| MSDS | : | PITTCLOR | | CAS | : | 7778-54-3 | | NAME | : | hypochlorous acid, calcium salt; (calcium hypochlorite (65% available
inert materials; (includes 5.5 - 10% moisture)
supdat:uses of ing 1 is source of chlorine for sanitization in drinking
ing 3: conducted to determine long-term efts of chlorinated drinking
ing 4:1000ppm chlorine in drinking water. no difference in fertility,
ing 5:observed between ctl & expos animals. two separate animal
ing 6:chlorination of municipal drinking water did not rslt in tox to
ing 7: long-term basis should emphasize minimizing repeated acute
first aid proc:do not induce vomit. take immed to hospital or md. if
ing 9: do not attempt to induce vomit or give anything by mouth to uncon
spill proc: & broom & dissolve material in water. dispose of
waste disp meth:lb of calcium hypochlorite to be neut) then dilute neut
ing 12:unneut matl can cause environmental dmg to receiving water or can
ing 13:for on-site neut, carefully & slowly pour approp qty of 35%
ing 14: then flush area w/plenty of water. comments:care must be taken
ing 15:cntnrs to pvnt environmental contam. it is your duty to disp of
ing 16:air act, clean water act, rcra, as well as any other relevant fed,
hndlg/stor precs:spks, open flames & lighted tobacco prods. use only
ing 18:time prod is taken from cntnr. do not add prod to any dispensing
ing 19:prod. such use may cause violent rxn leading to fire/explo. add
ing 20: if mixed w/other chems. fire may rslt if contamd w/acids or
ing 21: gasoline, paint prods & most other org matls. do not reuse
ing 22: can react to cause fire. thoroughly flush empty cntnr w/water
ing 23: collection. do not contam water, food or feed by storage or
eye prot: & full length faceshield (fp n).
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PPG INDUSTRIES INC -- PITTCLOR
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Material Safety Data Sheet
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MSDS Num: CDMFP
MSDS NAME: PITTCLOR
Responsible Party
Name: PPG INDUSTRIES INC
Address: ONE PPG PLACE
City: PITTSBURGH PA 15272
Info Phone: 304-843-1300
Emergency Phone Number: 304-843-1300
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: PPG INDUSTRIES INC
Address: ONE PPG PLACE
City: PITTSBURGH PA 15272
Phone: 1-800-245-2974 (CAL HYPO)
=======================================================
Ingredients
=======================================================
Cas: 7778-54-3
RTECS #: NH3485000
Name: HYPOCHLOROUS ACID, CALCIUM SALT; (CALCIUM HYPOCHLORITE (65% AVAILABLE
CHLORINE)) (CERCLA)
% Wt: 65
OSHA PEL: 0.5 PPM (CL)
ACGIH TLV: 0.5 PPM; 1 STEL (CL)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Name: INERT MATERIALS; (INCLUDES 5.5 - 10% MOISTURE)
% Wt: 35
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT:USES OF ING 1 IS SOURCE OF CHLORINE FOR SANITIZATION IN DRINKING
& RECREATIONAL WATER. STUDIES HAVE BEEN
-----------------------------
Name: ING 3: CONDUCTED TO DETERMINE LONG-TERM EFTS OF CHLORINATED DRINKING
WATER. SEVEN GENERATIONS OF RATS WERE GIVEN
-----------------------------
Name: ING 4:1000PPM CHLORINE IN DRINKING WATER. NO DIFFERENCE IN FERTILITY,
GROWTH, BLOOD PARAMETERS/SPECIFIC ORGAN TOX
-----------------------------
Name: ING 5:OBSERVED BETWEEN CTL & EXPOS ANIMALS. TWO SEPARATE ANIMAL
STUDIES BY DIFFERENT GOVT AGENCIES DETERMINED
-----------------------------
Name: ING 6:CHLORINATION OF MUNICIPAL DRINKING WATER DID NOT RSLT IN TOX TO
DEVELOPING FETUS. SAFE HNDLG OF MATL ON
-----------------------------
Name: ING 7: LONG-TERM BASIS SHOULD EMPHASIZE MINIMIZING REPEATED ACUTE
EXPOSURE.
-----------------------------
Name: FIRST AID PROC:DO NOT INDUCE VOMIT. TAKE IMMED TO HOSPITAL OR MD. IF
UNCON OR IN CONVLS, TAKE IMMED TO HOSPITAL.
-----------------------------
Name: ING 9: DO NOT ATTEMPT TO INDUCE VOMIT OR GIVE ANYTHING BY MOUTH TO UNCON
PERSON. NOTE TO MD: TREAT SYMPTOMATICALLY.
-----------------------------
Name: SPILL PROC: & BROOM & DISSOLVE MATERIAL IN WATER. DISPOSE OF
WASTE MATERIAL AS OUTLINED IN WASTE DISPOSAL SECTION.
