LIQUID CARBONIC -- HALOCARBON 113
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Material Safety Data Sheet
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MSDS Num: CHSPF
MSDS NAME: HALOCARBON 113
Responsible Party
Name: LIQUID CARBONIC
Address: 135 SOUTH LA SALLE ST
City: CHICAGO IL 60603-4282
Info Phone: 504-673-8831
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
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Contractor Summary
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Name: LIQUID CARBONIC
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
Name: LIQUID CARBONIC INDUSTRIES
Address: 810 JORIE BLVD.
City: OAK BROOK IL 60521-2216
Phone: 708-572-7500
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Ingredients
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Cas: 76-13-1
RTECS #: KJ4000000
Name: 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113); (HALOCARBON 113)
(SARA 313)
% Wt: >99
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM;1250 STEL
Ozone Depleting Chemical: 1
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION:CAUSES LIGHT HEADEDNESS, GIDDINESS,
DISORIENTATION, NAUSEA, VOMITING, NARCOSIS, CARDIAC DYSRHYTHMIAS, HYPOTENSION
AND EVENTUAL DEATH. SKIN & EYE:RAPIDLY EVAPORATING LIQUID MAY CAUSE
FROSTBI TE. VAPOR IS SLIGHT IRRITANT. CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRODUCED SENSIT OF MYOCARDIUM TO (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:EPINEPHRINE IN LAB ANIMALS &
COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (I.E., EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CFC'S (FP N).
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO HALOGEN 113 SHOULD NOT BE ALLOWED TO WORK
WITH OR HANDLE THIS PRODUCT.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). INHAL:REMOVE TO FRESH AIR. IF
UNCONSCIOUS OR BREATHING IS DIFFICULT, ADMINISTER ARTF RESP W/SUPP OXYGEN.
KEEP WARM & AT REST. SKIN:WASH AFFECTED AREAS W/WATER. IF FR OSTBITE,
FLUSH AFFECTED AREAS W/TEPID (105-115F) WATER. SEEK MEDICAL HELP FOR THERMAL
INJURY. EYES:WASH FOR AT LST 15 MINS W/WATER. IF FROSTBITE, FLUSH W/TEPID
WATER. SEEK MED HELP FOR THERMAL INJURY.
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Handling and Disposal
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Spill Release Procedures: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS OR VENTILATE AREA TO LESS THAN
TWA BEFORE ENTERING AREA TO STOP LEAK OR TO RETRIEVE LEAKING CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: REMOVE LEAKING CONTAINER OR DISPOSE OF WASTE BY VENTING
SLOWIN IN "DOWNWIND" REMOTE AREA. FOLLOW ALL FEDERAL, STATE & LOCAL
REGULATIONS.
Handling And Storage Precautions: PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE.
STORE IN A COOL, DRY, WELL VENTILATED AREA. DO NOT ALLOW AREA WHERE
CONTAINERS ARE STORED TO EXCEED 125F.
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC
WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE FORM OF
CHLORIDES, FLUORIDES/PHOSGENE (FP N). CNTNRS SHOULD NOT BE RECHARGED. SEE
CGA SFTY BULLETIN SB-1 & SB-5 (SUPDAT)
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Fire and Explosion Hazard Information
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Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). NONFLAMMABLE
LIQUID & VAPOR.
Fire Fighting Procedures: USE NIOSH APPROVED PRESSURE DEMAND SCBA & FULL
PROTECTIVE EQUIPMENT (FP N). IF CONTAINERS ARE EXPOSED TO FIRE, SAFELY
RELOCATE OR KEEP COOL W/WATER SPRAY.
Unusual Fire/Explosion Hazard: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
FLUORIDES, CHLORIDES & PHOSGENE (FP N). IF PRODUCT IS EXPOSED TO FIRE, IT
MAY DECOMPOSE YIELDING TOXIC PRODUCTS.
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Control Measures
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Respiratory Protection: NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IN
EVENT OF LEAK OR SPILL.
Ventilation: LOCAL EXHAUST &/OR MECHANICAL (GENERAL): TO PREVENT
ACCUMULATION ABOVE TWA.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). SAFETY SHOES.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: OTHER PREC:CONCERNING HAZARDS ASSOCIATED
W/REFILLING HALOGENATED HYDROCARBON CONTAINERS.
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Physical/Chemical Properties
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B.P. Text: 118F,48C
Vapor Pres: 5.6 PSIA
Spec Gravity: 1.42 (H*2O=1)
Solubility in Water: SLIGHTLY
Appearance and Odor: CLEAR, WHITE LIQUID W/VERY SLIGHT ETHEREAL ODOR.
Percent Volatiles by Volume: >99
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAMES & HIGH TEMPERATURES.
Materials To Avoid: ALKALI OR ALKALINE EARTH METALS.
Hazardous Decomposition Products: CHLORIDES, FLUORIDES & PHOSGENE (FP N). TOXIC
COMPOUNDS IF IN A FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: HALOCARBON 113
Assigned IND: Y
Company: LIQUID CARBONIC INDUSTRIES
Street: 810 JORIE BLVD.
City: OAK BROOK IL
Zipcode: 60521-2216
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 08/12/1998
Status Code: C
Label Date: 08/12/1998
Origination
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE:INHALATION OF VAPORS MAY CONTRIBUTE
TO THE OCCURRENCE OF IRREGULAR HEARTBEAT (FP N). INHALATION:CAUSES LIGHT
HEADEDNESS, GIDDINESS, DISORIENTATION, NAUSEA, VOMITING, NARCOSIS, CARDI AC
DYSRHYTHMIAS, HYPOTENSION AND EVENTUAL DEATH. SKIN & EYE:RAPIDLY
EVAPORATING LIQUID MAY CAUSE FROSTBITE. VAPOR IS SLIGHT IRRITANT.
CHRONIC:NONE LISTED BY MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.