PRENTISS INCORPORATED -- DURSBAN 4E INSECTICIDE
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Material Safety Data Sheet
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NIIN: 00-402-5411
MSDS Num: CJMYW
MSDS NAME: DURSBAN 4E INSECTICIDE
Responsible Party
Name: PRENTISS INCORPORATED
Address: C B 2000
City: FLORAL PARK NY 11001
Country: NY
Info Phone: 516-326-1919
Emergency Phone Number: 516-326-1919
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Item Description Information
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Item Manager: S9G
Item Name: INSECTICIDE,DURSBAN
Specification Number: MIL-I-51325
Unit of Issue: CN
Quantitative Expression: 00000000005GL
UI Container Qty: 0
Type of Container: CAN
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Health Hazards Data
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LD50 LC50 Mixture: ORAL LD50(RAT): UNKNOWN
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: MAY BE FATAL IF SWALLOWED OR ABSORBED THROUGH SKIN.
SOLVENT MAY PRESENT ASPIRATION HAZARD. GASTRIC LAVAGE MAY BE INDICATED IF
PRODUCT TAKEN INTERNALLY. INHALATION OF SOLVENT VAPORS AT HIGH CONCENTRA
TIONS CAN CAUSE CENTRAL NERVOUS DEPRESSION, RESPIRATORY TRACT IRRITATION,
ASPHYXIATION, CARDIAC STRESS AND COMA. EXPOSURE TO EXTREMELY HIGH LEVELS OF
XYLENE MAY CAUSE KIDNEY OR LIVER DAMAGE.
Signs And Symptions Of Overexposure: SYMPTOMS INCLUDE WEAKNESS, HEADACHE,
TIGHTNESS IN CHEST, BLURRED VISION, NON REACTIVE PINPOINT PUPILS, SALIVATION,
SWEATING, NAUSEA, VOMITING, DIARRHEA AND ABDOMINAL CRAMPS.
Medical Cond Aggravated By Exposure: GENETIC CHOLINESTERASE DEFICIENCY,
ADVANCED LIVER DISEASE, CHRONIC ALCOHOLISM, MALNUTRITION, EXISTING TOXICITY
FROM EXPOSURE TO CARBON DISULFIDE, ORGANIC MERCURY COMPOUNDS.
First Aid: IF SWALLOWED-CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
CONTAINS PETROLEUM DISTILLATES. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION
IMMEDIATELY. IF INHALED-REMOVE PERSON TO FRESH AIR. AP PLY ARTIFICIAL
RESPIRATION IF SYMPTOMS INDICATE. IF ON SKIN-WASH AFFECTED AREA WITH SOAP AND
WATER. IF IN EYES-FLUSH EYES WITH PLENTY OF WATER. GET PROMPT MEDICAL
ATTENTION.
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Handling and Disposal
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Spill Release Procedures: WEAR PROTECTIVE EQUIPMENT, AS REQUIRED, TO PREVENT
CONTACT WITH PRODUCT OR ITS VAPOR. COVER THE SPILLED MATERIAL WITH GENEROUS
AMOUNTS OF ABSORBENT MATERIAL, SUCH AS CLAY, DIATOMACEOUS EARTH, SAND OR
SAWDUST. SWEEP THE CONTAMINATED ABSORBENT ONTO A SHOVEL AND PUT THE SWEEPINGS
INTO A SALVAGE DRUM. PLACE ANY LEAKING CONTAINER INTO ANOTHER SALVAGE DRUM.
Waste Disposal Methods: PESTICIDE WASTES ARE TOXIC. IMPROPER DISPOSAL OF EXCESS
PESTICIDE SPRAY MIXTURE, OR RINSATE IS A VIOLATION OF FEDERAL LAW. IF THESES
WASTE CANNOT BE DISPOSED OF BY USE ACCORDING TO LABEL INSTRUCTIONS, CONTACT
YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL AGENCY, OR THE HAZARDOUS WASTE
REPRESENTATIV E AT THE NEAREST EPA REGIONAL OFFICE FOR GUIDANCE.
Handling And Storage Precautions: DO NOT CONTAMINATE WATER, FOOD OR FEED BY
STORAGE OR DISPOSAL. STORE IN A DRY PLACE AWAY FROM TEMPERATURE EXTREMES.
AVOID INHALATION OF VAPORS. AVOID CONTACT WITH SKIN. WEAR CLEAN PROTECTIVE
CLOTHING .
Other Precautions: TRIPLE RINSE (OR EQUIVALENT). THEN OFFER FOR RECYCLING OR
RECONDITIONING, OR PUNCTURE AND DISPOSE OF IN A SANITARY LANDFILL, OR BY
STATE OTHER APPROVED LOCAL AUTHORITIES.
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Fire and Explosion Hazard Information
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Flash Point: =43.9C, 111.F
Extinguishing Media: CO2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: FIGHT FIRE FROM UPWIND POSITIONS. USE SELF CONTAINED
BREATHING APPARATUS AND EQUIPMENT DESIGNED TO PREVENT SKIN AND EYE CONTACT.
COOL EXPOSED CONTAINERS WITH WATER SPRAY. THIS PRODUCT IS TOXIC TO B IRDS,
FISH AND OTHER WILDLIFE. PREVENT SPREAD OF CONTAMINATED RUNOFF.
Unusual Fire/Explosion Hazard: MAY GIVE OFF HYDROGEN CHLORIDE, ETHYL SULFIDE,
DIETHYL SULFIDE AND NITROGEN OXIDES. FOAM IS PREFERRED METHOD OF FIGHTING
FIRES TO HELP PREVENT SPREAD OF CONTAMINATED RUNOFF.
