| MSDS | : | CLEAN-SOLV 190, LOW VOC (190 G/L), (SUPDAT) | | CAS | : | 71-55-6
78-93-3 | | NAME | : | ethane, 1,1,1-trichloro-; (1,1,1-trichloroethane) (sara 313) (cercla).
2-butanone; (methyl ethyl ketone) (mek) (sara 313) (cercla).
volatile organic compound:190 g/l
supdat:depress. ingest may rslt in diarr, gi irrit, naus, & vomit.
ing 4:as even sm qtys may rslt in aspir pneum. signs & symps of
ing 5:depress may be evid by labored brthg, gidd, hdch, dizz, & naus.
ing 6:may occur. aspir pneum by labored brthg, cough, & cyanosis;
ing 7:sometimes pain in upper abdom on right side; optic nerve dmg by
ing 8:by changes in urine appear & output/edema; peripheral nerve dmg
ing 9:arms & legs. chronic tox:overexp has caused tox liver efts in
ing 10:indicate no adverse efts; 3rd study noted delays in normal
ing 11:life. methyl ethyl ketone:in female rats expos by inhal to
ing 12:embryotoxic fetotoxic efts were observed. mek has been
ing 13:caused by either n-hexane/methyl n-butyl ketone. mek by itself has
ing 14:pripheral neuropathy.
first aid proc:keep head below hips to pvnt aspir into lung. get med
spill proc:cloud; contain run-off, remove w/vacuum trucks/pump to
ing 17:as clay, sand/other suitable matl; place in non-leaking cntnrs for
ing 18:remove trace residue; dispose of flush solns as above. for more
other prec:use & until all vaps are gone. keep cntnrs clsd when not
ing 20:can contain explo vaps. do not cut, drill, grind, weld/perform
ing 21:pressurize drum cntnrs to empty them. static elec may accum &
ing 22:containers and equipment.
vent:explosion-proof vent to maintain expososures below osha-recommended
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IWU -- CLEAN-SOLV 190, LOW VOC (190 G/L), (SUPDAT)
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Material Safety Data Sheet
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MSDS Num: CDTKB
MSDS NAME: CLEAN-SOLV 190, LOW VOC (190 G/L), (SUPDAT)
Responsible Party
Name: IWU
Address: 5601 STATE ST
City: ONTARIO CA 91762
Info Phone: 909-984-9984
Emergency Phone Number: 909-984-9984
Preparer's Name: JAMES FREEMAN
Published: Y
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Name: IWU
Address: 5601 STATE ST
City: ONTARIO CA 91762
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Contractor Summary
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Name: IWU
Address: 5601 STATE ST
City: ONTARIO CA 91762
Phone: 909-984-9984
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Ingredients
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Cas: 71-55-6
RTECS #: KJ2975000
Name: ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA 313) (CERCLA).
LD50:(ORAL,RAT) 10 G/KG
% Wt: 83
OSHA PEL: 350 PPM
ACGIH TLV: 350 PPM/450 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
Ozone Depleting Chemical: 1
------------------------------
Cas: 78-93-3
RTECS #: EL6475000
Name: 2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA).
LD50:(ORAL,RAT) 3.4 G/KG
% Wt: 17
OSHA PEL: 200 PPM
ACGIH TLV: 200 PPM/300 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND:190 G/L
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT:DEPRESS. INGEST MAY RSLT IN DIARR, GI IRRIT, NAUS, & VOMIT.
ASPIR OF VOMIT INTO LUNGS MUST BE AVOIDED,
-----------------------------
Name: ING 4:AS EVEN SM QTYS MAY RSLT IN ASPIR PNEUM. SIGNS & SYMPS OF
EXCESS EXPOS:IRRIT AS NOTED. EARLY TO MOD CNS
-----------------------------
Name: ING 5:DEPRESS MAY BE EVID BY LABORED BRTHG, GIDD, HDCH, DIZZ, & NAUS.
IN SEV CASES, UNCON, RESP DEPRESS, & DEATH
-----------------------------
Name: ING 6:MAY OCCUR. ASPIR PNEUM BY LABORED BRTHG, COUGH, & CYANOSIS;
LIVER DMG BY LOSS OF APPETITE, JAUNDICE, &
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Name: ING 7:SOMETIMES PAIN IN UPPER ABDOM ON RIGHT SIDE; OPTIC NERVE DMG BY
PARTIAL/COMPLETE LOSS OF VISION; KIDNEY DMG
-----------------------------
Name: ING 8:BY CHANGES IN URINE APPEAR & OUTPUT/EDEMA; PERIPHERAL NERVE DMG
BY MUSCULAR WEAK & LOSS OF SENSATION IN
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Name: ING 9:ARMS & LEGS. CHRONIC TOX:OVEREXP HAS CAUSED TOX LIVER EFTS IN
LAB ANIMALS. 2 OF 3 REPROD-TOX STUDIES
-----------------------------
Name: ING 10:INDICATE NO ADVERSE EFTS; 3RD STUDY NOTED DELAYS IN NORMAL
DEVELOPMENT, BUT DELAYS DID NOT AFFECT LATER
-----------------------------
Name: ING 11:LIFE. METHYL ETHYL KETONE:IN FEMALE RATS EXPOS BY INHAL TO
>1,000 PPM (5 TIME OSHA PEL/TWA), MINOR
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Name: ING 12:EMBRYOTOXIC FETOTOXIC EFTS WERE OBSERVED. MEK HAS BEEN
DEMONSTRATED TO POTENTIATE PERIPHERAL NEUROPATHY
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Name: ING 13:CAUSED BY EITHER N-HEXANE/METHYL N-BUTYL KETONE. MEK BY ITSELF HAS
NOT BEEN DEMONSTRATED TO CAUSE
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Name: ING 14:PRIPHERAL NEUROPATHY.
