ing 21:tags/lbls thereon) cntng brazing/welding filler metals, fluxes ing 22:regs under 29cfr1910.252 "welding, cutting & brazing." also ing 23:in work environ", appendix b, section b2 "welding fumes" for efts of overexp:by some investigators to affect pulm func. arc rays can msds toxicity property">
argon. bp:-302.6f,-185.9c. vp:above critical temp of -188.1f,-122.3c. supp data:train welder to keep his head out of the fumes. eye prot:full lgth fshld (fp n) w/filter lens. as gen rule, start w/shade ing 4:then go to next lighter shade which gives sufficient view of weld ing 5:if necessary, to shield others from arc rays radiation which can other prot equip:to pvnt injury from radia, spks & elec shock. see ing 7:aprons, hats, shoulder prot, as well as dark substantial clthg. ing 8:to insulate himself from work and ground. other prec:use a check valve/trap in discharge line to pvnt haz back flow ing 10:store in cool, dry, well-vented area away from heavily trafficked ing 11:where cyls are stored to exceed 125f(52c). cyls should be stored ing 12:or being knocked over. full & empty cyls should be segregated. ing 13:pvnt full cyls being stored for excessive periods of time. for ing 14:gas assoc's pamphlets p-1, p-9, p-14, sfty bulletin sb-2. this ing 15:structural matls. compressed gas cyls should not be refilled ing 16:gases. shipment of compressed gas cyl which has not been filled by ing 17:violation of fed law (49 cfr). always secure cyls in upright ing 18:transport cyls in trunks of vehicles, enclsd vans, truck cabs/in ing 19:secured in open flatbed/in open pick-up type vehicles. caut:avoid ing 20:see ansi z49.1 "sfty in welding & cutting" published by aws. ing 21:tags/lbls thereon) cntng brazing/welding filler metals, fluxes ing 22:regs under 29cfr1910.252 "welding, cutting & brazing." also ing 23:in work environ", appendix b, section b2 "welding fumes" for efts of overexp:by some investigators to affect pulm func. arc rays can msds toxicity property">
MSDS
:
BLUESHIELD 6.7
CAS
:
124-38-9 7440-37-1
NAME
:
carbon dioxide. bp:-109.3f,-78.5c (sublimation point). vp:856 psia. argon. bp:-302.6f,-185.9c. vp:above critical temp of -188.1f,-122.3c. supp data:train welder to keep his head out of the fumes. eye prot:full lgth fshld (fp n) w/filter lens. as gen rule, start w/shade ing 4:then go to next lighter shade which gives sufficient view of weld ing 5:if necessary, to shield others from arc rays radiation which can other prot equip:to pvnt injury from radia, spks & elec shock. see ing 7:aprons, hats, shoulder prot, as well as dark substantial clthg. ing 8:to insulate himself from work and ground. other prec:use a check valve/trap in discharge line to pvnt haz back flow ing 10:store in cool, dry, well-vented area away from heavily trafficked ing 11:where cyls are stored to exceed 125f(52c). cyls should be stored ing 12:or being knocked over. full & empty cyls should be segregated. ing 13:pvnt full cyls being stored for excessive periods of time. for ing 14:gas assoc's pamphlets p-1, p-9, p-14, sfty bulletin sb-2. this ing 15:structural matls. compressed gas cyls should not be refilled ing 16:gases. shipment of compressed gas cyl which has not been filled by ing 17:violation of fed law (49 cfr). always secure cyls in upright ing 18:transport cyls in trunks of vehicles, enclsd vans, truck cabs/in ing 19:secured in open flatbed/in open pick-up type vehicles. caut:avoid ing 20:see ansi z49.1 "sfty in welding & cutting" published by aws. ing 21:tags/lbls thereon) cntng brazing/welding filler metals, fluxes ing 22:regs under 29cfr1910.252 "welding, cutting & brazing." also ing 23:in work environ", appendix b, section b2 "welding fumes" for efts of overexp:by some investigators to affect pulm func. arc rays can
LIQUID AIR CORP -- BLUESHIELD 6.7
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CHNRJ
MSDS NAME: BLUESHIELD 6.7
Responsible Party
Name: LIQUID AIR CORP
Address: 2121 N CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Info Phone: 415-977-6500
Emergency Phone Number: 415-977-6500
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Phone: 415-977-6500
=======================================================
Ingredients
=======================================================
Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE. BP:-109.3F,-78.5C (SUBLIMATION POINT). VP:856 PSIA.
