1-propene,1,1,2,3,3,3-hexafluoro-, polymer with 1,1-difluoroethene and carbon black calcium hydroxide magnesium oxide bisphenol af 4,4'-dichlorodiphenyl sulfone volatile organic compound: not determined; voc less h*2o & exempt supdat: this matl in normal storage & handling has not been reported ing 8: however, under normal processing cndtns, eg grinding or heating, ing 9: of variable composition based on specific process conditions. ing 10: or any of health efts listed above when emissions are present at waste disp meth: permitted to accept chemical waste. resp prot: regulations: half-mask supplied air respirator. vent: local exhaust for heat curing. use in a well-ventilated area.
3M GENERAL OFFICES -- TX-4400 ETAB SYSTEM
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CHNZJ
MSDS NAME: TX-4400 ETAB SYSTEM
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-737-6501
Emergency Phone Number: 800-364-3577
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
=======================================================
Ingredients
=======================================================
Cas: 25190-89-0
Name: 1-PROPENE,1,1,2,3,3,3-HEXAFLUORO-, POLYMER WITH 1,1-DIFLUOROETHENE AND
TETRAFLUOROETHENE
% Wt: 68-72
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1333-86-4
RTECS #: FF5800000
Name: CARBON BLACK
% Wt: 20-22
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
------------------------------
Cas: 1305-62-0
RTECS #: EW2800000
Name: CALCIUM HYDROXIDE
% Wt: 3-6
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 5 MG/M3
------------------------------
Cas: 1309-48-4
RTECS #: OM3850000
Name: MAGNESIUM OXIDE
% Wt: 1-4
OSHA PEL: 15 MG/M3 PARTICULATE
ACGIH TLV: 10 MG/M3 FUME
------------------------------
Cas: 1478-61-1
Name: BISPHENOL AF
% Wt: 0.5-1.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 80-07-9
RTECS #: WR3450000
Name: 4,4'-DICHLORODIPHENYL SULFONE
% Wt: 0.5-1.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: NOT DETERMINED; VOC LESS H*2O & EXEMPT
SOLVENTS: NOT DETERMINED
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: THIS MATL IN NORMAL STORAGE & HANDLING HAS NOT BEEN REPORTED
TO CAUSE SIGNIFICANT ADVERSE HEALTH EFTS.
-----------------------------
Name: ING 8: HOWEVER, UNDER NORMAL PROCESSING CNDTNS, EG GRINDING OR HEATING,
THIS PRODUCT MAY RELEASE FUMES & VAPS
-----------------------------
Name: ING 9: OF VARIABLE COMPOSITION BASED ON SPECIFIC PROCESS CONDITIONS.
THESE PROCESS RELEASES MAY PRODUCE IRRIT
-----------------------------
Name: ING 10: OR ANY OF HEALTH EFTS LISTED ABOVE WHEN EMISSIONS ARE PRESENT AT
ELEVATED CONCS. USE W/APPROP LOC EXHST VENT.
-----------------------------
Name: WASTE DISP METH: PERMITTED TO ACCEPT CHEMICAL WASTE.
-----------------------------
Name: RESP PROT: REGULATIONS: HALF-MASK SUPPLIED AIR RESPIRATOR.
-----------------------------
Name: VENT: LOCAL EXHAUST FOR HEAT CURING. USE IN A WELL-VENTILATED AREA.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: EYE CONTACT: DURING PROCESSING OR FABRICATION: VAPS FROM
HEATED MATL MAY CAUSE EYE IRRIT. DURING END USE: CONTACT W/EYES DURING PROD
USE IS NOT EXPECTED TO RSLT IN SIGNIFICANT IRRIT. SKIN CONTACT: DUR ING
PROCESSING OR FABRICATION: SKIN BURNS (THERMAL, FROM CONTACT W/HOT MATL):
SIGNS/SYMPS CAN INCLUDE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS, VOL 65, PG 149,
1996:GROUP 2B.
Signs And Symptions Of Overexposure: HLTH HAZ: BURNING PAIN, RED & SWOLLEN
SKIN & BLISTERS. DURING END USE: CONTACT W/SKIN DURING PROD USE NOT
EXPECTED TO RSLT IN SIGNIFICANT IRRIT. INHAL: DURING PROCESSING OR
FABRICATION: VAPS OF HEATED MATL MAY CAUSE RESP SYS IRRIT. DURING END USE:
HEALTH EFTS FROM INHAL ARE NOT EXPECTED UNLESS PROD IS HEATED. (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST: CALL MD IMMED (FP N). EYES: IMMED FLUSH W/LG AMTS OF WATER
FOR AT LEAST 15 MIN. GET IMMED MED ATTN. SKIN: FLUSH SKIN W/LG AMTS OF WATER.
