UNION CARBIDE CHEMICALS AND PL -- DIETHYLENETRIAMINE
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Material Safety Data Sheet
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MSDS Num: CDTJL
MSDS NAME: DIETHYLENETRIAMINE
Responsible Party
Name: UNION CARBIDE CHEMICALS AND PLASTIC CO INC
Address: 750 S 32ND ST
Box: 370
City: WASHOUGAL WA 98071
Info Phone: 206-835-8566
Emergency Phone Number: 800-822-4357
Published: Y
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Contractor Summary
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Name: UNION CARBIDE CHEMICALS & PLASTIC CO INC
Address: 750 S 32ND ST
City: WASHOUGAL WA 98671
Phone: 206-835-6566
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Ingredients
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Cas: 111-40-0
RTECS #: IE1225000
Name: DIETHYLENETRIAMINE. % (WT):98.5-99.5
% Wt: >98.5
OSHA PEL: 1 PPM
ACGIH TLV: S, 1 PPM
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Cas: 140-31-8
RTECS #: TK8050000
Name: PIPERAZINE, 1-(2-AMINOETHYL)-; (N-AMINOETHYLPIPERAZINE). % (WT):0.1-1.0
% Wt: >0.1
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Name: SUPDAT:CAUSES CORNEAL INJURY & IRITIS, SEV IRRIT, EXPERIENCED AS
DISCOMFORT/PAIN, EXCESS BLINKING & TEAR
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Name: ING 3:PRODUCTION, MARKED EXCESS REDNESS & SWELL OF CONJ, & CHEM
BURNS. CORNEAL INJURY MAY BE SEV, EXTENSIVE, &,
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Name: ING 4:IF NOT TREATED PROMPTLY, COULD RSLT IN PERM IMPAIRMENT OF VISION.
EFTS OF RPTD OVEREX:RPTD VAP EXPOS MAY
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Name: ING 5:CAUSE INJURY TO RESP TRACT. RPTD ORAL EXPOS MAY CAUSE KIDNEY &
LIVER CHANGES. INHAL OF ETHYLENEAMINES MAY
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Name: ING 6:CAUSE SENSIT OF RESP TRACT & DEVELOPMENT OF ASTHMATIC RXN ON
FURTHER EXPOS. MAY BE SUSCEPTIBLE INDIVIDUALS
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Name: ING 7:WHO DEVELOP LONG-TERM HYPERACT AIRWAYS, ASTHMA & OTHER RESP
INJURY FOLLOWING EXPOS TO EXTREMELY LOW CONCS
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Name: ING 8:OF ETHYLENEAMINES, EVEN BELOW IRRIT THRESHOLD. OTHER RESP IRRITANTS
MAY PRDCE RXN IN INDIVIDUALS WHOSE
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Name: ING 9:AIRWAYS HAVE BECOME HYPERACT. SINCE THERE ARE NO DEFINITIVE
SCREENING METH AVAIL TO IDENTIFY SUSCEPTIBLE
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Name: ING 10:INDIVIDUALS, PEOPLE W/ASTHMA/OTHER LONGSTANDING RESP CNDTNS (FOR
EXAMPLE, CHRONIC BRONCH, EMPHYSEMA, ETC)
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Name: ING 11;SHOULD BE PROTECTED FROM ANY POTNTL EXPOS TO ETHYLENEAMINES. SKIN
CONT MAY CAUSE SENSIT & ALLERGIC SKIN
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Name: ING 12:RXN. CROSS-SENSIT MAY OCCUR BY SKIN CONT W/MATL & OTHER
AMINES.
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Name: FIRST AID PROC:MAY BE GIVEN BY QUALIFIED PERS. OBTAIN MED ATTN.
EYES:IMMED FLUSH W/WATER & CONTINUE WASHING FOR
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Name: ING 14:@ LST 15 MINS. OBTAIN MED ATTN W/OUT DELAY, PREF FROM
OPTHALMOLOGIST. NOTES TO PHYS:NO SPECIFIC ANTIDOTE.
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Name: ING 15:TREATMENT OF OVEREXP SHOULD BE DIRECTED @ CTL OF SYMPS &
CLINICAL CNDTN OF PATIENT. FOR MORE INFO CONT NEHC(FP N)
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Name: SPILL PROC:BIODEGRADEABLE IN BIOLOGICAL WASTEWATER TREATMENT SYS.
HOWEVER, @ 150-200PPM CONC, IT CAN BE TOX TO
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Name: ING 19:BIOMASS IN TREATMENT SYS & CAN BE HIGHLY TOX TO FISH.
