| MSDS | : | CHEMGLAZE Z451 | | CAS | : | 67-63-0
584-84-9
108-88-3
1330-20-7
108-10-1
100-41-4
108-65-6
101-68-8
26471-62-5 | | NAME | : | other prot equip: remove & wash contaminated clothing before reuse.
hygiene pract: or beverages should not be consumed anywhere this prod is
ing 22: explo-proof equip) should be provided to prevent flamm vap/air
isopropyl alcohol; (isopropanol) (sara 313)
volatile organic compound: 4.31 lbs/gal, 517 g/l
efts of overexp: entry in indus/commercial uses. chronic: toluene appears
ing 11: list. seek consultation from approp hlth professionals concerning
ing 12: expos info (fp n). may cause liver/kidney dmg. rptd/prlngd solv
ing 13: cause long-term lung dmg. may affect gi sys, blood &
first aid: induce vomit. give one or two glasses of water/milk. call md
ing 15: instructions. never give anything by mouth to uncon person.
spill proc: w/inert absorb matl & non-spk tools. avoid cntct. before
hndlg/stor: in well-ventilated areas. do not puncture, drag or slide
other precs:& understood. empty cntnrs should not be reused. use
ing 19: prod residue & flam vaps, keep away from heat, spks &
ing 20: container. do not smoke where this product is used or stored.
vent: expos lims. caution:solv vaps are hvr/air & collect in lower
benzene, 2,4-diisocyanato-1-methyl-; (toluene-2, 4-diisocyanate) (tdi)
toluene (sara 313) (cercla)
xylene (sara 313) (cercla)
2-pentanone, 4-methyl-; (methyl isobutyl ketone) (sara 313) (cercla)
benzene, ethyl-; (ethyl benzene) (sara 313)
acetic acid, 2-methoxy-1-methylethyl ester; (1-methoxy-2-propyl acetate)
isocyanic acid, methylenedi-p-phenylene ester; (4,4'-diphenylmethane
isocyanic acid, methyl-m-phenylene ester; (toluene diisocyanate) (sara
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LORD CORP -- CHEMGLAZE Z451
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CBBJY
MSDS NAME: CHEMGLAZE Z451
Responsible Party
Name: LORD CORP
Address: 2000 W GRANDVIEW BLVD
City: ERIE PA 16514
Info Phone: 814-868-3611
Emergency Phone Number: 814-763-2348
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LORD CORP
Address: 2000 W GRANDVIEW BLVD
Box: 10038
City: ERIE PA 16514
Phone: 814-868-3611
Name: LORD CORPORATION, CHEMICAL PRODUCTS DIVISION
Address: 2000 WEST GRANDVIEW BLVD
City: ERIE PA 16514-0038
Phone: 814-868-3611
=======================================================
Ingredients
=======================================================
Name: OTHER PROT EQUIP: REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE.
-----------------------------
Name: HYGIENE PRACT: OR BEVERAGES SHOULD NOT BE CONSUMED ANYWHERE THIS PROD IS
HANDLED OR STORED. WASH THORO AFTER HANDLING.
-----------------------------
Name: ING 22: EXPLO-PROOF EQUIP) SHOULD BE PROVIDED TO PREVENT FLAMM VAP/AIR
MIXS FROM ACCUMULATING.
-----------------------------
Cas: 67-63-0
RTECS #: NT8050000
Name: ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313)
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM; 500 STEL
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: 4.31 LBS/GAL, 517 G/L
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: EFTS OF OVEREXP: ENTRY IN INDUS/COMMERCIAL USES. CHRONIC: TOLUENE APPEARS
ON NAVY LIST OF OCCUP CHEM REPRO HAZS
-----------------------------
Name: ING 11: LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST INFO & SAFE HNDLG &
-----------------------------
Name: ING 12: EXPOS INFO (FP N). MAY CAUSE LIVER/KIDNEY DMG. RPTD/PRLNGD SOLV
OVEREXP MAY RSLT IN PERM CNS DMG. MAY
-----------------------------
Name: ING 13: CAUSE LONG-TERM LUNG DMG. MAY AFFECT GI SYS, BLOOD &
BLOOD-FORMING ORGANS. CHRONIC SKIN CNTCT MAY CAUSE DERM.
-----------------------------
Name: FIRST AID: INDUCE VOMIT. GIVE ONE OR TWO GLASSES OF WATER/MILK. CALL MD
OR POIS CTL CTR IMMED FOR FURTHER
-----------------------------
Name: ING 15: INSTRUCTIONS. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.
-----------------------------
Name: SPILL PROC: W/INERT ABSORB MATL & NON-SPK TOOLS. AVOID CNTCT. BEFORE
CLEANUP REFER TO HAZ CAUTION INFO IN MSDS.
-----------------------------
Name: HNDLG/STOR: IN WELL-VENTILATED AREAS. DO NOT PUNCTURE, DRAG OR SLIDE
CNTNR. KEEP CNTNR CLSD WHEN NOT IN USE.
