DOW ELANCO -- 46482, DURSBANPRO INSECTICIDE
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Material Safety Data Sheet
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NIIN: 01-412-4361
MSDS Num: CJMTW
MSDS NAME: 46482, DURSBANPRO INSECTICIDE
Responsible Party
Name: DOW ELANCO
Address: QUAD IV, 9002 PURDUE RD
City: INDIANAPOLIS IN 46268-1189
Info Phone: 517-636-4400
Emergency Phone Number: 800-352-6776
Resp. Party Other MSDS No.: 004949
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Item Description Information
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Item Manager: S9G
Item Name: INSECTICIDE,DURSBAN
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: PT
UI Container Qty: 0
Type of Container: BOTTLE,SQUEEZ
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL, MALE RAT) IS 623MG/KG.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE:MAY CAUSE SLIGHT IRRITATION. CORNEAL INJURY IS
UNLIKELY. SKIN-PROLONGED EXPOSURE NOT LIKELY TO CAUSE SIGNIFICANT SKIN
IRRITATION. ABSORPTION-SINGLE PROLONGED EXPOSURE NOT LIKELY TO BE ABSORBED IN
HARMFUL AMOUNTS. INGESTION-SINGLE DOSE ORAL TOXICITY IS LOW. SWALLOWING
LARGER AMOUNTS MAY CAUSE INJURY. IF ASPIRATED (LIQUID ENTERS THE LUNG), MAY
CAUSE LUNG DAMAGE OR EVEN DEATH DUE TO CHEMICAL PNE UMONIA. INHALATION:
VAPORS (WHEN HEATED) MAY BE HAZARDOUS. EXCESSIVE EXPOSURE MAY PRODUCE
ORGANOPHOSPHATE TYPE CHOLINESTERASE INHIBITION.
Explanation Of Carcinogenicity: CHLORPYRIFOS AND OTHER TESTED COMPONENTS DID
NOT CAUSE CANCER IN LONG-TERM ANIMAL STUDIES.
Signs And Symptions Of Overexposure: SIGNS AND SYMPTOMS OF EXCESSIVE EXPOSURE
TO ACTIVE INGREDIENT MAY BE HEADACHE, DIZZINESS, INCOORDINATION, MUSCLE
TWITCHING, TREMORS, NAUSEA, ABDOMINAL CRAMPS, DIARRHEA, SWEATING, PINPOINT
PUPILS, BLUR RED VISION, SALIVATION, TEARING, TIGHTNESS IN CHEST, EXCESSIVE
URINATION, OR CONVULSIONS. ACTIVE INGREDIENT PRODUCED MILD ADRENAL EFFECTS
WHEN FED TO RATS, BUT ONLY AT DOSES THAT GREATLY EXCEEDED ANY EXPOSURES THAT
WOULD BE RECEIVED DURING USE OF THIS PRODUCT.
First Aid: EYE: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION. SKIN: WASH EXPOSED AREAS WITH PLENTY OF SOAP AND WATER. GET
MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUS E.
INGESTION: CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. DO NOT
INDUCE VOMITING. DO NOT PUT ANYTHING INTO THE MOUTH OF AN UNCONSCIOUS PERSON.
INHALATION: REMOVE PERSON TO FRESH AIR AND IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION, PREFERABLY BY MOUTH TO MOUTH. GET MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: WEAR LONG PANTS, LONGSLEEVE SHIRT AND IMPERVIOUS
RUBBER GLOVES WHEN HANDLING CONCENTRATE AND CLEANING UP SPILLS. ABSORB
SPILLS WITH AN INERT ABSORBANT MATERIAL SUCH AS HAZORB, ZORBALL, SAND OR
DIRT. SCOOP CONTAMINATED ABSORBANT MATERIAL INTO A CONTAINER. THOROUGHLY
WASH BODY AREAS THAT COME INTO CONTACT WITH THIS PRODUCT. FOR LARGE SPILLS
CONSULT DOWELANCO (517-636-4400).
