PPG INDUSTRIES INC -- ALKYD FLAT INTERIOR MIDTO, 6-66
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Material Safety Data Sheet
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MSDS Num: CJQMQ
MSDS NAME: ALKYD FLAT INTERIOR MIDTO, 6-66
Responsible Party
Name: PPG INDUSTRIES INC
Address: 4325 ROSANNA DR
Box: 9
City: ALLISON PARK PA 15101
Info Phone: 412-492-5555
Emergency Phone Number: 304-843-1300
Resp. Party Other MSDS No.: 00023668.0026-66
Review Ind: Y
Published: Y
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Contractor Summary
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Name: PPG INDUSTRIES INC
Address: ONE PPG PLACE
City: PITTSBURGH PA 15272
Phone: 1-800-245-2974 (CAL HYPO)
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Item Description Information
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Ingredients
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Cas: 1317-65-3
RTECS #: EV9580000
Name: NATURAL CALCIUM CARBONATE; (CALCIUM CARBONATE)
% Wt: 10 - <20
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM DIOXIDE
% Wt: 1 - <5
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 14464-46-1
RTECS #: VV7325000
Name: CRISTOBALITE; (SILICA CRISTOBALLITE)
% Wt: 5 - <10
OSHA PEL: see Table Z-3
ACGIH TLV: 0.05 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 14808-60-7
RTECS #: VV7330000
Name: QUARTZ
% Wt: 10 - <20
OSHA PEL: see Table Z-3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 64742-48-9
Name: NAPHTHA (PETROLEUM), HYDROTREATED HEAVY; (NAPHTHA)
% Wt: 30 - <40
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Cas: 96-29-7
RTECS #: FL9275000
Name: METHYL ETHYL KETOXIME
% Wt: 0.1- <1
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INGEST: MAY BE HARMFUL IF SWALLOWED. EYE: CAUSES
IRRIT. SKIN: MAY CAUSE SLIGHT IRRIT. INHAL: VAP &/SPRAY MISTS MAY BE
HARMFUL IF INHALED. VAP IRRIT EYES, NOSE & THROAT. SANDING & GRINDING
DUSTS MAY BE HARMFUL IF INHALED. RPTD EXPOS TO HIGH VAP CONCS MAY CAUSE
IRRIT OF RESP SYS & PERMANENT BRAIN & NERVOUS SYS DMG. CHRONIC: AVOID
LONG-TERM & RPTD CTNCT. THIS PROD CNTNS FORM OF CRYSTALLINE SIL
ICA/QUARTZ WHICH IARC ASSOC W/INCREASED RISK OF CANCER IN LAB ANIMALS.
LONG-TERM EXPOS TO CRYSTALLINE SILICA/QUARTZ MAY ALSO LEAD TO A DISABILING
INJURY KNOWN AS SILICOSIS. THESE EFTS ARE ASSOCIATED W /BREATHING (EFTS OF
OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE - QUARTZ/CRISTOBALITE: IARC
MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME
68, PAGE 41, 1997: GROUP 1. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998: RE
ASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
Signs And Symptions Of Overexposure: HLTH HAZ: EXCESSIVE AMTS OF SILICA DUST.
APPLICATION OF THIS PROD IS NOT EXPECTED TO GENERATE EXCESSIVE AMTS OF
RESPIRABLE SILICA/QUARTZ. THIS PROD CNTNS TITANIUM DIOXIDE. ANIMALS INHALING
MASSIVE QTI ES OF TITANIUM DIOXIDE DUST IN A LONG-TERM STUDY DEVELOPED LUNG
TUMORS. STUDIES W/HUMANS INVOLVED IN MFR OF THIS PIGMENT INDICATE NO INCR
RISK OF CANCER FROM EXPOS. POTENTIAL FOR INHAL OF TITANIUMM DI XODE DUST FROM
COATING IS VERY LIMITED. SINCE OVEREXPS ARE NOT EXPECTED, THERE IS NO
SIGNIFICANT HAZ FOR MAN. THIS PROD CNTNS METHYL ETHYL KETOXIME (MEKO).
STUDIES IN ANIMALS INDICATE THAT OVEREXP CAN CAUSE ADVERSE EFTS IN SPLEEN
(SUPDAT)
First Aid: INGEST: IF SWALLOWED, DO NOT INUCE VOMITING. GENTLY WIPE OUT INSIDE
MOUTH TO REMOVE ANY RESIDUAL MATL. EYE: REMOVE CONTACT LENSES & FLUSH
EYES IMMEDIATELY WITH A GENTLE STREAM OF LUKE WARM WATER FOR LEAST 15 MIN.
SKIN: FLUSH IMMED W/PLENTY OF WATER FOR AT LEAST 15 MINUTES FOLLOWED BY
WASHING W/SOAP & WATER. INHAL: IF AFFECTED BY INHAL OF VAP/SPRAY MIST,
REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHE R SUPPORT MEASURES AS
REQUIRED. OTHER: IF INGEST, ANY TYPE OF OVEREXP/SYMPS OF OVEREXPOSURE OCCUR
DURING OR FOLLOWING USE OF THIS PRODUCT, CONTACT A POISON CONTROL CENTER,
EMERGENCY ROOM/MD IMMED, HAV E MSDS INFORMATION AVAILABLE.