THEREFORE, AVOID DISCHARGE TO SEWERS/TO NATURAL WATERS.
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Name: OTHER PREC:INDUSTRY USE ONLY. WARNING:SUDDEN RELEASE OF HOT ORG CHEM
VAPS/MISTS FROM PROCESS EQUIP OPERATING @
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Name: ING 19:ELEVATED TEMP & PRESS/SUDDEN INGRESS OF AIR INTO VACUUM EQUIP,
MAY RSLT IN IGNIT W/OUT PRESENCE OF
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Name: ING 20:OBVIOUS IGNIT SOURCES. PUBLISHED "AUTOIGNIT"/"IGNIT" TEMP VALUES
CANNOT BE TREATED AS SAFE OPERATING
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Name: ING 21:TEMPS IN CHEM PROCESSES W/OUT ANALYSIS OF ACTUAL PROCESS CNDTNS.
ANY USE OF PROD IN ELEVATED-TEMP
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Name: ING 22:PROCESSES SHOULD BE THORO EVAL TO ESTABLISH & MAINTAIN SAFE
OPERATING CNDTNS. FOR MORE INFO CONT NEHC (FP N).
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Name: VENT:IS NEEDED @ POINTS WHERE VAPS CAN BE EXPECTED TO ESCAPE TO WORKPLACE
AIR.
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Name: EYE PROT:& FULL LENGTH FACESHIELD (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INGEST:MOD TOX. MAY CAUSE BURNS OF MOUTH &
THROAT, ABDOM PAIN, NAUS, VOMIT, DIARR, DIZZ, WEAK, THIRST, COLLAPSE, &
POSS COMA. NATURE & SEVERITY OF THESE SIGNS & SYMPS WILL BE DEPENDENT
ON AMTS I NGEST. ASPIR INTO LUNGS MAY OCCUR DURING INGEST/VOMIT, RSLTG IN
LUNG INJURY. SKIN ABSORP:PRLNGD OR (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:WIDESPREAD CONT MAY RSLT IN
ABSORP OF POTNTLY HARMFUL AMTS OF MATL. INHAL:VAP IS IRRIT & MAY CAUSE
EXCESS TEAR FORMATION, BURNING SENSATION OF NOSE & THROAT, COUGH,
WHEEZING, SHORTNESS OF BRE ATH, NAUS & VOMIT. EXTREMELY HIGH VAP CONCS
MAY CAUSE LUNG DMG. SOME INDIVIDUALS MAY DEVELOP ASTHMA. (SEE "OTHER(SUPDAT)
Medical Cond Aggravated By Exposure: SKIN CONT MAY AGGRAVATE EXISTING
DERMATITIS. INHALATION OF MATL MAY AGGRAVATE ASTHMA & INFLAMMATORY OR
FIBROTIC PULMONARY DISEASE.
First Aid: INGEST:IF CONSCIOUS, GIVE 2 GLASSES OF MILK/WATER @ ONCE. DO NOT
INDUCE VOMIT. OBTAIN MED ATTN W/OUT DELAY. SKIN:IMMED FLUSH THOROUGHLY
W/WATER FOR @ LST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. OBTAIN
MED ATTN W/OUT DELAY. WASH CLTHGBEFORE REUSE. DISCARD CONTAMD LEATHER
ARTICLES SUCH AS SHOES & BELT. INHAL:REMOVE TO FRESH AIR. GIVE ARTF RESP
IF NOT BRTHG. IF BRTHG IS DFCLT, OXYG
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Handling and Disposal
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Spill Release Procedures: WEAR SUITABLE PROT EQUIP; AVOID CONT W/LIQ &
VAPS! SM SPILLS COULD BE FLUSHED W/LG AMTS OF WATER. LGR SPILLS SHOULD BE
COLLECTED FOR DISP. AVOID DISCHARGE TO SEWERS/WATERWAYS. AT VERY LOW CONC IN
WATE R (ABOUT 10 PPM), DIETHYLENETRIAMINE IS
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE IN A FURNACE WHERE PERMITTED UNDER FEDERAL,
STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: DANGER! CAUSES EYE & SKIN BURNS. HARMFUL
& CORR IF SWALLOWED. HARMFUL IF INHALED/ABSORBED THRU SKIN. MAY CAUSE
ASTHMA W/POSS LONG-TERM LUNG DMG.
Other Precautions: MAY CAUSE ALLERGIC SKIN RXN. CROSS-SENSIT TO OTHER AMINES
MAY OCCUR. ASPIR MAY CAUSE LUNG DMG. MAY CAUSE RESP SYS DMG. DO NOT GET IN
EYES, ON SKIN ON CLTHG. DO NOT SWALLOW. AVOID BRTHG VAP. KEEP CNTNR CLSD.