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Control Measures
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Respiratory Protection: WEAR A PESTICIDE RESPIRATOR JOINTLY APPROVED BY THE
MINING ENFORCEMENT AND SAFETY ADMINISTRATION (FORMERLY US BUREAU OF MINES)
AND THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH (NIOSH), UN DER
THE PROVISIONS OF 30 CFR PART 11.
Ventilation: LOCAL EXHAUST AS REQUIRED TO MEET TLV VALUES.
Protective Gloves: NATURAL RUBBER OR OTHER CHEMICAL RESISTANT.
Eye Protection: FACE SHIELD, GOGGLES, OR SAFETY GLASSES.
Other Protective Equipment: FULL PROTECTIVE CLOTHING DESIGNED TO PREVENT SKIN
CONTACT SUCH AS WATER RESISTANT OVERALLS.
Work Hygienic Practices: MAY BE FATAL IF INHALED OR ABSORBED THROUGH SKIN.
Supplemental Safety and Health: CAUSES EYE DAMAGE. DO NOT GET IN EYES. DONOT
USE OR STORE NEAR HEAT OR OPEN FLAMES. AVOID CONTAMINATION OF FOOD OR FOOD
PROCESSING SURFACES. SEE PRODUCT LABEL FOR OTHER PRECAUTIONARY STATEMENTS FOR
S AFE USE.PERIODICALLY INSPECT STORED MATERIALS.
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Physical/Chemical Properties
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HCC: F5
B.P. Text: N/D
M.P/F.P Text: N/D
Vapor Pres: N/D
Vapor Density: N/D
Spec Gravity: 1.0674
Evaporation Rate & Reference: N/D
Solubility in Water: EMEMULSIFIED
Appearance and Odor: YELLOW LIQUID, MILD MERCAPTAN ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: CHLORPYRIFAS UNDERGOES EXOTHERMIC DECOMPOSITION
AT ABOUT 130 C (266F.) WHICH CAN LEAD TO HIGHER TEMPERATURES AND VIOLENT
DECOMPOSITION IF GENERATED HEAT IS NOT REMOVED.
Materials To Avoid: ALKALIES.
Hazardous Decomposition Products: HYDROGEN CHLORIDE, ETHYL SULFIDE, DIETHYL
SULFIDE AND NITROGEN OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE.
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Toxicological Information
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Toxicological Information: THIS PRODUCT CONTAINS A XYLENE RANGE AROMATIC
SOLVENT COMPOSED OF XYLENES, ETHYLBENZENES AND AROMATIC NAPTHA CONTAINING
TRIMETHYLBENZENE.
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: THIS PRODUCT CONTAINS A TOXIC CHEMICAL
(1,2,4-TRIMETHYL BENZENE,MIXED XYLENES, CUMENE, ETHYL BENZENE) SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III AND OF 40 CFR 372. ANY
COPIES OR REPRODUCTIONS OF THIS MSDS MUST DUPLICATE THIS NOTICE.
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Other Information
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Other Information: NOTE TO PHYSICIAN: CHLORPYRIFOS IS A
CHOLINESTERASEINHIBITOR. IF SYMPTOMSOF CHOLINESTERASE INHIBITIONS ARE
PRESENT, ATROPINE SULFATE BY INJECTION IS ANTIDOTAL. 2-PAM IS ALSO ANTIDOTAL
AND MAY BE ADMIN ISTERED, BUT ONLY IN CONJUNCTION WITH ATROPINE.
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Transportation Information
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Trans ID NO: 148757
MSDS NAME: DURSBAN 4E INSECTICIDE
MSDS Prepared Date: 01/20/1994
Review Date: 09/28/1999
Tech Entry NOS Shipping Nm: CHLORPYRIFOS
Net Unit Weight: 44.5 LBS
Multiple KIT Number: 0
Unit Of Issue: CN
Container QTY: 0
Type Of Container: CAN
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Detail DOT Information
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DOT PSN Code: GJS
Symbols: G
DOT Proper Shipping Name: FLAMMABLE LIQUIDS, TOXIC, N.O.S.
Hazard Class: 3
UN ID Num: UN1992
DOT Packaging Group: III
Label: FLAMMABLE LIQUID, KEEP AWAY FROM FOOD
Special Provision: B1,T18
Packaging Exception: 150
Non Bulk Pack: 203
Bulk Pack: 242
Max Qty Pass: 60 L
Max Qty Cargo: 220 L
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: HIE
IMO Proper Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. o
IMDG Page Number: 3346-1
UN Number: 1992
UN Hazard Class: 3.3
IMO Packaging Group: III
Subsidiary Risk Label: TOXIC
EMS Number: 3-07
MED First Aid Guide NUM: T
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Detail IATA Information
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IATA PSN CP
IATA UN ID Num: 1992
IATA Proper Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. *
IATA UN Class: 3
Subsidiary Risk Class: 6.1
IATA Label: FLAMMABLE LIQUID & TOXIC
UN Packing Group: III
Packing Note Passenger: 309
Max Quant Pass: 60L
Max Quant Cargo: 220L
Packaging Note Cargo: 310
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Detail AFI Information
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AFI PSN CP
AFI Symbols: *
AFI Proper Shipping Name: FLAMMABLE LIQUIDS, POISONOUS, N.O.S.
AFI Hazard Class: 3
AFI UN ID NUM: UN1992
AFI Packing Group: III
AFI Label: 6.1
Special Provisions: P5
Back Pack Reference: A7.3
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HAZCOM Label
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MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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