| MSDS | : | EN ALKYD SEMIGLOSS LOW VOC GREEN 24664, 775480 07 | | CAS | : | 123-86-4
100-41-4
1330-20-7
13463-67-7
112945-52-5
14807-96-6
14808-60-7
110-12-3
78-93-3 | | NAME | : | acetic acid, butyl ester; (n-butyl acetate) (cercla) vp: 10 @ 20c; lel:
ethyl benzene (sara 313) vp: 1 @ 20c; lel: 1%; uel: 6.7%
xylene (sara 313) (cercla) vp: 5 @ 20c; lel: 1%; uel: 7%
titanium oxide; (titanium dioxide)
silica gel; (silica, amorphous hydrated)
talc (powder), containing no asbestos fibers; (talc)
silica, crystalline - quartz; (crystalline silica)
2-hexanone, 5-methyl-; (methyl isoamyl ketone)
2-butanone; (methyl ethyl ketone) (sara 313) (cercla) vp: 70 @ 20c; lel:
voc: 3.04 lbs/gal less water & nprs (365 g/l less water calculated);
sup dat: & repeated occup overexp to solvs w/perm brain & nerv
ing 11: & inhaling contents may be harmful/fatal. significant lab
ing 12: dioxide in a 24-month inhal study w/rats revealed significant
ing 13: group exposed to 250 mg/m3 resp tio*2 dust. norm clearance
ing 14: at 250 mg/m3 expos level, & this may have contributed to
ing 15: relevant to workplace where occup expos lims are observed. at tlv
ing 16: significant haz for man. lab studies involving rats indicate some
ing 17: be embryotoxic, fetotoxic & teratogenic.
first aid proc: notes to md: any treatment that might be required for
ing 19: of symptoms and the clinical conditions.
spill proc: use only non-spkg tools. place absorb diking matls in covered
ing 21: sewers, streams, and ground water with spilled material or used
resp prot: in restricted vent areas niosh apprvd chem cartridge resp may
ing 23: as spraying, niosh apprvd mech prefilter may also be required. in
ing 24: supplied resp. if tlv's are exceeded, use properly fitted niosh
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PRATT & LAMBERT -- EN ALKYD SEMIGLOSS LOW VOC GREEN 24664, 77548
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGQHX
MSDS NAME: EN ALKYD SEMIGLOSS LOW VOC GREEN 24664, 775480 07
Responsible Party
Name: PRATT & LAMBERT
Address: 101 PROSPECT AVE
City: CLEVELAND OH 44115
Info Phone: 316-733-1361
Emergency Phone Number: 800-255-3924
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: PRATT & LAMBERT
Address: 250 PETTIT AVE
Box: 2153
City: BELLMORE NY 11710
Phone: 800-647-2253
Name: PRATT & LAMBERT
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
=======================================================
Ingredients
=======================================================
Cas: 123-86-4
RTECS #: AF7350000
Name: ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) VP: 10 @ 20C; LEL:
1.7%; UEL: 7.6%
OSHA PEL: 150 PPM
ACGIH TLV: 150 PPM/200 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 100-41-4
RTECS #: DA0700000
Name: ETHYL BENZENE (SARA 313) VP: 1 @ 20C; LEL: 1%; UEL: 6.7%
% Wt: <5
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/125 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA) VP: 5 @ 20C; LEL: 1%; UEL: 7%
% Wt: 10
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 112945-52-5
RTECS #: VV7310000