MP:-69.8F,-56.6C. SOL IN H*2O:SOLUBLE.
OSHA PEL: 5000 PPM
ACGIH TLV: 5000 PPM;30000 STEL
------------------------------
Cas: 7440-37-1
RTECS #: CF2300000
Name: ARGON. BP:-302.6F,-185.9C. VP:ABOVE CRITICAL TEMP OF -188.1F,-122.3C.
MP:-308.9F,-189.4C. SOL IN H*2O:NEGLIGIBLE.
OSHA PEL: N/K (FP N)
ACGIH TLV: ASPHYXIANT
------------------------------
Name: SUPP DATA:TRAIN WELDER TO KEEP HIS HEAD OUT OF THE FUMES.
-----------------------------
Name: EYE PROT:FULL LGTH FSHLD (FP N) W/FILTER LENS. AS GEN RULE, START W/SHADE
WHICH IS TOO DARK TO SEE WELD ZONE.
-----------------------------
Name: ING 4:THEN GO TO NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF WELD
ZONE. PROVIDE PROT SCREENS & FLASH GOGGS,
-----------------------------
Name: ING 5:IF NECESSARY, TO SHIELD OTHERS FROM ARC RAYS RADIATION WHICH CAN
INJURE EYES & BURN SKIN.
-----------------------------
Name: OTHER PROT EQUIP:TO PVNT INJURY FROM RADIA, SPKS & ELEC SHOCK. SEE
ANSI Z49.1. THIS MAY INCL ARM PROTECTORS,
-----------------------------
Name: ING 7:APRONS, HATS, SHOULDER PROT, AS WELL AS DARK SUBSTANTIAL CLTHG.
TRAIN WELDER NOT TO TOUCH LIVE ELEC PARTS &
-----------------------------
Name: ING 8:TO INSULATE HIMSELF FROM WORK AND GROUND.
-----------------------------
Name: OTHER PREC:USE A CHECK VALVE/TRAP IN DISCHARGE LINE TO PVNT HAZ BACK FLOW
INTO CYL. PROT CYLS FROM PHYSICAL DMG.
-----------------------------
Name: ING 10:STORE IN COOL, DRY, WELL-VENTED AREA AWAY FROM HEAVILY TRAFFICKED
AREAS & EMER EXITS. DO NOT ALLOW TEMP
-----------------------------
Name: ING 11:WHERE CYLS ARE STORED TO EXCEED 125F(52C). CYLS SHOULD BE STORED
UPRIGHT & FIRMLY SECURED TO PVNT FALLING
-----------------------------
Name: ING 12:OR BEING KNOCKED OVER. FULL & EMPTY CYLS SHOULD BE SEGREGATED.
