calcium hypochlorite (cercla) sodium chloride calcium chlorate calcium chloride calcium hydroxide calcium carbonate water supp data:perm lung damage. ingest:irrit &/or burns can occur to ing 8:charact by naus, vomit, diarr, abdom pain, bleeding &/or tiss ing 9:effects from chronic exposure.
LOS ANGELES CHEMICAL CO -- CALCIUM HYPOCHLORITE GRANULAR, LACCO
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Material Safety Data Sheet
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MSDS Num: CHNRN
MSDS NAME: CALCIUM HYPOCHLORITE GRANULAR, LACCO
Responsible Party
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE STREET
City: SOUTH GATE CA 90280
Info Phone: 213-562-9500
Emergency Phone Number: 213-562-9500
Preparer's Name: B. MARTINEZ
Published: Y
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Contractor Summary
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Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280
Phone: 213-562-9500
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Ingredients
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Cas: 7778-54-3
RTECS #: NH3485000
Name: CALCIUM HYPOCHLORITE (CERCLA)
% Wt: 65-75
OSHA PEL: 0.5 PPM (CL)
ACGIH TLV: 0.5 PPM;1 STEL (CL)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 7647-14-5
RTECS #: VZ4725000
Name: SODIUM CHLORIDE
% Wt: 10-20
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 10137-74-3
RTECS #: FN9800000
Name: CALCIUM CHLORATE
% Wt: 0-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 10043-52-4
RTECS #: EV9800000
Name: CALCIUM CHLORIDE
% Wt: 0-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1305-62-0
RTECS #: EW2800000
Name: CALCIUM HYDROXIDE
% Wt: 0-4
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 5 MG/M3
------------------------------
Cas: 471-34-1
RTECS #: FF9335000
Name: CALCIUM CARBONATE
% Wt: 0-4
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: 0-5.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: SUPP DATA:PERM LUNG DAMAGE. INGEST:IRRIT &/OR BURNS CAN OCCUR TO
ENTIRE GI TRACT, INCL STOMACH & INTESTINES,
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Name: ING 8:CHARACT BY NAUS, VOMIT, DIARR, ABDOM PAIN, BLEEDING &/OR TISS
ULCERATION. THERE ARE NO KNOWN/REPORTED
-----------------------------
Name: ING 9:EFFECTS FROM CHRONIC EXPOSURE.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE CONT:SEV IRRIT &/OR BURNS CAN OCCUR FOLLOWING
EXPOS. CONT MAY CAUSE IMPAIRMENT OF VISION & CORNEAL DMG. SKIN
CONT:DERMAL EXPOS CAN CAUSE SEV IRRIT &/OR BURNS CHARACT BY REDNESS,
SWELL & SCAB FORM. PRLNG EXPOS MAY CAUSE DESTRUCT OF DERMIS W/IMPAIRMENT
OF SKIN AT SITE OF CONT TO REGENERATE. EFTS FROM(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:CHRONIC EXPOS WOULD BE SIMILAR TO
THOSE FROM SINGLE EXPOS EXCEPT FOR EFTS SECONDARY TO TISS DESTRUCT.
INHAL:INHAL OF MATL IS IRRIT TO NOSE, THROAT & LUNGS. IT MAY ALSO CAUSE
BURNS TO RESP TRA CT W/PRODUCTION OF LUNG EDEMA WHICH CANRSLT IN SHORTNESS OF
BREATH, WHEEZING, CHOKING, CHEST PAIN & IMPAIRMENT (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES:IMMED FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS, OCCAS
LIFTING UPPER & LOWER LIDS. CALL MD AT ONCE. SKIN:IMMED FLUSH W/WATER FOR
AT LST 15 MINS. CALL MD. IF CLTHG COMES IN CONT W/PROD, CLTHG SH OULD BE
LAUNDERED BEFORE RE-USE. INHAL:REMOVE VICTIM TO FRESH AIR. SUPPORT RESP IF
NEEDED, CALL MD. INGEST:IMMED DRINK LG QTYS OF WATER. DO NOT INDUCE VOMIT.