IF IRRIT PERSISTS, GET MED ATTN. IMMED FLUSH AFFECTED A REA W/PLENTY OF COLD
WATER & COVER W/CLEAN DRESSING. DO NOT ATTEMPT TO REMOVE MOLTEN MATL.
HAVE BURN TREATED BY MD. INHAL: IF SIGNS/SYMPS OCCUR, REMOVE TO FRESH AIR. IF
SIGNS/SYMPS CONTINUE, CALL MD.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFORMATION
REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION
AND PERSONAL PROTECTIVE EQUIPMENT. COLLECT SPILLED MATERIAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGS
(FP N). INCINERATE IN PERMITTED HAZ WASTE INCINERATOR IN PRESENCE OF COMBUST
MATL. COMBUST PRODS WILL INCL HF. DISPOSE OF WASTE PROD IN SANITARY LAND
FILL. DISPOSE OF WASTE PROD IN FACILITY
Handling And Storage Precautions: STORE AWAY FROM HEAT. KEEP AWAY FROM ALUMINUM
AND ZINC. KEEP CONTAINER DRY.
Other Precautions: WASH HANDS AFTER HANDLING AND BEFORE EATING. NO SMOKING
WHILE HANDLING THIS MATERIAL.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N) INCL
HELMET, BUNKER COAT & PANTS, BANDS AROUND ARMS, WAIST & LEGS,
FACEMASK & PROT COVERING FOR EXPOS AREAS OF HEAD.
Unusual Fire/Explosion Hazard: SEE HAZARDOUS DECOMPOSITION SECTION FOR PRODUCTS
OF COMBUSTION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: DURING PROCESSING OR FABRICATION: AVOID BRTHG VAPS
CREATED DURING CURE CYCLE. AVOID BRTHG AIRBORNE MATL. IF THERMAL DECOMP
OCCURS: SELECT ONE OF FOLLOWING NIOSH APPRVD RESPS BASED ON AIRBORNE CONC OF
CONTAMINANTS & I/A/W OSHA
Ventilation: GEN VENT ADEQ BELOW 400C. LOCAL EXHAUST RECOM ABOVE 400C. DURING
PROCESSING OR FABRICATION: PROVIDE APPROP
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: AVOID PROLONGED OR REPEATED SKIN CONTACT OR SKIN
CONTACT WITH HOT MATERIAL. AVOID EYE CONTACT.
Supplemental Safety and Health: HAZ DECOMP PRODS: TEMPS ABOVE 400C,
FLUOROELASTOMER COMPONENT OF THIS PROD MAY BEGIN TO DECOMPOSE W/EVOLUTION OF
HF. EFTS OF OVEREXP: INGEST: DURING PROCESSING OR FABRICATION: INGEST IF NOT
LIKELY ROU TE OF EXPOS TO THIS PROD. DURING END USE: NO ADVERSE HEALTH EFTS
EXPECTED FROM SWALLOWING. OTHER: EXPOS TO
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.8 (H*2O=1)
Solubility in Water: NEGLIGIBLE
Appearance and Odor: BLACK ODORLESS SOLID.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HIGH SHEAR/TEMPERATURE CONDITIONS.
Materials To Avoid: AL OR MG POWDER.
Hazardous Decomposition Products: CARBON MONOXIDE & CARBON DIOXIDE, HYDROGEN
FLUORIDE, CARBONYL FLUORIDE, TOX VAPS, GASES OR PARTICULATES. AT (SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
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Ecological Information
=======================================================
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MSDS Transport Information
=======================================================
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Regulatory Information
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Other Information
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=======================================================
HAZCOM Label
=======================================================
MSDS NAME: TX-4400 ETAB SYSTEM
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 800-364-3577
Label Required IND: Y
Date Of Label Review: 08/06/1998
Status Code: C
Label Date: 08/06/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYES: VAPORS FROM HEATED MATERIAL MAY CAUSE EYE
IRRITATION. SKIN: CONTACT WITH HOT MATERIAL CAN CAUSE BURNING PAIN, RED AND
SWOLLEN SKIN AND BLISTERS. INHALATION: VAPORS OF HEATED MATERIAL MAY CAUSE
RESPIRATORY SYSTEM IRRITATION. CHRONIC: CANCER HAZARD. CONTAINS CARBON BLACK
WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.