USE "FIRST IN-FIRST OUT" INVENTORY SYS TO
-----------------------------
Name: ING 13:PVNT FULL CYLS BEING STORED FOR EXCESSIVE PERIODS OF TIME. FOR
ADDNL HNDLG/STOR RECS, CONSULT COMPRESSED
-----------------------------
Name: ING 14:GAS ASSOC'S PAMPHLETS P-1, P-9, P-14, SFTY BULLETIN SB-2. THIS
MIXT IS NONCORR & MAY BE USED W/ANY COMMON
-----------------------------
Name: ING 15:STRUCTURAL MATLS. COMPRESSED GAS CYLS SHOULD NOT BE REFILLED
EXCEPT BY QUALIFIED PRODUCERS OF COMPRESSED
-----------------------------
Name: ING 16:GASES. SHIPMENT OF COMPRESSED GAS CYL WHICH HAS NOT BEEN FILLED BY
OWNER/WITH HIS (WRITTEN) CONSENT IS A
-----------------------------
Name: ING 17:VIOLATION OF FED LAW (49 CFR). ALWAYS SECURE CYLS IN UPRIGHT
POSITION BEFORE TRANSPORTING THEM. NEVER
-----------------------------
Name: ING 18:TRANSPORT CYLS IN TRUNKS OF VEHICLES, ENCLSD VANS, TRUCK CABS/IN
PASSENGER COMPARTMENTS. TRANSPORT CYLS
-----------------------------
Name: ING 19:SECURED IN OPEN FLATBED/IN OPEN PICK-UP TYPE VEHICLES. CAUT:AVOID
BRTHG FUMES & GASES. USE ADEQ VENT.
-----------------------------
Name: ING 20:SEE ANSI Z49.1 "SFTY IN WELDING & CUTTING" PUBLISHED BY AWS.
CONSULT HAZ WARNINGS ON BOXES/CNTNRS (OR ON
-----------------------------
Name: ING 21:TAGS/LBLS THEREON) CNTNG BRAZING/WELDING FILLER METALS, FLUXES
& FUSIBLE GRANULAR MATLS. SEE OSHA SFTY
-----------------------------
Name: ING 22:REGS UNDER 29CFR1910.252 "WELDING, CUTTING & BRAZING." ALSO
SEE ACGIH "TLV(1991-1992) FOR CHEM SUBSTANCES
-----------------------------
Name: ING 23:IN WORK ENVIRON", APPENDIX B, SECTION B2 "WELDING FUMES" FOR
FURTHER INFO. FOR MORE INFO, CONTACT NEHC (FP N).
-----------------------------
Name: EFTS OF OVEREXP:BY SOME INVESTIGATORS TO AFFECT PULM FUNC. ARC RAYS CAN
INJURE EYES & BURN SKIN. ELEC SHOCK CAN KILL.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CONCS OF 20-30% OF THESE MIXTS WHEN INHAL W/ADEQ OXYG IN
AIR WILL CAUSE INCR IN RESP RATE. HIGHER CONCS WILL CAUSE HDCH, NAUS &
EVENTUAL UNCON. CARBON DIOXIDE IS MOST POWERFUL CEREBRAL VASODILATOR KNO WN.
INHAL LG CONCS CAUSES RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA &
DEATH. CHRONIC HARMFUL EFTS(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:ARE NOT KNOWN FROM RPTD INHAL OF
LOW(20-30%) CONCS OF MIXT. CAUT:WELDING/BRAZING MAY PRDCE FUMES & GASES
HAZ TO HLTH. ACUTE OVEREXP TO WELDING FUMES MAY RSLT IN DISCOMFORT SUCH
AS:DIZZ, NAUS, DRYNESS/IRRIT OF NOSE, THROAT/EYES. CHRONIC OVEREXP MAY LEAD
TO SIDEROSIS(IRON DEPOSITS IN LUNGS) & IS BELIEVED
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO THESE MIXTURES SHOULD NOT BE ALLOWED TO
WORK WITH OR HANDLE THESE PRODUCTS.
First Aid: PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP TO THESE MIXTS.
RESCUE PERS SHOULD BE EQUIPPED W/NIOSH APPRVD SCBA. INGEST:CALL MD IMMED (FP
N). EYES:IMMED FLUSH W/POTABLE WATER FOR MIN OF 15 MIN S, SEEK ASSISTANCE
FROM MD (FP N). SKIN:FLUSH W/COPIOUS AMTS OF WATER. CALL MD (FP N).
