| MSDS | : | AQUA AMMONIA | | CAS | : | 1336-21-6 | | NAME | : | ing 4: congestion &, ultimately, death from resp failure due pulm
ing 5: burns of skin & muc memb. hdch, salivation, naus & vomit.
ing 6: discharge. bronchitis, laryngitis, hemoptysis & pulm
ing 7: and corneal and lenticular opacities. damage to the eyes may be
first aid proc: exposed areas of skin & continue for at least 15 min.
ing 9: apply water. do not apply salves/ointments to affected areas.
ing 10: flowing water for at least 15 min w/eyelids held apart. obtain
spill proc: entering streams, drinking water supply or sewers. dike to
ing 12: necessary to reduce ammonia vaporization.
resp prot: from 0-200 ppm, a niosh/msha apprvd cartridge type 1/2 mask
ing 14: niosh/msha apprvd type "n" gas mask w/full facepiece is needed.
vent: lead upwards to outside. local exhaust must be adequate to reduce
other prot equip: broad-brimmed rubber or felt hat. use of protective oil
hygiene pract: work area. wash hands before eating, drinking, or using
ammonium hydroxide; (ammonia) (cercla)
efts of overexp: expos. may cause second-degree burns on long expos.
ing 2: signs & symps of expos: burning of eyes, conjunc, skin irrit,
ing 3: tongue, burning in throat & coughing. in more sev cases of
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HILL BROTHERS CHEMICAL CO -- AQUA AMMONIA
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Material Safety Data Sheet
=======================================================
MSDS Num: CBBGW
MSDS NAME: AQUA AMMONIA
Responsible Party
Name: HILL BROTHERS CHEMICAL CO
Address: 1675 NORTH MAIN ST
City: ORANGE CA 92667
Info Phone: 800-821-7234
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: HILL BROS CHEMICAL CO
Address: 1675 N MAIN ST
City: ORANGE CA 92667
Phone: 714-998-8800
Name: HILL BROTHERS CHEMICAL CO.
Address: 1675 NO. MAIN STREET
Box: NA
City: ORANGE CA 92667
Phone: CHEMTREC 800-424-9300
=======================================================
Ingredients
=======================================================
Name: ING 4: CONGESTION &, ULTIMATELY, DEATH FROM RESP FAILURE DUE PULM
EDEMA MAY OCCUR. EFTS OF OVEREXP: IRRIT & POSS
-----------------------------
Name: ING 5: BURNS OF SKIN & MUC MEMB. HDCH, SALIVATION, NAUS & VOMIT.
DFCLT/LABORED BRTHG & COUGH W/BLOODY MUCOUS
-----------------------------
Name: ING 6: DISCHARGE. BRONCHITIS, LARYNGITIS, HEMOPTYSIS & PULM
EDEMA/PNEUMIT. ULCERATION OF CONJUNCTIVA & CORNEA,
-----------------------------
Name: ING 7: AND CORNEAL AND LENTICULAR OPACITIES. DAMAGE TO THE EYES MAY BE
PERMANENT.
-----------------------------
Name: FIRST AID PROC: EXPOSED AREAS OF SKIN & CONTINUE FOR AT LEAST 15 MIN.
REMOVE CONTAM CLTHG WHILE CONTINUING TO
-----------------------------
Name: ING 9: APPLY WATER. DO NOT APPLY SALVES/OINTMENTS TO AFFECTED AREAS.
OBTAIN MED ATTN. EYES: IMMED FLUSH WITH
-----------------------------
Name: ING 10: FLOWING WATER FOR AT LEAST 15 MIN W/EYELIDS HELD APART. OBTAIN
MED ATTN.
-----------------------------
Name: SPILL PROC: ENTERING STREAMS, DRINKING WATER SUPPLY OR SEWERS. DIKE TO
CONTAIN SPILL. DILUTE WITH WATER, IF
-----------------------------
Name: ING 12: NECESSARY TO REDUCE AMMONIA VAPORIZATION.
-----------------------------
Name: RESP PROT: FROM 0-200 PPM, A NIOSH/MSHA APPRVD CARTRIDGE TYPE 1/2 MASK
RESP IS NEEDED. FROM 200-500 PPM, A
-----------------------------
Name: ING 14: NIOSH/MSHA APPRVD TYPE "N" GAS MASK W/FULL FACEPIECE IS NEEDED.
> 500 PPM A NIOSH/MSHA APPRVD SCBA IS REQUIRED.
-----------------------------
Name: VENT: LEAD UPWARDS TO OUTSIDE. LOCAL EXHAUST MUST BE ADEQUATE TO REDUCE
AMMONIA CONCENTRATION BELOW 25 PPM.