-----------------------------
Name: OTHER PRECS:& UNDERSTOOD. EMPTY CNTNRS SHOULD NOT BE REUSED. USE
W/ADEQ VENT. BECAUSE EMPTY CNTNRS MAY RETAIN
-----------------------------
Name: ING 19: PROD RESIDUE & FLAM VAPS, KEEP AWAY FROM HEAT, SPKS &
FLAME; DO NOT CUT, PUNCTURE/WELD ON/NEAR EMPTY
-----------------------------
Name: ING 20: CONTAINER. DO NOT SMOKE WHERE THIS PRODUCT IS USED OR STORED.
-----------------------------
Name: VENT: EXPOS LIMS. CAUTION:SOLV VAPS ARE HVR/AIR & COLLECT IN LOWER
LEVELS OF WORK AREA. SUFFICIENT VENT (USING
-----------------------------
Cas: 584-84-9
RTECS #: CZ6300000
Name: BENZENE, 2,4-DIISOCYANATO-1-METHYL-; (TOLUENE-2, 4-DIISOCYANATE) (TDI)
(SARA 302/313) (CERCLA)
% Wt: <1.0
OSHA PEL: 0.02 PPM, C
ACGIH TLV: 0.005 PPM; 0.02 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA)
% Wt: <20
OSHA PEL: 200 PPM
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA)
% Wt: <15
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM; 150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 108-10-1
RTECS #: SA9275000
Name: 2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA)
% Wt: <10
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM; 75 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 100-41-4
RTECS #: DA0700000
Name: BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313)
% Wt: <4.0
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM; 125 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 108-65-6
RTECS #: AI8925000
Name: ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY-2-PROPYL ACETATE)
% Wt: <3.0
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 101-68-8
RTECS #: NQ9350000
Name: ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (4,4'-DIPHENYLMETHANE
DIISOCYANATE) (SARA 313)
% Wt: <1.0
OSHA PEL: 0.02 PPM, C
ACGIH TLV: 0.005 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 26471-62-5
RTECS #: NQ9490000
Name: ISOCYANIC ACID, METHYL-M-PHENYLENE ESTER; (TOLUENE DIISOCYANATE) (SARA
313) (CERCLA)
% Wt: <1.0
OSHA PEL: N/K (FP N)
ACGIH TLV: 0.005 PPM; 0.02 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: EYE CNTCT: CAUSES IRRIT. SKIN CNTCT: MAY BE ABSORBED THRU
SKIN IN HARMFUL AMTS. MAY CAUSE SKIN SENSIT. MAY CAUSE DERM. CAUSES SKIN
IRRIT. INHAL: POSS IRRIT OF RESP SYS CAN OCCUR CAUSING VARIETY OF SYM PS SUCH
AS DRYNESS OF THROAT, TIGHTNESSOF CHEST & SHORTNESS OF BRTH. ALLERGIC
CNDTNS CAN OCCUR IN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: TOLUENE DIISOCYANATE: IARC MONO, SUPP, VOL 7,
PG 56, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994: (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: CERTAIN INDIVIDUALS W/HIGH
SENSITIVITY TO ISOCYANATES; MAY RSLT IN ASTHMA-LIKE SYMPS. MAY CAUSE CNS
DEPRESS CHARACT BY FOLLOWING PROGRESSIVE STEPS: HDCH, DIZZ, STAG GAIT,
CONFUSN, UNCON OR C OMA. MAY CAUSE RESP SENSIT. MAY CAUSE LUNG DMG. INGEST:
HARMFUL IF SWALLOWED. INGEST IS NOT EXPECTED ROUTE OF
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: FLUSH IMMED W/LG AMT OF WATER FOR AT LEAST 15 MIN HOLDING
EYELIDS OPEN WHILE FLUSHING. GET PROMPT MED ATTN. SKIN: FLUSH CONTAMD SKIN
W/LG AMTS OF WATER WHILE REMOVING CONTAMD CLTHG. WASH AFFECTE D SKIN AREAS
W/SOAP & WATER. GET MED ATTN IF SYMPS OCCUR. INHAL: MOVE TO FRESH AIR.
RESTORE & SUPPORT CONTINUED BRTHG. IF BRTHG IS DFCLT, GIVE OXYGEN. GET
IMMED MED ATTN. INGEST: DO NOT
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: KEEP NON-ESSTL PERS SAFE DIST AWAY FROM SPILL AREA.
REMOVE ALL SOURCES OF IGNIT (FLAME, HOT SURFS & ELEC, STATIC/FRICTIONAL
SPK). AVOID BRTHG VAPS. USE NIOSH/MSHA APPRVD SELF-CONTAINED BRTHG EQUIP. NO
TIFY APPROP AUTHS IF NEC. CONTAIN & REMOVE
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL SHOULD BE DONE ACCORDANCE WITH FEDERAL (40CFR
PART 261), STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. IF WASTE IS
DETERMINED TO BE HAZARDOUS, USE LICENSED HAZARDOUS WASTE TRANSPORTER AN D
DISPOSAL FACILITY.