Name: SILICA GEL; (SILICA, AMORPHOUS HYDRATED)
OSHA PEL: 6 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)
OSHA PEL: 20 MPPCF Z-3
ACGIH TLV: 2 MG/M3 RDUST
------------------------------
Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA)
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 0.1 MG/M3 RDUST
------------------------------
Cas: 110-12-3
RTECS #: MP3850000
Name: 2-HEXANONE, 5-METHYL-; (METHYL ISOAMYL KETONE)
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM
------------------------------
Cas: 78-93-3
RTECS #: EL6475000
Name: 2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA) VP: 70 @ 20C; LEL:
2%; UEL: 10%
% Wt: 5
OSHA PEL: 200 PPM
ACGIH TLV: 200 PPM/300 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOC: 3.04 LBS/GAL LESS WATER & NPRS (365 G/L LESS WATER CALCULATED);
5.38 LBS/GAL SOLIDS (646 G/L SOLIDS CALCULATED)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUP DAT: & REPEATED OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV
SYS DMG. INTENTIONAL MISUSE BY DELIBERATELY CONC
-----------------------------
Name: ING 11: & INHALING CONTENTS MAY BE HARMFUL/FATAL. SIGNIFICANT LAB
DATA W/POSS RELEVANCE TO HUMAN HLTH: TITANIUM
-----------------------------
Name: ING 12: DIOXIDE IN A 24-MONTH INHAL STUDY W/RATS REVEALED SIGNIFICANT
INCR IN BENIGN & MALIGNANT LUNG TUMORS IN
-----------------------------
Name: ING 13: GROUP EXPOSED TO 250 MG/M3 RESP TIO*2 DUST. NORM CLEARANCE
MECHANISMS OF LUNGS MAY HAVE BEEN OVERWHELMED
-----------------------------
Name: ING 14: AT 250 MG/M3 EXPOS LEVEL, & THIS MAY HAVE CONTRIBUTED TO
TUMOR FORM. THESE RSLTS MAY NOT BE DIRECTLY
-----------------------------
Name: ING 15: RELEVANT TO WORKPLACE WHERE OCCUP EXPOS LIMS ARE OBSERVED. AT TLV
TIO*2 MFR CONCLUDES THAT THERE IS NO
-----------------------------
Name: ING 16: SIGNIFICANT HAZ FOR MAN. LAB STUDIES INVOLVING RATS INDICATE SOME
EVIDENCE THAT METHYL ETHYL KETOME MAY
-----------------------------
Name: ING 17: BE EMBRYOTOXIC, FETOTOXIC & TERATOGENIC.
-----------------------------
Name: FIRST AID PROC: NOTES TO MD: ANY TREATMENT THAT MIGHT BE REQUIRED FOR
OVEREXP SHOULD BE DIRECTED AT THE CONTROL
-----------------------------
Name: ING 19: OF SYMPTOMS AND THE CLINICAL CONDITIONS.
-----------------------------
Name: SPILL PROC: USE ONLY NON-SPKG TOOLS. PLACE ABSORB DIKING MATLS IN COVERED
METAL CONTRS FOR DISP. PVNT CONTAM OF
-----------------------------
Name: ING 21: SEWERS, STREAMS, AND GROUND WATER WITH SPILLED MATERIAL OR USED
ABSORBENT.
-----------------------------
Name: RESP PROT: IN RESTRICTED VENT AREAS NIOSH APPRVD CHEM CARTRIDGE RESP MAY
BE REQUIRED. UNDER CERTAIN CNDTNS, SUCH
-----------------------------
Name: ING 23: AS SPRAYING, NIOSH APPRVD MECH PREFILTER MAY ALSO BE REQUIRED. IN
CONFINED AREAS USE NIOSH APPRVD AIR
-----------------------------
Name: ING 24: SUPPLIED RESP. IF TLV'S ARE EXCEEDED, USE PROPERLY FITTED NIOSH
APPRVD RESP W/APPROP PROT FACTOR.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INGEST: CAN CAUSE GI IRRIT, NAUS, & VOMIT.