USE W/ADEQ VENT. FOR
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point Text: 208F,98C
Extinguishing Media: APPLY ALCOHOL-TYPE/ALL-PURPOSE-TYPE FOAM BY MFR'S REC
TECHNIQUES FOR LG FIRES. USE CO*2/DRY CHEM MEDIA FOR SM FIRES.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). DO
NOT DIRECT SOLID STREAM OF WATER/FOAM INTO BURNING MOLTEN MATL:THIS MAY CAUSE
SPATTERING & SPREAD FIRE.
Unusual Fire/Explosion Hazard: DURING FIRE, OXIDES OF NITROGEN MAY BE EVOLVED.
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Control Measures
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Respiratory Protection: NIOSH APPRVD POSITIVE PRESSURE SUPPLIED AIR RESP
EQUIPPED W/FULL FACEPIECE SHOULD BE USED DURING ANY OPERATION WHERE THERE IS
POTNTL FOR RELEASE OF THIS PROD TO WORKPLACE AIR.
Ventilation: GEN (MECH) ROOM VENT EXPECTED TO BE SATISFACTORY WHERE PROD IS
STORED & HNDLD IN CLSD EQUIP. SPEC, LOC VENT
Protective Gloves: BUTYL NEOPRENE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
CHEMICAL APRON.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: HAZ DECOMP PROD:PRODS:ETHYLENEDIAMINE, VOLAT
AMINES, AMMONIA. EFTS OF OVEREXP:EFTS OF OVEREXP.") SKIN:CAUSES LOC
DISCOMFORT/PAIN, SEV EXCESS REDNESS & SWELL, TISS DESTRUCTION, FISSURES,
ULCERATION, & POSSIBLY BLEEDING INTO INJURED AREA. EYE:VAP MAY CAUSE
TEMPORARY DISTURB OF VISION. (SEE "NOTES TO PHYS".)
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Physical/Chemical Properties
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B.P. Text: 404F,207C
M.P/F.P Text: -38F,-39C
Vapor Pres: 0.08 @ 20C
Vapor Density: 3.6
Spec Gravity: 0.952 (H*2O=1)
Evaporation Rate & Reference: 0.01 (BUTYL ACETATE =1)
Solubility in Water: 100% BY WT
Appearance and Odor: TRANSPARENT COLORLESS LIQUID, MILD AMINE ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: SOME DECOMPOSITION CAN OCCUR UPON VIGOROUS
HEATING; E.G., APPLICATION OF HIGH-PRESSURE STEAM OR FLAME.
Materials To Avoid: ACIDS, OXIDIZING AGENTS, ALDEHYDES, KETONES, EPOXIDES,
ACRYLATES, ORGANIC HALIDES.
Hazardous Decomposition Products: BURNING CAN PRDCE FOLLOWING COMBUST
PRODS:OXIDES OF CARBON & NITROGEN. THERMAL DECOMP CAN PRDCE FOLLOWING
DECOMP(SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: DIETHYLENETRIAMINE
Company: UNION CARBIDE CHEMICALS & PLASTIC CO INC
Street: 750 S 32ND ST
City: WASHOUGAL WA
Zipcode: 98671
Health Emergency Phone: 800-822-4357
Label Required IND: Y
Date Of Label Review: 04/22/1997
Status Code: C
Label Date: 04/22/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INGEST:MOD TOX. MAY CAUSE BURNS OF MOUTH &
THROAT, ABDOM PAIN, NAUS, VOMIT, DIARR, DIZZ, WEAK, THIRST, COLLAPSE, &
POSS COMA. ASPIR INTO LUNGS MAY OCCUR DURING INGEST/VOMIT, RSLTG IN LUNG
INJURY . SKIN ABSORP:PRLNGD/WIDESPREAD CONT MAY RSLT IN ABSORP OF HARMFUL
AMTS. CONT CAUSES LOC DISCOMFORT/PAIN. SEV REDNESS/SWELL & DESTRUCTION OF
TISS. EYE:VAP MAY DISTURB VISION. CONT CAUSES SEV IRRIT & C ORNEAL
INJURY. INHAL:VAP IRRIT CAUSING TEARING, BURNING SENSATION OF THROAT &
NOSE, COUGH, WHEEZING, NAUS & VOMIT. CHRONIC:OVEREXP MAY INJURE RESP
TRACT. RPTD INGEST MAY CAUSE KIDNEY & LIVER CHANGES. SKIN &
RESPIRATORY SENSITIZATION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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