Waste Disposal Methods: DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR
DISPOSAL. EXCESS PESTICIDE RESULTING FROM THE USE OF THIS PRODUCT MAY BE
DISPOSED OF ON SITE ACCORDING TO LABEL DIRECTIONS OR AT AN APPROVED WASTE
DISPOSAL FACILITY. FOLLOW ALL LOCAL, STATE AND FEDERAL REQUIREMENTS FOR
DISPOSAL.
Handling And Storage Precautions: SEE LABEL.KEEP OUT OF REACH OF CHILDREN.
DON'T SWALLOW. AVOID EYE, SKIN, & CLOTHES CONTACT. AVOID BREATH VAPOR
& SRAPY MIST. HANDLE CONCENTRATE IN VENTILATED AREA. WASH WELL WITH SOAP
AND WATER BEFOR E EATING OR SMOKING. KEEP AWAY FROM FOOD, FEEDSTUFFS AND
WATER SUPPLIES.
Other Precautions: FOR HEALTH AND SAFETY INFO ON END-USE DILUTIONS OF UP TO 1%
DURSBAN INSECTICIDES SEE HEALTH AND SAFETY FACT SHEET FORM NO. 312-10-014,
AVAILABLE FROM DOWELANCO.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point: =115.C, 239.F
Lower Limits: N/DETERMINED
Upper Limits: N/DETERMINED
Extinguishing Media: FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: USE POSITIVE-PRESSURE, SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard: FOAM FIRE EXTINGUISHING SYSTEM IS PREFERRED
BECAUSE UNCONTROLLED WATER CAN SPREAD POSSIBLE CONTAMINATION. TOXIC
IRRITATING GASES MAY BE FORMED UNDER FIRE CONDITIONS.
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Control Measures
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Respiratory Protection: ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE
EXPOSURE GUIDELINES. WHEN RESPIRATORY PROTECTION IS REQUIRED, USE AN APPROVED
AIR-PURIFYING OR POSITIVE PRESSURE SUPPLIED AIR RESPIRATOR DEPENDING ON THE
POTENTIAL AIRBORNE CONCENTRATION.
Ventilation: PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
Protective Gloves: CHEMICALLY-RESISTANT GLOVES
Eye Protection: WEAR EYE PROTECTION SUCH AS SAFETY GLASSES.
Other Protective Equipment: WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices: N/P.
Supplemental Safety and Health: EPA REGISTRATION NUMBER: 62719-166.
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Physical/Chemical Properties
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HCC: T4
NRC/State LIC No: NONE
B.P. Text: N/DETERMINED
Vapor Pres: N/DETERMINED
Vapor Density: N/DETERMIN
Spec Gravity: 1.07 @20C
Evaporation Rate & Reference: NOT GIVEN
Solubility in Water: EMULSIFIABLE
Appearance and Odor: SLIGHTLY CLOUDY COLORLESS LIQUID, ODOR NOT AVAILABLE
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID HEATING ABOVE 122F(50C). CHLORPYRIFOS
DECOMPOSES EXOTHERMICALLY AT 130C(266F) WHICH CAN LEAD TO HIGHER TEMPERATURES
AND VIOLENT DECOMPOSITION IF GENERATED HEAT IS NOT REMOVED.
Materials To Avoid: OXIDIZING MATERIALS AND STRONG ACID. IF IN CONTACT WITH
ORGANIC MATERIAL AND FINELY DIVIDED INORGANIC MATERIALS SUCH AS CLAY, ROCK
WOOL INSULATION, RAGS, PAPER, ETC. THIS PRODUCT MAY UNDERGO SPONTANEOUS
COMBUSTION.