INHAL:CONSCIOUS PERS SHOULD BE ASSISTED TO UNCONTAM AREA & INHALED FRESH
AIR. QUICK REMOVAL FROM CONTAM (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE
APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR CONTAINER VALVE,
CONTACT CLOSEST LIQUID AIR CORPORATION LOCATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT ATTEMPT TO DISPOSE OF WATER OR UNUSED
QUANTITIES. RETURN IN SHIPPING CONTAINER PROPERLY LABELED, W/ANY VALVE OUTLET
PLUGS OR CAPS SECURED TO MFR FOR PROPER DISPOSAL. FOR EMERGENCY DISPOSAL, CON
TACT CLOSEST LIQUID AIR CORPORATION LOCATION.
Handling And Storage Precautions: USE ONLY IN WELL-VENTILATED AREAS. VALVE
PROTECTION CAPS MUST REMAIN IN PLACE UNLESS CYLINDER IS SECURED W/VALVE
OUTLET PIPED TO USE POINT.
Other Precautions: DO NOT DRAG, SLIDE/ROLL CYLS. USE SUITABLE HAND TRUCK FOR
CYL MOVEMENT. USE PRESS REDUCING REGULATOR WHEN CONNECTING CYL TO LOWER PRESS
(<3,000 PSIG) PIPING/SYS. DO NOT HEAT CYL BY ANY MEANS TO INCR D ISCHARGE
RATE OF PROD FROM CYL.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). NONFLAMMABLE
GAS MIXTURE.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). IF CYLINDERS ARE INVOLVED IN A FIRE, SAFELY RELOCATE OR
KEEP COOL W/WATER SPRAY.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED POSITIVE PRESSURE AIR LINE W/MASK OR
SCBA SHOULD BE AVAIL FOR EMERGENCY USE. WHEN WELDING IN CONFINED SPACE/WHERE
LOC EXHST/VENT DOES NOT KEEP EXPOS BELOW WELDING FUME TLV, USE NIOSH AP PRVD
POS PRESS AIR LINE MASK OR SCBA.
Ventilation: LOC EXHST:TO PVNT ACCUM OF HIGH CONCS OF GASES SO AS TO REDUCE
OXYG LEVEL IN AIR TO <18 MOLAR PERCENT. WHEN (SUPP DATA)
Protective Gloves: WELDER'S GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS &
Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER (FP
N). SFTY SHOES. WHEN WELDING, WEAR HEAD & BODY PROT WHICH HELP
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRST AID PROC:AREA IS MOST IMPORTANT. UNCON
PERS SHOULD BE MOVED TO UNCONTAM AREA, GIVEN ASSISTED RESP & SUPP OXYG.
FURTHER TREATMENT SHOULD BE SYMPTOMATIC & SUPPORTIVE. VENT:WELDING, USE
ENOUGH VENT , LOC EXHST AT ARC/BOTH, TO KEEP WELDING FUMES & GASES BELOW
APPLIC TLV'S IN WORKER'S BRTHG ZONE & GEN AREA.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SEE INGS
M.P/F.P Text: SEE INGS
Vapor Pres: SEE INGS
Spec Gravity: 1.39 (AIR=1)
Solubility in Water: SEE INGREDIENTS
Appearance and Odor: COLORLESS, ODORLESS GAS.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE.
Materials To Avoid: NONE.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: BLUESHIELD 6.7
Company: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Street: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA
Zipcode: 94596
Health Emergency Phone: 415-977-6500
Label Required IND: Y
Date Of Label Review: 08/03/1998
Status Code: C
Label Date: 08/03/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:CONCENTRATIONS OF 20-30% OF THESE MIXTURES WHEN
INHALED WITH ADEQUATE OXYGEN IN AIR WILL CAUSE INCREASE IN RESPIRATORY RATE.
HIGHER CONCENTRATIONS WILL CAUSE HEADACHE, NAUSEA AND EVENTUAL UNCONS
CIOUSNESS. CARBON DIOXIDE IS THE MOST POWERFUL CEREBRAL VASODILATOR KNOWN.
INHALING LARGE CONCENTRATIONS CAUSES RAPID CIRCULATORY INSUFFICIENCY LEADING
TO COMA AND DEATH. CHRONIC:SIDEROSIS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.