-----------------------------
Name: WASTE DISP METH:LB OF CALCIUM HYPOCHLORITE TO BE NEUT) THEN DILUTE NEUT
MATL W/PLENTY OF WATER & FLUSH TO SEWER.
-----------------------------
Name: ING 12:UNNEUT MATL CAN CAUSE ENVIRONMENTAL DMG TO RECEIVING WATER OR CAN
INTERFERE W/TREATMENT PLANT OPERATION.
-----------------------------
Name: ING 13:FOR ON-SITE NEUT, CAREFULLY & SLOWLY POUR APPROP QTY OF 35%
HYDROGEN PEROXIDE SOLN OVER ALL SPILLED MATL
-----------------------------
Name: ING 14: THEN FLUSH AREA W/PLENTY OF WATER. COMMENTS:CARE MUST BE TAKEN
WHEN USING/DISP OF CHEM MATLS &/OR THEIR
-----------------------------
Name: ING 15:CNTNRS TO PVNT ENVIRONMENTAL CONTAM. IT IS YOUR DUTY TO DISP OF
CHEM MATLS &/OR THEIR CNTNRS I/A/W CLEAN
-----------------------------
Name: ING 16:AIR ACT, CLEAN WATER ACT, RCRA, AS WELL AS ANY OTHER RELEVANT FED,
STATE & LOCAL LAWS/REGS REGARDING DISPOSAL.
-----------------------------
Name: HNDLG/STOR PRECS:SPKS, OPEN FLAMES & LIGHTED TOBACCO PRODS. USE ONLY
CLEAN, DRY SCOOP MADE OF METAL/PLASTIC EACH
-----------------------------
Name: ING 18:TIME PROD IS TAKEN FROM CNTNR. DO NOT ADD PROD TO ANY DISPENSING
DEVICE CONTAINING REMNANTS OF ANY OTHER
-----------------------------
Name: ING 19:PROD. SUCH USE MAY CAUSE VIOLENT RXN LEADING TO FIRE/EXPLO. ADD
PROD ONLY TO WATER. MAY CAUSE FIRE/EXPLO
-----------------------------
Name: ING 20: IF MIXED W/OTHER CHEMS. FIRE MAY RSLT IF CONTAMD W/ACIDS OR
EASILY COMBUST MATLS SUCH AS OIL, KEROSENE,
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Name: ING 21: GASOLINE, PAINT PRODS & MOST OTHER ORG MATLS. DO NOT REUSE
CNTNR. RESIDUAL MATL REMAINING IN EMPTY DRUM
-----------------------------
Name: ING 22: CAN REACT TO CAUSE FIRE. THOROUGHLY FLUSH EMPTY CNTNR W/WATER
THEN DESTROY BY PLACING IN TRASH
-----------------------------
Name: ING 23: COLLECTION. DO NOT CONTAM WATER, FOOD OR FEED BY STORAGE OR
DISPOSAL.
-----------------------------
Name: EYE PROT: & FULL LENGTH FACESHIELD (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL OF ING 1 AS DUST & DECOMP OF PARTICLES IN
RESP TRACT CAN LEAD TO IRRIT OF TISS & VARIETY OF EFTS DEPENDING ON
CONC:UPPER RESP TRACT IRRIT, NASAL CONGESTION, COUGH, SORE THROAT, LARYNGITIS
, SHORTNESS OF BRTH. IF THERE ARE HIGH CONCS OF RESPIRABLE PARTICULATES, PULM
EDEMA POSS; CAN THREATEN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:LIFE. SINCE PROD IN GRANULAR
FORM, PARTICLES OF RESPIRABLE SIZE NOT USUALLY ENCOUNTERED. EYE:ING 1 IS
CORR. EVEN MINUTE AMT OF DUST IN CNTCT W/EYES FOR SHORT DURATION CAN CAUSE
SEV IRRIT, BLN DNESS. SKIN:SEV IRRIT, BURNS/TISS DESTRUCTION. INGEST:CAUSES
SEV BURNS TO DIGEST TRACT & IS POSS FATAL. CHRONIC:(SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP, PREF
MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. SKIN:FLUSH W/PLENTY
OF WATER FOR AT LST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOE S. IF
IRRIT OCCURS, GET MED ATTN. EYE:FLUSH W/PLENTY OF WATER FOR AT LST 15 MIN.
GET IMMED MED ATTN. INGEST: IF CONSCIOUS, DRINK LG QTYS OF WATER & ANY
COMMON COOKING (VEGETABLE) OIL, IF AVAIL.
=======================================================
Handling and Disposal
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Spill Release Procedures: NOTE:USE EXTREME CAUTION IN HNDLG SPILLED MATL.
CONTAM W/ORG OR COMBUST MATL MAY CAUSE FIRE/VIOLENT DECOMP. IF FIRE/DECOMP
OCCURS IN AREA OF SPILL, IMMED DOUSE W/PLENTY OF WATER. OTHERWISE, SWEEP UP A
LL VISIBLE MATL USING CLEAN, DRY SHOVEL
Neutralizing Agent: ONE PINT OF 35% HYDROGEN PEROXIDE SOLUTION PER POUND OF
CALCIUM HYPOCHLORITE.