CALL MD AT ONCE. DO NOT GIVE (SUPP DATA)
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Handling and Disposal
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Spill Release Procedures: CONTAINERIZE ALL VIRGIN MATL IN CLEAN, DRY CNTNR
USING ONLY CLEAN DEDICATED EQUIP TO CLEAN MATL UP. CONTAINERIZE ALL CONTAM
MATL IN CLEAN, DRY CNTNR & REMOVE TO WELL VENTED AREA BEING SURE TO NOT
SEAL TIGHTLY. CONTAM SPILL MATL MAY BECOME HAZ WASTE.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: IT MUST BE DISPOSED OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS IN A PERMITTED HAZARDOUS WASTE TREATMENT, STORAGE & DISPOSAL
FACILITY TREATMENT.
Handling And Storage Precautions: DO NOT TAKE INTERNALLY. AVOID CONTACT W/EYES,
SKIN OR CLOTHING. KEEP CONTAINERS TIGHTLY SEALED. STORE IN A CLEAN, DRY,
WELL-VENTILATED AREA.
Other Precautions: DO NOT STORE AT TEMPERATURES ABOVE 52C.
=======================================================
Fire and Explosion Hazard Information
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Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. DO NOT USE
EXTINGUISHERS CONTAINING AMMONIUM CMPDS.
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Control Measures
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Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF
CONCERN (FP N).
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: UPON CONTACT W/SKIN OR EYES, WASH OFF W/WATER.
Supplemental Safety and Health: PH:10.5-11.5 (1% SOLN). MATLS TO AVOID:CORR,
FLAMM/COMBUST MATLS. FIRST AID PROC:ANYTHING BY MOUTH IF PERS IS UNCON/IF
HAVING CONVLS. EYE PROT:& FULL LGTH FSHLD (FP N). EFTS OF OVEREXP:OF LUNG
FUNC. I NHAL OF HIGH CONCS CAN RSLT IN PERM LUNG DMG. CHRONIC (RPTD) INHAL
EXPOS MAY CAUSE IMPAIRMENT OF LUNG FUNC & PERM
=======================================================
Physical/Chemical Properties
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PH: SUPDAT
Solubility in Water: APPROX 18% @ 25C
Appearance and Odor: WHITE, FREE FLOWING GRANULES OR TABLET FORM PRODUCT;
CHLORINE LIKE ODOR.
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Reactivity Data
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Stability Indicator: NO
Stability Condition To Avoid: HIGH TEMPERATURES >125F, HIGH HUMIDITY.
Materials To Avoid: ACIDS, ORGANICS, NITROGEN CONTAINING CMPDS, DRY POWDER,
FIRE EXTINGS (CONTAINING MONO-AMMONIUM PHOSPHATES), (SUPP DATA)
Hazardous Decomposition Products: CHLORINE GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: CALCIUM HYPOCHLORITE GRANULAR, LACCO
Company: LOS ANGELES CHEMICAL CO
Street: 4545 ARDINE ST
PO Box: 1987
City: SOUTH GATE CA
Zipcode: 90280
Health Emergency Phone: 213-562-9500
Label Required IND: Y
Date Of Label Review: 08/03/1998
Status Code: C
Label Date: 08/03/1998
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:EYE CONTACT:SEVERE IRRITATION AND/OR BURNS CAN
OCCUR FOLLOWING EXPOSURE. CONTACT MAY CAUSE IMPAIRMENT OF VISION AND CORNEAL
DAMAGE. SKIN CONTACT:DERMAL EXPOSURE CAN CAUSE SEVERE IRRITATION AND/O R
BURNS CHARACTERIZED BY REDNESS, SWELLING AND SCAB FORMATION. PROLONGED
EXPOSURE MAY CAUSE DESTRUCTION OF DERMIS WITH IMPAIRMENT OF SKIN AT SITE OF
CONTACT TO REGENERATE. INHALATION:IRRITATION OR BUR NS TO RESPIRATORY TRACT.
INGESTION:IRRITATION OR BURNS TO GASTROINTESTINAL TRACT, ULCERATION, NAUSEA,
VOMITING. CHRONIC:LUNG DAMAGE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.