ASPIR OF MATL INTO LUNGS MAY CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. INHAL:
MAY CAUSE NOSE/THROAT IRRIT. HIGH CONCS MAY CAUSE ACUTE CNS DEPRESS INCL HD
CH, DIZZ, NAUS & CONFUSION. EYE: MAY CAUSE IRRIT. SKIN: LIQ MATL MAY BE
ABSORBED THRU SKIN IN HARMFUL (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE-QUARTZ: IARC MONO, VOL 68,
1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE (SUP DAT)
Signs And Symptions Of Overexposure: HLTH HAZ: AMTS. SKIN: MAY CAUSE DEFAT
& IRRIT. CHRONIC: RPTD & PRLNG OCCUP OVEREXP TO CRYSTALLINE SILICA
MAY CAUSE SILICOSIS, A PROGRESSIVELY DISABLING LUNG DISEASE. OVEREXP TO
XYLENE MAY CAUSE INJURY TO LIVER, KIDNEYS, & BLOOD. EXPOS TO METHYL
ETHYL KETONE MAY ENHANCE NEUROTOXICITY OF N-HEXANE & METHYL-N- (SUP DAT)
Medical Cond Aggravated By Exposure: PREEXISTING RESPIRATORY CONDITIONS MAY BE
AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
First Aid: INGEST: DO NOT INDUCE VOMIT. CALL POIS CTL CTR, HOSPITAL EMER
ROOM/MD IMMED. INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE
ARTF RESP. KEEP WARM & QUIET. GET MED ATTN IMMED. EYES: FLUSH W/LGE AMTS
OF WATER, LIFTING UPPER & LOWER LIDS OCCAS, FOR AT LEAST 15 MIN. GET MED
ATTN. SKIN: REMOVE CONTAM CLTHG. WASH AFFECTED AREA W/SOAP & WATER.
OBTAIN MED ATTN IF IRRIT PERSISTS.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: KEEP SPECTATORS AWAY. ELIM ALL IGNIT SOURCES (FLAMES,
HOT SURFS, & SOURCES OF ELEC, STATIC/FRICTIONAL SPKS). DIKE & CONTAIN
SPILL W/INERT MATL (E.G., SAND, EARTH). TRANSFER LIQS TO COVERED METAL CONTR
S FOR RECOVERY/DISP/REMOVE W/INERT ABSORB.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISP I/A/W FED, STATE & LOC REGS. THIS PROD, IF
DISCARDED DIRECTLY, WOULD BE CLASSIFIED AS HAZ WASTE BASED ON ITS
IGNITABILITY CHARACT, I.E. HAS FLASH POINT OF 140F (60C)/LESS. PROPER RCRA
CLASSIFICAT ION WOULD BE D001.
Handling And Storage Precautions: DO NOT STORE ABOVE 115F (46C). STORE LGE QTYS
IN COMPLIANCE W/OSHA 29 CFR 1910.106. DO NOT TAKE INTERNALLY. CLOSE CONTR
AFTER EACH USE.
Other Precautions: DO NOT BREATHE SANDING DUST. EMPTY CONTRS MUST NOT BE WASHED
& REUSED FOR ANY PURPOSE. CONTRS SHOULD BE GROUNDED & BONDED TO
RECEIVING CONTR. DO NOT WELD, BRAZE/CUT ON EMPTY CONTR. NEVER USE PRESS TO
EMPTY. DRUM IS NOT A PRESS VESSEL.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: 24.0F,-4.4C
Lower Limits: 1.0%
Upper Limits: 10.0%
Extinguishing Media: USE NFPA CLASS B FIRE EXTINGS (CARBON DIOXIDE, ALL PURPOSE
DRY CHEM/ALCOHOL FOAM) DESIGNED TO EXTING FLAM LIQ (SUP DAT)
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL EXPOSED CONTRS TO PVNT
PRESS BUILD-UP & POSS AUTO- (SUP DAT)
Unusual Fire/Explosion Hazard: DURING EMER CNDTNS, OVEREXPOSURE TO
DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMED
APPARENT. OBTAIN MEDICAL ATTN. WARNING! FLAMM!
