ing 5: society. consult haz warnings on boxes/contrs (or on tags/labels ing 6: filler metals, fluxes & fusible granular matls. see osha sfty ing 7: & brazing". also see acgih "tlvs (1990-1991) for chem ing 8: "welding fumes" (total particulate tlv-twa, 5 mg/m3) for further ing 9: consumables & related prods for reactivity & hlth haz other prec: means to incr discharge rate of prod from cyl. use check ing 11: back flow into cyl. keep cyl away from heat & flame. do not ing 12: after each use & when empty. see nfpa pamphlet 51a "welding ing 13: consult compressed gas association's pamphlet p-1. protect cyls ing 14: well-ventd area away from heavily trafficked areas & emer ing 15: to exceed 125f (52c). cyls should be stored upright & firmly ing 16: full & empty cyls should be segregated. use "first in-firts ing 17: stored for excess periods fo time. these mixts are non-corr & ing 18: compressed gas cyls should not be refilled except by qualified ing 19: compressed gas cyl which has not been filled by owner/with his ing 20: law (49 cfr). always secure cyls in upright position before ing 21: trunks of vehicles, enclsd vans, truck cabs/in passenger ing 22: flatbed or in open pick-up type vehicles. other prot equip: help to pvnt injury from radia, spks & elec shock. ing 24: welder's gloves & prot fshld & may incl arm prot, aprons, msds toxicity property">
argon; bp: -302.6f (-185.9c); spec grav: 1.38; vp: > critical temp of efts of overexp: long-term (chronic) overexp may lead to siderosis (iron ing 3: investigators to affect pulm func. arc rays can injure eyes & ing 4: fumes & gases. use adeq vent. see ansi z-49-1 "sfty in welding ing 5: society. consult haz warnings on boxes/contrs (or on tags/labels ing 6: filler metals, fluxes & fusible granular matls. see osha sfty ing 7: & brazing". also see acgih "tlvs (1990-1991) for chem ing 8: "welding fumes" (total particulate tlv-twa, 5 mg/m3) for further ing 9: consumables & related prods for reactivity & hlth haz other prec: means to incr discharge rate of prod from cyl. use check ing 11: back flow into cyl. keep cyl away from heat & flame. do not ing 12: after each use & when empty. see nfpa pamphlet 51a "welding ing 13: consult compressed gas association's pamphlet p-1. protect cyls ing 14: well-ventd area away from heavily trafficked areas & emer ing 15: to exceed 125f (52c). cyls should be stored upright & firmly ing 16: full & empty cyls should be segregated. use "first in-firts ing 17: stored for excess periods fo time. these mixts are non-corr & ing 18: compressed gas cyls should not be refilled except by qualified ing 19: compressed gas cyl which has not been filled by owner/with his ing 20: law (49 cfr). always secure cyls in upright position before ing 21: trunks of vehicles, enclsd vans, truck cabs/in passenger ing 22: flatbed or in open pick-up type vehicles. other prot equip: help to pvnt injury from radia, spks & elec shock. ing 24: welder's gloves & prot fshld & may incl arm prot, aprons, msds toxicity property">
MSDS
:
8-25% CARBON DIOXIDE IN ARGON
CAS
:
124-38-9 7440-37-1
NAME
:
carbon dioxide; bp: -109.3f (-78.5c); spec grav: 1.65; vp: 865 psia @ argon; bp: -302.6f (-185.9c); spec grav: 1.38; vp: > critical temp of efts of overexp: long-term (chronic) overexp may lead to siderosis (iron ing 3: investigators to affect pulm func. arc rays can injure eyes & ing 4: fumes & gases. use adeq vent. see ansi z-49-1 "sfty in welding ing 5: society. consult haz warnings on boxes/contrs (or on tags/labels ing 6: filler metals, fluxes & fusible granular matls. see osha sfty ing 7: & brazing". also see acgih "tlvs (1990-1991) for chem ing 8: "welding fumes" (total particulate tlv-twa, 5 mg/m3) for further ing 9: consumables & related prods for reactivity & hlth haz other prec: means to incr discharge rate of prod from cyl. use check ing 11: back flow into cyl. keep cyl away from heat & flame. do not ing 12: after each use & when empty. see nfpa pamphlet 51a "welding ing 13: consult compressed gas association's pamphlet p-1. protect cyls ing 14: well-ventd area away from heavily trafficked areas & emer ing 15: to exceed 125f (52c). cyls should be stored upright & firmly ing 16: full & empty cyls should be segregated. use "first in-firts ing 17: stored for excess periods fo time. these mixts are non-corr & ing 18: compressed gas cyls should not be refilled except by qualified ing 19: compressed gas cyl which has not been filled by owner/with his ing 20: law (49 cfr). always secure cyls in upright position before ing 21: trunks of vehicles, enclsd vans, truck cabs/in passenger ing 22: flatbed or in open pick-up type vehicles. other prot equip: help to pvnt injury from radia, spks & elec shock. ing 24: welder's gloves & prot fshld & may incl arm prot, aprons,
INDIANA OXYGEN CO -- 8-25% CARBON DIOXIDE IN ARGON
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CHTCV
MSDS NAME: 8-25% CARBON DIOXIDE IN ARGON
Responsible Party
Name: INDIANA OXYGEN CO
Address: 6099 WEST CORPORATE WAY
Box: 78588
City: INDIANAPOLIS IN 46278
Info Phone: 317-290-0003
Emergency Phone Number: 317-290-0003
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: INDIANA OXYGEN CO
Address: 6099 W CORPORATE WAY
Box: 78588
City: INDIANAPOLIS IN 46278
Phone: 317-632-4525
Name: INDIANA OXYGEN CO
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
=======================================================
Ingredients
=======================================================
Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE; BP: -109.3F (-78.5C); SPEC GRAV: 1.65; VP: 865 PSIA @
70F; SOL IN WATER: VERY SOLUBLE
OSHA PEL: 5000 PPM
ACGIH TLV: 5000 PPM/30000 STEL
------------------------------
Cas: 7440-37-1
RTECS #: CF2300000
Name: ARGON; BP: -302.6F (-185.9C); SPEC GRAV: 1.38; VP: > CRITICAL TEMP OF
-188.1F (-122.3C); SOL IN WATER: VERY SLIGHT
OSHA PEL: N/K (FP N)
ACGIH TLV: ASPHYXIANT
------------------------------
Name: EFTS OF OVEREXP: LONG-TERM (CHRONIC) OVEREXP MAY LEAD TO SIDEROSIS (IRON
DEPOSITS IN LUNGS) & IS BELIEVED BY SOME
-----------------------------
Name: ING 3: INVESTIGATORS TO AFFECT PULM FUNC. ARC RAYS CAN INJURE EYES &
BURN SKIN. ELEC SHOCK CAN KILL. AVOID BRTHG
-----------------------------
Name: ING 4: FUMES & GASES. USE ADEQ VENT. SEE ANSI Z-49-1 "SFTY IN WELDING
& CUTTING" PUBLISHED BY AMERICAN WELDING
-----------------------------
Name: ING 5: SOCIETY. CONSULT HAZ WARNINGS ON BOXES/CONTRS (OR ON TAGS/LABELS
THEREON) CONTAINING BRAZING/WELDING
-----------------------------
Name: ING 6: FILLER METALS, FLUXES & FUSIBLE GRANULAR MATLS. SEE OSHA SFTY
REGS UNDER 29 CFR 1910.252 "WELDING, CUTTING
-----------------------------
Name: ING 7: & BRAZING". ALSO SEE ACGIH "TLVS (1990-1991) FOR CHEM
SUBSTANCES IN WORK ENVIRON", APPENDIX B, SECTION B2
-----------------------------
Name: ING 8: "WELDING FUMES" (TOTAL PARTICULATE TLV-TWA, 5 MG/M3) FOR FURTHER
INFO. CONSULT MFR'S MSDS ON WELDING
-----------------------------
Name: ING 9: CONSUMABLES & RELATED PRODS FOR REACTIVITY & HLTH HAZ
DATA, & FOR FURTHER INFO REGARDING WELDING FUMES.