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Name: FIRST AID PROC:KEEP HEAD BELOW HIPS TO PVNT ASPIR INTO LUNG. GET MED
ATTN. NOTE TO PHYS: CONT NEHC FOR MORE INFO (FP N).
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Name: SPILL PROC:CLOUD; CONTAIN RUN-OFF, REMOVE W/VACUUM TRUCKS/PUMP TO
STOR/SALV VESS. SOAK UP RESIDUE W/ABSORB SUCH
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Name: ING 17:AS CLAY, SAND/OTHER SUITABLE MATL; PLACE IN NON-LEAKING CNTNRS FOR
PROPER DISP. FLUSH AREA W/WATER TO
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Name: ING 18:REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLNS AS ABOVE. FOR MORE
SPECIFIC INFORMATION CONT NEHC (FP N).
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Name: OTHER PREC:USE & UNTIL ALL VAPS ARE GONE. KEEP CNTNRS CLSD WHEN NOT
IN USE; EVEN CNTNRS THAT HAVE BEEN EMPTIED
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Name: ING 20:CAN CONTAIN EXPLO VAPS. DO NOT CUT, DRILL, GRIND, WELD/PERFORM
SIMILAR OPERATIONS ON/NEAR CNTNRS. DO NOT
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Name: ING 21:PRESSURIZE DRUM CNTNRS TO EMPTY THEM. STATIC ELEC MAY ACCUM &
CREATE FIRE HAZ. BOND & GROUND TRANSFER
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Name: ING 22:CONTAINERS AND EQUIPMENT.
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Name: VENT:EXPLOSION-PROOF VENT TO MAINTAIN EXPOSOSURES BELOW OSHA-RECOMMENDED
EXPOSURE LIMITS.
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR
LIFE-SUSTAIN ING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBS (FP
N). ACUTE:INHAL:VAPS MAY BE IRRITATING (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:TO NOSE, THROAT, & RESP
TRACT, HIGH VAP CONCS MAY CAUSE CNS DEPRESS &/OR LIVER & KIDNEY DMG,
OPTIC &/OR PERIPHERAL NERVE DMG, PERIPHERAL NEUROPATHY, VENTRICULAR
ARRHY, & CARD SENSIT. SKIN:MIL DLY TO MOD IRRITATING; PRLNGD/RPTD LIQ
CONT CAN RSLT IN DEFAT & DRYING, WHICH MAY RSLT IN IRRIT & DERM.
EYES:LIQ(SUPDAT)
Medical Cond Aggravated By Exposure: PRE-EXISTING EYE, SKIN, & RESP
DISORDERS & IMPAIRED LIVER & KINDY FUNCTIONS FROM PRE-EXISTING
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
First Aid: EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS WHILE HOLDING
EYELIDS OPEN. GET MED ATTN. SKIN:REMOVE CONTAMD CLTHG & SHOES. FLUSH
W/WATER THEN WASH EXPOS AREA W/SOAP & WATER. IF IRRIT OCCURS, GET MED
ATTN. INHAL:REMOVE TO FRESH AIR. HAVE QUALIFIED INDIVIDUAL PROVIDE OXYG IF
DFCLTY BRTHG. ADMIN ARTF RESP IF BRTHG STOPPED. GET MED ATTN. INGEST:DO NOT
INDUCE VOMIT. IF VOMIT OCCURS SPONT,
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Handling and Disposal
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Spill Release Procedures: WARNING. FLAM. ELIM ALL IGNIT SOURCES. HNDLG EQUIP
MUST BE GROUNDED TO PVNT SPK. LG SPILLS:ISOLATE HAZ AREA & DENY ENTRY TO
UNNEC PERS. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE &
CONTAIN. W ATER FOG MAY BE USEFUL IN SUPPRESSING VAP
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: UNDER EPA-RCRA 40CFR 261.21, IF PROD BECOMES WASTE
MATL, IT WOULD BE IGNITABLE HAZ WASTE NO:D001. DISPOSE OF I/A/W LOCAL, STATE,
& FEDERAL REGULATIONS (FP N). FOR MORE SPECIFIC INFORMATION CONTACT NEH C
(FP N).
Handling And Storage Precautions: KEEP PROD AWAY FROM HEAT, SPKS, & FLAME.
SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE PROD EVEN IN ABSENCE OF SPARKS
& FLAME.