-----------------------------
Name: OTHER PROT EQUIP: BROAD-BRIMMED RUBBER OR FELT HAT. USE OF PROTECTIVE OIL
WILL REDUCE SKIN IRRITATION FROM AMMONIA.
-----------------------------
Name: HYGIENE PRACT: WORK AREA. WASH HANDS BEFORE EATING, DRINKING, OR USING
RESTROOM.
-----------------------------
Cas: 1336-21-6
RTECS #: BQ9625000
Name: AMMONIUM HYDROXIDE; (AMMONIA) (CERCLA)
% Wt: 20-30
OSHA PEL: 25 PPM (MFR)
ACGIH TLV: 25 PPM (MFR)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: EFTS OF OVEREXP: EXPOS. MAY CAUSE SECOND-DEGREE BURNS ON LONG EXPOS.
EYES: VAP IS IRRIT. LIQ WILL CAUSE BURNS.
-----------------------------
Name: ING 2: SIGNS & SYMPS OF EXPOS: BURNING OF EYES, CONJUNC, SKIN IRRIT,
SWELLING OF EYELIDS & LIPS, DRY RED MOUTH &
-----------------------------
Name: ING 3: TONGUE, BURNING IN THROAT & COUGHING. IN MORE SEV CASES OF
EXPOS, DFCLT BRTHG, SIGNS & SYMPS OF LUNG
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Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INGEST: BURNING PAIN IN MOUTH, THROAT, STOM &
THORAX, CONSTRICTION OF THROAT & COUGHING, SOON FOLLOWED BY VOMIT OF
BLOOD/BY PASSAGE OF LOOSE STOOLS CONTAINING BLOOD. INGEST OF 3-4 ML MAY BE
FAT AL. INHAL: NAUS, VOMIT, DFCLT BRTHG & CONVULSIONS. SHOCK/LOSS OF
CONSCIOUSNESS MAY RSLT. BRIEF EXPOS TO(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: 5000 PPM MAY BE FATAL. SKIN
ABSORPTION: AMMONIA, BECAUSE OF ITS ALKALINITY & WATER SOLUBILITY, TENDS
TO BREAK DOWN & DISRUPT OUTER CELL LAYERS, PERMITTING RAPID PENETRATION.
EVEN SO, AMMONIA IS NOT SYSTEMIC POIS & EFTS WILL BE LIM TO LOC EFTS.
SKIN CONT: SMARTING OF SKIN & FIRST-DEGREE BURNS ON SHORT
Medical Cond Aggravated By Exposure: AMMONIA IS A RESPIRATORY IRRITANT. PERSONS
WITH IMPAIRED PULMONARY FUNCTION MAY BE AT INCREASED RISK FROM EXPOSURE.
First Aid: INGEST: DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LGE QTYS OF WATER
&, IF POSS, DILUTED VINEGAR, LEMON JUICE, ORANGE JUICE/OTHER CITRIC
JUICES TO NEUT AMMONIA. DELAY MAY CAUSE PERFORATION OF ESOPHAGUS/S TOM.
OBTAIN MED ATTN. INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN IF BRTHG IS DFCLT.
IF BRTHG HAS STOPPED, START ARTF RESP. KEEP VICTIM CALM & RESTING. OBTAIN
MED ATTN. SKIN: APPLY WATER IMMED TO
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SPILLS MAY NEED TO BE REPORTED TO NATIONAL RESPONSE
CTR (800-424-8802). DOT REPORTABLE QTY (RQ) IS 1000 LBS. STOP FLOW. WEAR
NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. APPROACH SPILL FROM UPWIND
& EVAC UATE AREA DOWNWIND. PVNT RUNOFF FROM
Neutralizing Agent: CAN BE NEUTRALIZED WITH DILUTE PHOSPHORIC OR SULFURIC
ACIDS. (SUP DAT)
Waste Disposal Methods: CONSULT FEDERAL, STATE, OR LOCAL AUTHORITIES FOR PROPER
DISPOSAL PROCEDURES.
Handling And Storage Precautions: HARMFUL TO AQUATIC LIFE IN VERY LOW
CONCENTRATIONS. MAY BE DANGEROUS IF IT ENTERS WATER INTAKES. NOTIFY LOCAL
HEALTH AND WILDLIFE OFFICIALS.