Waste Disposal Methods: SPILLED MATL THAT HAS BEEN SWEPT UP & DISSOLVED IN
WATER SHOULD BE USED IMMED IN NORM APPLICATN FOR WHICH ING 1 IS BEING
CONSUMED. IF NOT POSS, CAREFULLY NEUT DISSOLVED MATL BY ADDING HYDROGEN
PEROXID E (1 PINT OF 35% HYDROGEN PEROXIDE PER
Handling And Storage Precautions: DO NOT GET IN EYES/ON SKIN/CLTHG. KEEP IN
ORIGINAL CNTNR IN COOL, DRY PLACE. KEEP CNTNR CLSD WHEN NOT IN USE. KEEP AWAY
FROM HEAT SOURCES,
Other Precautions: KEEP OUT OF REACH OF CHILDREN. STRONG OXIDIZER-FIRE MAY RSLT
FROM CNTCT W/HEAT, ACIDS, ORG OR COMBUST MATTER. MAY BE FATAL/HARMFUL IF
SWALLOWED. MAY CAUSE CHEM BURNS. IRRIT TO NOSE & THROAT-AVOID BRTH G
DUST. WASH HANDS AFTER HNDLG.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Extinguishing Media: WATER ONLY! SMOTHERING INEFFECTIVE - PRODUCT SUPPLIES OWN
OXYGEN.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: DECOMPOSES AT 180C RELEASING OXYGEN GAS;
CONTAINERS MAY RUPTURE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF DUSTY CONDITIONS ARE ENCOUNTERED, USE NIOSH APPROVED
RESPIRATOR W/ACID GAS CARTRIDGE & DUST PREFILTER. RESPIRATOR USE
LIMITATIONS SPECIFIED BY NIOSH OR MFR MUST BE OBSERVED. RESPIRATORY
PROTECTION PROGRAMS MUST BE I/A/W 29 CFR 1910.134.
Ventilation: NONE, UNLESS DUSTY CONDITIONS ARE ENCOUNTERED.
Protective Gloves: NATURAL OR SYNTHETIC RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
BOOTS, APRONS OR CHEMICAL SUITS WHEN NECESSARY TO PREVENT SKIN CONTACT.
Work Hygienic Practices: PERSONAL PROTECTIVE CLOTHING & USE OF EQUIPMENT MUST
BE IN ACCORDANCE WITH 29 CFR 1910.132 & 29 CFR 1910.133.
Supplemental Safety and Health: BP: 356F,180C DECOMPOSES. PH: ALKALINE. EFTS OF
OVEREXP:GENOTOX:ING 1 PRDCED POS RESPONSES IN IN-VITRO ASSAYS USING BACTERIAL
SYS (AMES TEST) & CHROMOSOMAL ABERRATIONS IN CHINESE HAMSTER FIBROBLASTS.
IN WHOLE ANIMAL EXPERIMENTS W/EXPOS FROM 20-160 MG/KG, NO CMPD RELATED
CHROMOSOMAL ABNORMS PRDCED. ONE OF MAJOR
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SUPDAT
Decomp Text: 356F,180C
PH: SUPDAT
Solubility in Water: 217 G/L @ 27C
Appearance and Odor: WHITE POWDER WITH SLIGHT CHLORINE ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: NO
Stability Condition To Avoid: CONTAMINATION OR EXCESSIVE HEAT ABOVE 177C.
Materials To Avoid: ACIDS, COMBUSTIBLE MATERIALS, ORGANICS, REDUCING AGENTS.
Hazardous Decomposition Products: ACIDS OR AMMONIA CONTAM WILL RELS TOX GASES.
EXCESSIVE HEAT WILL CAUSE DECOMP RSLTG IN RELS OF OXYGEN & CHLORINE GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: PITTCLOR
Company: PPG INDUSTRIES INC
Street: ONE PPG PLACE
City: PITTSBURGH PA
Zipcode: 15272
Health Emergency Phone: 412-434-3131
Label Required IND: Y
Date Of Label Review: 04/04/1997
Status Code: C
Label Date: 04/04/1997
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: DECOMPOSITION PRODUCTS MAY BE TOXIC. ACUTE: UPPER
RESPIRATORY TRACT IRRITATION, NASAL CONGESTION, COUGH, SORE THROAT,
LARYNGITIS, SHORTNESS OF BREATH, PULMONARY EDEMA. EYES: CORROSIVE; SEVERE
IRRITATI ON, BLINDNESS. SKIN: SEVERE IRRITATION,BURNS OR TISSUE DESTRUCTION.
INGESTION: SEVERE BURNS TO DIGESTIVE TRACT AND CAN BE FATAL. CHRONIC: NONE
LISTED BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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