=======================================================
Control Measures
=======================================================
Respiratory Protection: PROPER SELECTION OF RESP PROT DEPENDS UPON MANY FACTORS
INCL DURATION/LEVEL OF EXPOS & CNDTNS OF USE. IN GEN EXPOS TO ORG CHEMS
SUCH AS THOSE CONTAINED IN THIS PROD MAY NOT REQUIRE USE OF RESP PROT IF
USED IN WELL-VENTD AREAS.
Ventilation: PROVIDE LOC EXHST VENT IN SUFFICIENT VOL & PATTERN TO MAINTAIN
EXPOS BELOW PEL. CONT NEHC FOR MORE SPECIFIC INFO (FP N).
Protective Gloves: IMPERMEABLE (NORTH-SILVER SHIELD).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXTING MEDIA: FIRES. POLYMER FOAM PREF FOR LGE
FIRES. FIGHT FIGHT PROC: IGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER
IS USED, FOG NOZZ ARE PREF. EXPLAN OF CARCIN: CARCIN. HUMAN: LUNG. EFTS OF OV
EREXP: BUTYL KETONE. THIS SYNERGISTIC EFT HAS RESULTED IN PERIPHERAL
NEUROPATHY IN HUMANS. RPTS HAVE ASSOC PRLNG
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >175F,>79C
M.P/F.P Text: -50F,-46C
Vapor Pres: 70 @ 68F
Vapor Density: HVR/AIR
Spec Gravity: 1.4
PH: 4-7
Evaporation Rate & Reference: SLOWER THAN DIETHYL ETHER
Solubility in Water: SLIGHT
Appearance and Odor: LIQUID; SOLVENT ODOR
Percent Volatiles by Volume: 43
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID EXCESSIVE HEAT (>115F/46C) AND SOURCES OF
IGNITION.
Materials To Avoid: STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
Hazardous Decomposition Products: BURNING, INCLUDING WHEN HEATED BY WELDING OR
CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: EN ALKYD SEMIGLOSS LOW VOC GREEN 24664, 775480 07
Company: PRATT & LAMBERT
Street: 250 PETTIT AVE
PO Box: 2153
City: BELLMORE NY
Zipcode: 11710
Health Emergency Phone: 800-255-3924
Label Required IND: Y
Date Of Label Review: 02/23/1998
Status Code: C
Label Date: 02/23/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE LIQUID CLASS IB. ACUTE: INGESTION: CAN CAUSE
GI IRRITATION, NAUSEA, AND VOMITING. ASPIRATION OF MATERIAL INTO LUNGS MAY
CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. INHALATION: MAY CAUSE N OSE OR
THROAT IRRITATION. HIGH CONCENTRATIONS MAY CAUSE ACUTE CNS DEPRESSION
INCLUDING HEADACHE, DIZZINESS, NAUSEA AND CONFUSION. EYE: MAY CAUSE
IRRITATION. SKIN: LIQUID MATERIAL MAY BE ABSORBED THROU GH SKIN IN HARMFUL
AMOUNTS. MAY CAUSE DEFATTING AND IRRITATION. CHRONIC: CANCERHAZARD. CONTAINS
CRUSTALLINE SILICA QUARTZ, WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N).