Other Precautions: DO NOT CONTAMINATE ANY BODY OF WATER BY DIRECT APPLICATION,
CLEANING OF EQUIPMENT OR DISPOSAL.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Lower Limits: 16%
Upper Limits: 25%
Extinguishing Media: USE WATER SPRAY OR FOG TYPE STREAMS. CHEMICAL OR CARBON
DIOXIDE SHOULD BE USED ON SMALL FIRES ONLY.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP
N). STOP FLOW OF LIQ. USE WATER TO KEEP FIRE EXPOSED CONTRS COOL & TO
PROTECT MEN AFFECTING SHUT (SUP DAT)
Unusual Fire/Explosion Hazard: THE PRESENCE OF OIL/OTHER COMBUST MATLS WILL
INCR FIRE HAZ. EXPLO (FLAM) RANGE OF AMMONIA IS BROADENED BY MIX OF OXYGEN
REPLACING AIR, & BY TEMP & (SUP DAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: UNLESS VENT IS ADEQ TO KEEP AIRBORNE CONCS BELOW EXPOS
STD, WEAR NIOSH/MSHA APPRVD RESP PROT SUCH AS AMMONIA CANISTER
MASK/NIOSH/MSHA APPRVD AIR SUPP RESP. CANISTER/CARTRIDGE TYPE MASK MUST NOT
BE USE D ABOVE THEIR EXPOS LIMITS.
Ventilation: LOC EXHAUST IS ESSENTIAL. SPARK-PROOF FANS DESIRABLE W/MECH VENT.
DUCTS SHOULD BE LOCATED AT CEILING LEVEL &
Protective Gloves: RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). RUBBER BOOTS, APRON, AND COAT.
Work Hygienic Practices: DO NOT WEAR CONTACT LENSES. AVOID CONTACT WITH SKIN
AND AVOID BREATHING VAPORS. DO NOT EAT, DRINK OR SMOKE IN
Supplemental Safety and Health: SPEC GRAV: 0.89-0.92 (H*2O=1). FIRE FIGHT PROC:
OFF. APPROACH FIRE UPWIND & EVACUATE AREA DOWNWIND IF NEEDED. EXPLO HAZ:
PRESS HIGHER THAN ATM. HAZ DECOMP PROD: WILL YIELD SML AMTS OF NITROGEN &
WATER . NEUT AGENT: VINEGAR WILL EFFECTIVELY NEUTRALIZE SMALL SPILLS OF AQUA
AMMONIA.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 86.6F,30.3C
Spec Gravity: SUP DAT
PH: >13
Solubility in Water: 100%
Appearance and Odor: COLORLESS LIQUID, WITH PUNGENT ODOR
Percent Volatiles by Volume: 25-30
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT, OPEN FLAMES, AND ELECTRICAL EQUIPMENT AND
FIXTURES WHICH ARE NOT VAPOR-PROOF OR GROUNDED.
Materials To Avoid: CONTACT WITH MERCURY, CHLORINE, BROMINE, IODINE, CALCIUM,
SILVER OXIDE, OR HYPOCHLORITE CAN FORM EXPLOSIVE COMPOUNDS.
Hazardous Decomposition Products: AMMONIA IS LIGHTLY REACTIVE, EASILY
UNDERGOING OXIDATION, SUBSTITUTION & ADDITIONAL RXNS. COMBUST OF AMMONIA (SUP
DAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: AQUA AMMONIA
Assigned IND: Y
Company: HILL BROTHERS CHEMICAL CO.
Street: 1675 NO. MAIN STREET
PO Box: NA
City: ORANGE CA
Zipcode: 92667
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 03/06/1996
Status Code: C
Label Date: 03/06/1996
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: CORROSIVE. ACUTE: INGEST: BURNING PAIN IN MOUTH,
THROAT, STOM & THORAX, CONSTRICTION OF THROAT & COUGHING, SOON
FOLLOWED BY VOMIT OF BLOOD/BY PASSAGE OF LOOSE STOOLS CONTAINING BLOOD.
INGEST OF 3-4 ML MAY BE FATAL. INHAL: NAUS, VOMIT, DFCLT BRTHG &
CONVULSIONS. SHOCK/LOSS OF CONSCIOUSNESS MAY RSLT. BRIEF EXPOS TO 5000 PPM
MAY BE FATAL. SKIN: CAN BE ABSORBED CAUSING BURNS. EYES: VAPOR IRRITATING. L
IQUID WILL BURN. CHRONIC: IRRIT & POSS BURNS OF SKIN & MUC MEMB,
HDCH, SALIVATION, NAUSEA & VOMIT. DIFFICULT BREATHING & COUGH
W/BLOODY MUCOUS DISCHARGE. BRONCHITIS, LARYNGITIS, PULM EDEMA/PNEUMIT. UL
CERATION OF CONJUNCTIVA & CORNEA. PERM EYE DMG.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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