barium sulfate s-triazine-2,4,6(1h,3h,5h)-trione, 1,3,5-tris(2,3- epoxypropyl)-; titanium oxide; (titanium dioxide) c.i. pigment yellow 42/ % (wt): 0.5-1.5 dust, nuisance; (nuisance dust) supdat: expos could cause benign pneumoconiosis called baritosis. ing 7: expos to high levels (250 mg/kg) of titanium dioxide causes ing 8: occurs at lower expos levels & may be due to high levels ing 9: relevance of this data to humans is not significant where tlv is vent: or acgih's tlv twa limit.
HERBERTS-O BRIEN INC -- CHARGER GRAY, PFH604S8055
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Material Safety Data Sheet
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MSDS Num: CGTVY
MSDS NAME: CHARGER GRAY, PFH604S8055
Responsible Party
Name: HERBERTS-O BRIEN INC
Address: 9800 GENARD RD
City: HOUSTON TX 77041-7624
Info Phone: 713-939-4000
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
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Contractor Summary
=======================================================
Name: DUPONT POWDER COATINGS
Address: 9800 GENARD RD
City: HOUSTON TX 77041-7624
Phone: 713-939-4000
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Ingredients
=======================================================
Cas: 7727-43-7
RTECS #: CR0600000
Name: BARIUM SULFATE
% Wt: 10-30
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 2451-62-9
RTECS #: XZ1994900
Name: S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3,5-TRIS(2,3- EPOXYPROPYL)-;
(1,3,5-TRIGLYCIDYL ISOCYANURATE)
% Wt: 3-7
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 1-5
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 51274-00-1
Name: C.I. PIGMENT YELLOW 42/ % (WT): 0.5-1.5
% Wt: <1.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: DUST, NUISANCE; (NUISANCE DUST)
% Wt: 100
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: EXPOS COULD CAUSE BENIGN PNEUMOCONIOSIS CALLED BARITOSIS.
TITANIUM DIOXIDE: LAB STUDIES SHOW THAT INHAL
-----------------------------
Name: ING 7: EXPOS TO HIGH LEVELS (250 MG/KG) OF TITANIUM DIOXIDE CAUSES
CANCEROUS TUMORS IN RATS. THIS RESPONSE
-----------------------------
Name: ING 8: OCCURS AT LOWER EXPOS LEVELS & MAY BE DUE TO HIGH LEVELS
OVERWHELMING NORMAL LUNG CLEARANCE MECHANISMS.
-----------------------------
Name: ING 9: RELEVANCE OF THIS DATA TO HUMANS IS NOT SIGNIFICANT WHERE TLV IS
OBSERVED.
-----------------------------
Name: VENT: OR ACGIH'S TLV TWA LIMIT.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: 1,3,5-TRIGLYCIDYL ISOCYANURATE: INGEST: MOD TOXIC.
SYMPS ARE NOT FULLY KNOWN, MAY INCL LOSS OF APPETITE & NOSE BLEEDING.
INHAL: IRRIT TO UPPER RESP TRACT. MAY CAUSE NOSEBLEEDS. EYE CONT: IRRIT.
SKIN CONT: IRRIT. CAN BE ABSORBED THRUSKIN IN HARMFUL AMTS. EFTS SIMILAR TO
INGEST. BARIUM SULFATE: (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: INHAL OF DUSTS CNTNG BARIUM
SULFATE MAY BE IRRIT TO RESP TRACT. CONT W/EYES MAY ALSO CAUSE IRRIT.
TITANIUM DIOXIDE: INGEST: LOW ORAL TOX. NO TOXIC EFTS DUE TO INGEST ARE
DESCRIBED IN LITERAT URE. INHAL: IRRIT TO UPPER RESP TRACT. EYE CONT: IRRIT.
CHRONIC: 1,3,5-TRIGLYCIDYL ISOCYANURATE: IRRIT OF EYES, (SUPDAT)
Medical Cond Aggravated By Exposure: 1,3,5-TRIGLYCIDYL ISOCYANURATE:
RESPIRATORY ILLNESS & DERMATITIS MAY BE AGGRAVATED BY EXCESSIVE EXPOSURE.
