Cargo: 50KG
Packaging Note Cargo: 816
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Detail AFI Information
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AFI PSN Code: WSO
AFI Proper Shipping Name: SODIUM HYDROXIDE, SOLID
AFI Hazard Class: 8
AFI UN ID NUM: UN1823
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A12.4
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HAZCOM Label
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MSDS NAME: SODIUM HYDROXIDE
Company: MILITARY SPECIFICATIONS PROMULGATED BY MILITARY
Street: DEPTS/AGENCIES UNDER AUTH OF DEF STD
PO Box: MANUAL
City: 4120 3-M NK
Zipcode: 00000
Health Emergency Phone: 804-279-3131
Label Required IND: Y
Date Of Label Review: 10/22/1992
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 10/22/1992
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Moderate
Hazard And Precautions: EYES:CORROSIVE,IRRITATION,BURNS,BLINDNESS;
SKIN:CORROSIVE,IRRITATION,BURNS,SCARRING;INHALATION:SEVERE IRRITATION, DAMAGE
OF UPPER RESPIRATORY TRACT. INGESTION:CORROSIVE,BURNING OF MOUTH,
THROAT,STOMAC H,DEATH. CHRONIC:DERMATITIS,CORNEAL,NASAL,BRONCHIAL AND GASTRIC
ULCERATION. STORE IN COOL,DRY WELL VENTED AREA. FIRST AID:EYES: FLUSH WITH
WATER FOR AT LEAST 15 MIN. GET MEDICAL HELP. SKIN:WASH WITH W ATER, REMOVE
CONTAMINATED CLOTHES & SHOES. SEE DOCTOR. INHALATION:REMOVE TO FRESH
AIR.IF NOT BREATHING GIVE CPR/OXYGEN. GET MEDICAL HELP. INGESTION: DO NOT
INDUCE VOMITING. GIVE WATER/MILK, FOLLOWED B Y CITRUS FRUIT JUICE. NOTHING BY
MOUTH IF UNCONSCI
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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