OVEREXPOSURE MAY INJURE LI VER, KIDNEYS, LUNGS AND BLOOD.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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| ALL PAGES On Chemical Property IN THIS GROUP
| | NAME | CAS |
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DRILINE INK, RED
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DRILINE INK, GREEN
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DRILINE INK, ORANGE
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DRILINE INK, BROWN
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DRILINE INK, PURPLE
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DRILINE INK, YELLOW
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DEEP BASE 64-105, CRAFT KOTE INTERIOR LATEX (SUPDAT)
| 1317-65-3
1332-58-7
1318-94-1
24937-78-8
14808-60-7
13463-67-7
25067-01-0
7732-18-5 |
|
INTERIOR FLAT VINYL LATEX 69-705, CRAFT KOTE (SUPDAT)
| 1317-65-3
1332-58-7
1318-94-1
24937-78-8
14808-60-7
13463-67-7
25067-01-0
7732-18-5 |
|
PASTEL BASE 64-102, CRAFT KOTE INTERIOR LATEX(SUPDAT)
| 1317-65-3
1332-58-7
1318-94-1
24937-78-8
14808-60-7
13463-67-7
25067-01-0
7732-18-5 |
|
HEAVY DUTY GRAY LO-VOC PVC CEMENT, 31860
| |
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HEAVY DUTY GRAY LO-VOC PVC CEMENT, 31816
| |
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HEAVY DUTY GRAY LO-VOC PVC CEMENT, 31862
| |
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HEAVY DUTY GRAY LO-VOC PVC CEMENT, 31863
| |
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HEAVY DUTY GRAY LO-VOC PVC CEMENT, 31864
| |
|
ANTIQUE WHITE 53-931, PRO KOTE LATEX SEMI (SUPDAT)
| 25265-77-4
107-21-1
13463-67-7
7732-18-5 |
|
BONE WHITE 53-918, PRO KOTE LATEX SEMI (SUPDAT)
| 25265-77-4
107-21-1
13463-67-7
7732-18-5 |
|
OYSTER WHITE 53-826, PRO KOTE LATEX SEMI (SUPDAT)
| 25265-77-4
107-21-1
13463-67-7
7732-18-5 |
|
SHELL WHITE 53-910, PRO KOTE LATEX SEMI (SUPDAT)
| 25265-77-4
107-21-1
13463-67-7
7732-18-5 |
|
TONED WHITE 53-902, PRO KOTE LATEX SEMI (SUPDAT)
| 25265-77-4
107-21-1
13463-67-7
7732-18-5 |
|
NITRIC ACID ACS GRADE, 152
| 7697-37-2
7732-18-5 |
|
CHROMAVER 3, 12066
| 7790-62-7
7487-88-9 |
|
ACID REAGENT, 2126
| 7790-62-7 |
|
PRIMER EPOXY CTG CORR INHIB, E90H00226
| |
|
3033 HANDICAP BLUE ACRYLIC W/B TRAFFIC, 3033
| 112-34-5
1336-21-6
25265-77-4 |
|
4775A BLACK WATER-BASED TRAFFIC PAINT, 4775A
| 112-34-5
67-56-1 |
|
00-0120
| 108-05-4 |
|
HOT MELT ADHESIVE, 00-0710
| |
|
PYR AFI-12P 12P, 80250020
| |
|
MIRROR FINISH, 2449
| 111-90-0 |
|
HILCO SCRUB, 3232
| |
|
SUPER BRITE COIL CL, 3116
| 1310-73-2 |
|
GUN DEGREASER, 2735
| 111-76-2
1310-58-3 |
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SELTECT 574
| |
|
PERMALITE 462 CLEAR PVC/CPVC/ABS MULTI-PURPOSE
| 109-99-9
78-93-3
108-94-1 |
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JANITOL
| 7732-18-5 |
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CHROMATE CHECK SWABS, 7CR8
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CADMIUMCHECK SWABS, 5CN8
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NICKELCHECK SWABS, 5N18
| |
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TURCO 6813E, M1604
| |
|
EN ALKYD SEMIGLOSS LOW VOC GREEN 24664, 775480 07
| 123-86-4
100-41-4
1330-20-7
13463-67-7
112945-52-5
14807-96-6
14808-60-7
110-12-3
78-93-3 |
|
BUFF, 5447 05M
| |
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ARCOPLUS AIRCRAFT DEICING FLUID
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TECHTHANE-13 CATALYST
| |
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TECHTHANE-13 COMPONENT B (RESIN)
| |
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CREST 2605 A
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CREST 2605 B
| |
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TECHGRIP M3
| |
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TECHGRIP FG1
| |
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