-----------------------------
Name: OTHER PREC: MEANS TO INCR DISCHARGE RATE OF PROD FROM CYL. USE CHECK
VALVE/TRAP IN DISCHARGE LINE TO PVNT HAZ
-----------------------------
Name: ING 11: BACK FLOW INTO CYL. KEEP CYL AWAY FROM HEAT & FLAME. DO NOT
TAMPER W/(VALVE) SFTY DEVICE. CLOSE VALVE
-----------------------------
Name: ING 12: AFTER EACH USE & WHEN EMPTY. SEE NFPA PAMPHLET 51A "WELDING
& CUTTING" FOR ADDNL INFO. FOR ADDNL INFO
-----------------------------
Name: ING 13: CONSULT COMPRESSED GAS ASSOCIATION'S PAMPHLET P-1. PROTECT CYLS
FROM PHYSICAL DMG. STORE IN COOL, DRY,
-----------------------------
Name: ING 14: WELL-VENTD AREA AWAY FROM HEAVILY TRAFFICKED AREAS & EMER
EXITS. DO NOT ALLOW TEMP WHERE CYLS ARE STORED
-----------------------------
Name: ING 15: TO EXCEED 125F (52C). CYLS SHOULD BE STORED UPRIGHT & FIRMLY
SECURED TO PVNT FALLING/BEING KNOCKED OVER.
-----------------------------
Name: ING 16: FULL & EMPTY CYLS SHOULD BE SEGREGATED. USE "FIRST IN-FIRTS
OUT" INVENTORY SYS TO PVNT FULL CYLS BEING
-----------------------------
Name: ING 17: STORED FOR EXCESS PERIODS FO TIME. THESE MIXTS ARE NON-CORR &
MAY BE USED W/ANY COMMON STRUCTURAL MATL.
-----------------------------
Name: ING 18: COMPRESSED GAS CYLS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED
PRODUCERS OF COMPRESSED GAS. SHIPMENT OF
-----------------------------
Name: ING 19: COMPRESSED GAS CYL WHICH HAS NOT BEEN FILLED BY OWNER/WITH HIS
(WRITTEN) CONSENT IS A VIOLATION OF FED
-----------------------------
Name: ING 20: LAW (49 CFR). ALWAYS SECURE CYLS IN UPRIGHT POSITION BEFORE
TRANSPORTING THEM. NEVER TRANSPORT CYLS IN
-----------------------------
Name: ING 21: TRUNKS OF VEHICLES, ENCLSD VANS, TRUCK CABS/IN PASSENGER
COMPARTMENTS. TRANSPORT CYLS SECURED IN OPEN
-----------------------------
Name: ING 22: FLATBED OR IN OPEN PICK-UP TYPE VEHICLES.
-----------------------------
Name: OTHER PROT EQUIP: HELP TO PVNT INJURY FROM RADIA, SPKS & ELEC SHOCK.
SEE ANSI Z-49-1. AT MIN, THIS INCLUDES
-----------------------------
Name: ING 24: WELDER'S GLOVES & PROT FSHLD & MAY INCL ARM PROT, APRONS,
HATS, SHOULDER PROT & DARK SUBSTANTIAL CLTHG.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: CONCS OF 20-30% OF THESE MIXTS WHEN INHALED W/ADEQ
OXYGEN IN AIR WILL CAUSE INCR IN RESP RATE. HIGHER CONCS WILL CAUSE HDCH,
NAUS & EVENTUAL UNCON. TOX PROPERTIES: CARBON DIOXIDE IS MOST POWERF UL
CEREBRAL VASODILATOR KNOWN. INHALINGLGE CONCS CAUSES RAPID CIRCULATORY
INSUFFICIENCY LEADING TO (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: COMA & DEATH. CHRONIC
HARMFUL EFTS ARE NOT KNOWN FROM RPTD INHAL OF LOW (20-30%) CONCS OF THESE
MIXTS. CAUTION: WELDING/BRAZING MAY PRDCE FUMES & GASES HAZ TO HLTH.
SHORT-TERM (ACUTE) OVEREX P TO WELDING FUMES MAY RSLT IN DISCOMFORT SUCH AS
DIZZ, NAUS/DRYNESS/IRRIT OF NOSE, THROAT/EYES.
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO THESE MIXTURES SHOULD NOT BE ALLOWED TO
WORK WITH OR HANDLE THESE PRODUCTS.