First Aid: EYE CONT: FLUSH W/COOL WATER FOR @ LST 15 MINS, OCCASNLY LIFTING
LIDS TO ENSURE THOROUGH RINSING. SEEK MED ASSISTANCE. SKIN CONT: WASH
THOROUGHLY W/SOAP & WATER. INHAL: REMOVE FROM AREA TO FRESH AIR. INGEST:
DRINK 1 OR 2 GLASSES OF WATER &INDUCE VOMITING BY PLACING FINGER AT BACK
OF THROAT. SEEK MEDICAL ASSISTANCE.
=======================================================
Handling and Disposal
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Spill Release Procedures: SWEEP UP CAREFULLY OR USE EXPLOSION-PROOF VACUUM
CLEANER, THEN DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: MANAGE OR DISPOSE IN ACCORDANCE WTIH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
Handling And Storage Precautions: KEEP CONTAINERS SEALED AND AVOID STATIC
ELECTRICITY DISCHARGES. KEEP ALL EQUIPMENT CLEAN & PROPERLY GROUNDED TO
AVOID STATIC ELECTRICITY DISCHARGE.
Other Precautions: KEEP WORK AREAS FREE OF DUST. AVOID EXCESSIVE SKIN CONTACT.
DO NOT INGEST OR INHALE. KEEP OUT OF REACH OF CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: FOAM, CO*2, DRY CHEMICAL, WATER FOG, DRY SAND.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE A PROPERLY FITTED NIOSH APPROVED MECHANICAL
RESPIRATOR OR MASK TO AVOID BREATHING DUST. CAREFULLY FOLLOW RESPIRATOR
MANUFACTURER'S INSTRUCTIONS FOR USE.
Ventilation: PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR CONTAM
CONC BELOW APPLIC OSHA PERMISSIBLE EXPOS LEVELS
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
PROTECTIVE OVERALLS RECOMMENDED.
Work Hygienic Practices: REMOVE AND WASH SOILED CLOTHING.
Supplemental Safety and Health: EFTS OF OVEREXP: SKIN & RESP TRACT; LOSS OF
APPETITE, MAY CAUSE NOSEBLEEDS; TOXIC BY INGEST & IF ABSORBED THRU SKIN.
PRLNGD/RPTD CONT MAY CAUSE SKIN SENSITIZ. ANIMAL STUDIES SHOW THAT OVEREXP
CAN RSLT IN TOXIC EFTS TO TESTES, POSS EFTS ON LIVER & LUNG, & POSS
ADVERSE MALE REPROD EFTS. BARIUM SULFATE: PRLNGD
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.477
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NOT KNOWN
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: FUMES MAY CONTAIN CO, CO*2, NO*2 OR OTHER
NITROGEN COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Other Information: VOLATILE ORGANIC COMPOUND: 0
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HAZCOM Label
=======================================================
MSDS NAME: CHARGER GRAY, PFH604S8055
Company: DUPONT POWDER COATINGS
Street: 9800 GENARD RD
City: HOUSTON TX
Zipcode: 77041-7624
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 04/08/1998
Status Code: C
Label Date: 04/08/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: 1,3,5-TRIGLYCIDYL ISOCYANURATE: INGEST: MODERATE
TOXICITY. POSSIBLE LOSS OF APPETITE & NOSE BLEEDING. INHAL: IRRITATION.
NOSEBLEEDS. EYE & SKIN CONT: IRRITATION. CAN BE ABSORBED THRU SKIN IN HA
RMFUL AMOUNTS. BARIUM SULFATE: IRRITATION TO RESPIRATORY TRACT. EYE CONT:
IRRITATION. TITANIUM DIOXIDE: INGEST: LOW ORAL TOX. INHAL: IRRITATION. EYE:
IRRITATION. CHRONIC: 1,3,5-TRIGLYCIDYL ISOCYANURAT E: IRRITATION OF EYES,
SKIN & RESP TRACT; LOSS OF APPETITE, NOSEBLEEDS; TOXIC BY INGEST & IF
ABSORBED THRU SKIN. SKIN SENSITIZATION. REPRODUCTIVE EFFECTS. LIVER AND LUNG
DAMAGE. BARIUM SULFATE: BARITO SIS. TITANIUM DIOXIDE - POSSIBLE CANCEROUS
TUMORS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
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and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.