Handling And Storage Precautions: DO NOT STORE/USE NEAR HEAT, SPKS OR OPEN
FLAME. REFER TO OSHA 29CFR PART 1910.106 "FLAM & COMBUST LIQS" FOR
SPECIFIC STORAGE REQS. STORE ONLY
Other Precautions: KEEP CLOSURE TIGHT & CNTNR UPRIGHT TO PVNT LEAKAGE.
GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID SKIN & EYE CNTCT.
WASH THORO AFTER HNDLG. AVOID BRTHG OF VAP OR SPRAY MISTS. DO NOT HANDLE
UNTIL ALL SFTY PRECS HAVE BEEN READ
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point Text: 58.0F,14.4C
Lower Limits: 0.9%
Upper Limits: 13.1%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures: USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP
N). WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. DURING
FIRE, IRRIT &/OR TOXIC (SUPDAT)
Unusual Fire/Explosion Hazard: FLAMM LIQ & VAP. KEEP CNTNRS TIGHTLY CLSD.
ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, OPEN FLAME & OTHER SOURCES OF
IGNIT. CLSD CNTNRS MAY RUPTURE WHEN (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: THIS PRODUCT CONTAINS ISOCYANATES WHICH HAVE POOR ODOR
WARNING PROPERTIES. IF OCCUPATIONAL EXPOSURE LIMITS ARE EXCEEDED, NIOSH/MSHA
APPROVED SUPPLIED-AIR RESPIRATOR IS REQUIRED. OBSERVE OSHA REGULATIO NS
(29CFR 1910.134) FOR RESPIRATOR USE.
Ventilation: SUFFICIENT VENT IN PATTERN & VOL SHOULD BE PROVIDED IN ORDER
TO MAINTAIN AIR CONTAMINANT LEVELS BELOW RECOM
Protective Gloves: NEOPRENE, NITRILE OR RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). USE
DISPOSABLE OR IMPERVIOUS CLTHG IF WORK CLTHG CONTAM IS LIKELY.
Work Hygienic Practices: WASH HANDS BEFORE EATING, SMKNG OR USING TOILET
FACILITY. DO NOT SMOKE IN ANY CHEM HNDLG/STORAGE AREA. FOOD
Supplemental Safety and Health: FIRE FIGHT PROC: GASES & PARTICULATE MAY BE
GENERATED BY THERMAL DECOMP OR COMBUST. EXPLO HAZ: EXPOSED TO EXTREME HEAT.
USE WATER SPRAY TO KEEP FIRE EXPOS CNTNRS COOL. EXPLAN OF CARCIN: ANTIC TO BE
CA RCIN. TOLUENE DIISOCYANATE(2,4): IARC MONO, SUPP, VOL 7,PG 56, 1987:GROUP
2B.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >232F,>111C
Vapor Density: HVR/AIR
Spec Gravity: 1.14
Evaporation Rate & Reference: SLOWER THAN ETHER
Solubility in Water: INSOLUBLE
Appearance and Odor: GRAY LIQUID; SOLVENT ODOR.
Percent Volatiles by Volume: 60.4
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES. SOURCES OF IGNITION.
Materials To Avoid: AMINES, ACIDS, WATER, HYDROXYL OR ACTIVE HYDROGEN
COMPOUNDS.
Hazardous Decomposition Products: MONOMERIC ISOCYANATE, TRACES OF HYDROGEN
CYANIDE, NITROGEN DIOXIDE. CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
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Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: CHEMGLAZE Z451
Assigned IND: Y
Company: LORD CORP
Street: 2000 W GRANDVIEW BLVD
PO Box: 10038
City: ERIE PA
Zipcode: 16514
Health Emergency Phone: 814-763-2348
Label Required IND: Y
Date Of Label Review: 05/07/1996
Status Code: C
Label Date: 05/07/1996
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMM LIQUID CLASS IB. ACUTE: EYES: IRRIT. SKIN: MAY BE
ABSORBED IN HARMFUL AMOUNTS. SKIN SENSIT, DERM. INHAL: RESP SYSTEM IRRIT
W/DRY THROAT, TIGHTNESS OF CHEST & SHORTNESS OF BREATH. CNS DEPRESSION
W/HEADACHE, DIZZINESS, CONFUSION, UNCONOR COMA. RESPIRATORY SENSIT, LUNG
DAMAGE. INGEST: HARMFUL IF SWALLOWED. CHRONIC: CANCER HAZARD. CONTAINS
TOLUENE DIISOCYANATE & TOLUENE-2,4-DIISOCYANATE WHICH AR E LISTED AS
ANIMAL LIVER CARCINOGENS (FP N). TOLUENE APPEARS ON THE NAVY OCCUPATIONAL
CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N) LIVER/KIDNEY DAMAGE. PERMANENT CNS
DAMAGE. LONG TERM LUNG DAMAGE. MAY AF FECT GI SYS, BLOOD & BLOOD-FORMING
ORGANS. DERM.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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