Other Precautions: NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC
WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE FORMATION OF
HCL &/OR PHOSGENE (FP N). EXTING ALL FLAME NEAR STOR SITES & TURN OFF
OTHER SOURCES OF IGNIT PRIOR TO
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: <70F,<21C
Lower Limits: 1.8%
Upper Limits: 15%
Extinguishing Media: USE WATER FOG, DRY CHEM/CO*2. DO NOT USE DIRECT STREAM OF
WATER; PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF WATER.
Fire Fighting Procedures: NIOSH APPROVED PRESSURE DEMAND SCBA & FULL
PROTECTIVE EQUIPMENT (FP N). CLEAR FIRE AREA OF UNPROTECTED PERSONNEL.
Unusual Fire/Explosion Hazard: THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE
(FP N). CNTNRS & CNTNR AREAS EXPOS TO HEAT FROM FIRES/DIRECT FLAME CONT
SHOULD BE COOLED W/WATER TO PVNT (SUPDAT)
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Control Measures
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Respiratory Protection: AVOID BRTHG OF VAPS. IF EXPOS EXCEED OCCUP EXPOS LIMS,
USE NIOSH APPRVD RESP TO PVNT OVEREXP. IN ACCORD WITH 29 CFR 1910.134, USE
EITHER NIOSH APPRVD ATM-SUPPLYING/NIOSH APPRVD AIR-PURIFYING RESPIRATO R FOR
ORGANIC VAPORS.
Ventilation: MAINTAIN VAP CONCS BELOW OCCUP EXPOS LIMS. DO NOT USE IN
CLSD/CONFINED SPACES. OPEN DOORS & WINDOWS. USE ADEQ
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). CLTHG
AS REQD TO MINIMIZE CONT. AVOID PRLNGD/RPTD CONT W/SKIN.
Work Hygienic Practices: AVOID SKIN CONT & BRTHG VAPS. DO NOT EAT, DRINK/SMOKE
IN WORK AREA. WASH HANDS PRIOR TO EATING, DRINKS/USE RESTROOM.
Supplemental Safety and Health: MFR TRADE NAME/PART NO:INDUSTRIAL CLEANING
SOLVENT. EXPLO HAZ:VAP-PRESS BUILD-UP, WHICH COULD RSLT IN CNTNR RUPTURE. HAZ
DECOMP PROD:COMBUST. EFTS OF OVEREXP:IS SEV IRRITATING & MAY CAUSE
TEMPORARY CO RNEAL INJURY, HIGH VAP CONCS MAY ALSO BE IRRITATING. INGEST:LIQ
IS TOX & MAY BE HARMFUL, POSSIBLY PRODUCING CNS
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Physical/Chemical Properties
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B.P. Text: >165F,>74C
Vapor Pres: 118 @ 25C
Vapor Density: 4.2
Spec Gravity: 1.24 (H*2O=1)
Evaporation Rate & Reference: 1.1 (N-BUTYL ACETATE =1)
Solubility in Water: 27.5% @ 25C (WT %)
Appearance and Odor: CLEAR, COLORLESS LIQUID, CHLOROFORM-LIKE ODOR.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEAT, SPKS, FLAME, STRONG OXIDIZING AGENTS,
ALKALIES, REACTIVE METALS, MINERAL ACIDS, & STOR IN ALUMINUM @ TEMPS >120F.
Materials To Avoid: HEAT, SPKS, FLAME, STRONG OXIDIZING AGENTS, ALKALIES,
REACTIVE METALS, MINERAL ACIDS, & STOR IN ALUMINUM @ TEMPS >120F.
Hazardous Decomposition Products: CO, CO*2, METHYL VINYL KETONE, HYDROGEN
CHLORIDE, PHOSGENE, & OTHER UNIDENTIFIED ORG CMPDS MAY BE FORMED DURING
(SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: CLEAN-SOLV 190, LOW VOC (190 G/L), (SUPDAT)
Company: IWU
Street: 5601 STATE ST
City: ONTARIO CA
Zipcode: 91762
Health Emergency Phone: 909-984-9984
Label Required IND: Y
Date Of Label Review: 04/18/1997
Status Code: C
Label Date: 04/18/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE LIQUID. ACUTE:INHAL:EXPOSURE TO VAPOR/MIST
MAY CONTRIBUTE TO OCCURRENCE OF IRREGULAR HEARTBEAT (FP N). VAPORS CAN
IRRITATE NOSE, THROAT AND RESPIRATORY TRACT. MAY CAUSE CNS DEPRESS. SKIN:MIL
D TO MODERATE IRRITATION. MAY RESULT INDEFATTING, DRYING AND DERMATITIS.
EYE:LIQUID SEVERELY IRRITATES AND MAY CAUSE TEMPORARY CORNEAL INJURY. VAPORS
CAN ALSO IRRITATE. INGEST:TOXIC AND MAY BE HARMFUL . MAY PRODUCE CNS
DEPRESSION. CAN CAUSE DIARRHEA, VOMITING, NAUSEA AND GASTROINTESTINAL
IRRITATION. CHRONIC:OVEREXPOSURE CAN DAMAGE KIDNEYS, LIVER, OPTIC NERVE AND
PERIPHERAL NERVOUS SYSTEM.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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