First Aid: PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP. RESCUE PERS
SHOULD BE EQUIPPED W/NIOSH APPRVD SCBA. INHAL: MOVE CONSCIOUS PERS TO FRESH
AIR. QUICK REMOVAL FROM CONTAM AREA IS MOST IMPORTANT. MOV E UNCON PERS TO
UNCONTAM AREA, GIVE ASSISTED RESP & SUPP OXYGEN. FURTHER TREATMENT SHOULD
BE SYMPTOMATIC & SUPPORTIVE. EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15
MIN. SEE MD (FP N). (SUP DAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE ALL PERS FROM AFFECTED AREA. USE APPROP PROT
EQUIP. IF LEAK IS IN USER'S EQUIP, BE CERTAIN TO PURGE PIPING W/INERT GAS
PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CONTR/CONTR VALVE, CONT YOUR
CLOSEST SUPPLIER LOCATION/CALL EMER NUMBER LISTED.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT ATTEMPT TO DISPOSE OF WASTE/UNUSED QTYS. RETURN
IN SHIPPING CONTR PROPERLY LABELED, W/ANY VALVE OUTLET PLUGS/CAPS SECURED
& VALVE PROT CAP IN PLACE TO YOUR SUPPLIER. FOR EMER DISP ASSIST, CONT
YOUR CLOSEST SUPPLIER LOCATION/CALL EMER (SUP DAT)
Handling And Storage Precautions: USE ONLY IN WELL-VENTD AREAS. VALVE PROT CAPS
MUST REMAIN IN PLACE UNLESS CONTR IS SECURED W/VALVE OUTLET PIPED TO USE
POINT.
Other Precautions: TRAIN WELDER TO KEEP HEAD OUT OF FUMES. DO NOT DRAG, SLIDE,
DROP/ROLL CYLS. USE SUITABLE HAND TRUCK FOR CYL MOVEMENT. USE PRESS REDUCING
REGULATOR WHEN CONNECTING CYL TO LOWER PRESS (<3,000 PSIG) PIPI NG/SYS. DO
NOT HEAT CYL BY ANY
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: NON-FLAMMABLE GAS MIXTURE. USE MEDIA SUITABLE FOR
SURROUNDING FIRE (FP N).
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). IF CYLINDERS ARE INVOLVED IN A FIRE, SAFELY RELOCATE OR
KEEP COOL WITH WATER SPRAY.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPRVD POSITIVE PRESSURE AIR LINE W/MASK/SCBA
SHOULD BE AVAIL FOR EMER USE. WHEN WELDING IN CONFINED SPACE/WHERE LOC
EXHAUST/VENT DOES NOT KEEP EXPOS BELOW WELDING FUME TLV, USE NIOSH APPRVD POS
ITIVE PRESSURE AIR LINE W/MASK/SCBA.
Ventilation: LOC EXHST TO PVNT ACCUM OF HIGH CONCS OF GASES SO AS TO REDUCE
OXYGEN LEVEL IN AIR TO UNDER 18 MOLAR PERCENT. (SUP DAT)
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
WHEN WELDING, WEAR SFTY SHOES, HEAD, HAND & BODY PROT WHICH
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRST AID PROC: SKIN: FLUSH W/COPIOUS AMTS OF
WATER. SEE MD (FP N). INGEST: CALL MD IMMED (FP N). WASTE DISP METH: NUMBER
LISTED. DISPOSE OF I/A/W LOC, STATE & FED REGS (FP N). VENT: WHEN
WELDING, USE ENOUGH VENT, LOC EXHST AT ARC/BOTH, TOKEEP WELDING FUMES &
GASES BELOW APPLIC ELV'S IN WORKER'S BRTHG ZONE & GEN AREA.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SEE INGS
Vapor Pres: SEE INGS
Spec Gravity: SEE INGS
Evaporation Rate & Reference: N/A (GAS)
Solubility in Water: SEE INGS
Appearance and Odor: COLORLESS, ODORLESS GAS
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Materials To Avoid: NONE.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: 8-25% CARBON DIOXIDE IN ARGON
Company: INDIANA OXYGEN CO
Street: 6099 W CORPORATE WAY
PO Box: 78588
City: INDIANAPOLIS IN
Zipcode: 46278
Health Emergency Phone: 317-290-0003
Label Required IND: Y
Date Of Label Review: 06/10/1998
Status Code: C
Label Date: 06/10/1998
Origination
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: CONCENTRATIONS OF 20-30% OF THESE MIXTURES WHEN
INHALED WITH ADEQUATE OXYGEN IN AIR WILL CAUSE INCREASE IN RESPIRATORY RATE.
HIGHER CONCENTRATIONS WILL CAUSE HEADACHE, NAUSEA AND EVENTUAL UNCON
SCIOUSNESS. TOXICOLOGICAL PROPERTIES: CARBON DIOXIDE IS THE MOST POWERFUL
CEREBRAL VASODILATOR KNOWN. INHALING LARGE CONCENTRATIONS CAUSES RAPID
CIRCULATORY INSUFFICIENCY LEADING TO COMA AND DEATH. CH RONIC: NONE SPECIFIED
BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.