Hazardous Decomposition Products: HYDROGEN CHLORIDE, NITROGEN OXIDES AND OTHER
TOXIC, IRRITATING VAPORS MAY BE FORMED IF PRODUCT IS INVOLVED IN FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: CHLORPYRIFOS DID NOT CAUSE BIRTH DEFECTS IN
LABORATORY ANIMALS AND DID NOT INTERFERE WITH FERTILITY IN REPRODUCTION
STUDIES IN LABORATORY ANIMALS. SOME EVIDENCE OF TOXICITY TO THE OFFSPRING
OCCURED, BUT ONLY AT A DOSE HIGH ENOUGH TO PRODUCE SIGNIFICANT TOXICITY TO
THE PARENT ANIMAL. CHLORPYRIFOS IS CONSIDERED TO HAVE MINIMAL MUTAGENIC
POTENTIAL.
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Ecological Information
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Ecological: THIS PESTICIDE IS TOXIC TO BIRDS AND WILDLIFE AND EXTREMELY TOXIC
TO FISH AND AQUATIC ORGANISMS. DO NOT APPLY DIRECTLY TO WATER, TO AREAS
WHERE SURFACE WATER IS PRESENT OR TO INTERTIDAL AREAS BELOW T HE MEAN HIGH
WATER MARK.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: SARA TITLE III:CONSIDERED,UNDER APPLICABLE
DEFINITIONS,TO MEET FOLLOWING CATEGORIES:AN IMMED HEALTH HAZ;A DELAYED HEALTH
HAZARD.
Federal Regulatory Information: PRODUCT IS HAZ CHEMICAL AS DEFINED BY OSHA HAZ
COMMUNICATION STD 29 CFR 1910.1200. ALL INGREDIENTS ARE ON THE TSCA
INVENTORY OR ARE NOT REQUIRED TO BE LISTED ON THE TSCA INVENTORY.
State Regulatory Information: 1,2-PROPANEDIOL CAS#57-55-6 PA HAZ SUBSTANCE
PRESENT @>/=1.0%. CHLORPYRIFOS CAS # 2921-88-2, NEW JERSEY WORKPLACE HAZ
SUBSTANCE, PA HAZ SUBSTANCE, PA ENVIRO HAZ SUBSTANCE (PRESENT @</=1.0%).
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Other Information
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Transportation Information
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Trans ID NO: 148694
MSDS NAME: 46482, DURSBANPRO INSECTICIDE
MSDS Prepared Date: 10/05/1994
Review Date: 11/29/1999
Tech Entry NOS Shipping Nm: CHLORPYRIFOS
Net Unit Weight: 1.1 LBS
Multiple KIT Number: 0
Unit Of Issue: PT
Container QTY: 0
Type Of Container: BOTTLE,SQUEEZ
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Detail DOT Information
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DOT PSN Code: LCM
Symbols: D
DOT Proper Shipping Name: OTHER REGULATED SUBSTANCES, LIQUID, N.O.S.
Hazard Class: 9
UN ID Num: NA3082
DOT Packaging Group: III
Label: CLASS 9
Packaging Exception: 155
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: NO LIMIT
Max Qty Cargo: NO LIMIT
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: LKP
IMO Proper Shipping Name: PESTICIDE, LIQUID, TOXIC, N.O.S. o
IMDG Page Number: 6219
UN Number: 2902
UN Hazard Class: 6.1
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 6.1-02
MED First Aid Guide NUM: *
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Detail IATA Information
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IATA PSN Code: TGT
IATA UN ID Num: 2902
IATA Proper Shipping Name: PESTICIDE, LIQUID, TOXIC, N.O.S. *
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 611
Max Quant Pass: 60L
Max Quant Cargo: 220L
Packaging Note Cargo: 618
Exceptions: A3,A4,A6
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Detail AFI Information
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AFI PSN Code: TGT
AFI Symbols: *
AFI Proper Shipping Name: PESTICIDES, LIQUID, TOXIC, N.O.S.
AFI Hazard Class: 6.1
AFI UN ID NUM: UN2902
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A10.5
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HAZCOM Label
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MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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