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Handling and Disposal
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Spill Release Procedures: PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED
WITH PROPER RESPIRATORY, SKIN, AND EYE PROTECTION SHOULD BE PERMITTED IN THE
AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILL MATERIAL WITH SAND ,
VERMICULITE, OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL AND PLACE IN CLEAN,
EMPTY CONTAINERS FOR DISPOSAL. ONLY THE SPILLED MATERIAL AND THE ABSORBANT
SHOULD BE PLACED IN THIS CONTAINER.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE, PROVINCIAL, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WA STE
MANAGEMENT FACILITY.
Handling And Storage Precautions: DO NOT STORE ABOVE 120 DEGREES F (48 DEGREES
C). STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF
NFPA CLASS II COMBUSTIBLE LIQUIDS.
Other Precautions: VAPORS MAY COLLECT IN LOW AREA. IF THIS MATERIAL IS PART OF
A MULTIPLE COMPONENT SYSTEM, READ MSDS(S) FOR THE OTHER COMPONENT OR
COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARD S OF
ALL OF ITS PARTS. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL
OF LIQUIDS IN EXC ESS OF A FEW INCHES.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: =47.8C, 118.F
Lower Limits: 0.7%
Extinguishing Media: USE NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY
CHEMICAL, OR UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA
CLASS II COMBUSTIBLE LIQUID FIRES.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY MAY BE USED TO
COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION
OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE.
Unusual Fire/Explosion Hazard: WHEN THIS PROD IS USED, OVERSPRAY & OTHER
COMBUST MATLS SUCH AS PAINT BOOTH FILTERS, RAGS, MASKING MATLS, ETC., CONTAM
BY COATING MATLS ARE SUBJECT TO SPONT COMBUSTION. WETTING CONTAMD MATLS &
NOT PAC KING THEM TIGHTLY TOGETHER IN REFUSE CNTNRS WILL MINIMIZE POTENTIAL
FOR THIS TO OCCUR. KEEP THIS PROD AWAY (SUPDAT)
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Control Measures
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Respiratory Protection: OVEREXP TO VAPS MAY BE PREVENTED BY ENSURING
VENTILATION CONTROLS, VAP EXHAUST/ FRESH AIR ENTRY. NIOSH APPRVD (TC-23C) AIR
PURIFYING/AIR SUPPLIED (TC-19C) RESPS MAY ALSO REDUCE EXPOS. READ RESP MFR'S
INSTRUCTION & LITERATURE CAREFULLY TO DERTERMINE THE TYPE OF AIRBORNE
CONTAMINANTS AGAINST WHICH RESPIRATOR IS EFFECTIVE & HOW IT IS TO BE
PROPERLY FITTED.
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
CONC OF INGREDS LISTED IN SECTION 2 BELOW LOWEST SUGGESTED EXPOS LIMITS, LEL
BELOW (OTHER INFO)
Protective Gloves: NEOPRENE RUBBER OR NITILE RUBBER.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYE WASH & DELUGE SHWR MTG ANSI DESIGN CRIT (FP N).
WEAR PROT CLTHG. NO SPECIFIC PERMEATION/DEGRADATION TESTING HAVE BEEN DONE ON
PROT CLTHG OF THIS PROD. RECOMS FOR SKIN PROT ARE BASED ON(OTHER INFO)
Supplemental Safety and Health: HLTH HAZ: & KIDNEY, ANEMIA, LIVER CANCER
& CATERACTS. SIGNS & SYMPS OF OVEREXP: EYE WATERING, HDCHS, NAUS,
DIZZ, & LOSS OF COORDINATION ARE INDICATIONS THAT SOLV LEVS ARE TOO HIGH.
INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN BE
HARMFUL/FATAL. EXPLO HAZ: FROM HEAT, SPKS, FLAME, & OTHER (OTHER INFO)
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Physical/Chemical Properties
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Boiling Point: >152.2C, 306.F
B.P. Text: 306-468F
Vapor Pres: 15 MM HG
Vapor Density: HVR/AIR
Spec Gravity: 1.289
Evaporation Rate & Reference: 12 (BU O AC = 100)
Solubility in Water: 0.4%
Appearance and Odor: VISCOUS LIQUID WITH AN ODOR CHARACTERISTIC OF THE SOLVENTS
LISTED IN SECTION 2.
Percent Volatiles by Volume: 58.400
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRODUCE FOLLOWING HAZ DECOMP PRODS WHEN
EXPOSED TO EXTREME HEAT: CO, CO*2 ; LOWER MOLECULAR WEIGHT POLYMER FRACTIONS;
.. EXTREME HEAT INCLS, BUT IS NOT LIMITED TO, FLAME CUTTING, BRAZING, &
WELDING.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Regulatory Information
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Sara Title III Information: SARA 311/312: AC: NAPHTHA & METHYL ETHYL
KETOXIME; CH: SILICA CRISTOBALITE, QUARTZ AND METHYL ETHYL KETOXIME; GL:
NAPHTHA AND METHYL ETHYL KETOXIME. SARA 311/312 CATEGORIES FOR THIS PRODUCT:
ACUTE = Y, CHRONIC = Y, FLAMMABILITY = Y, PRESSURE = N, REACTIVITY = N.
SARA 102 RQ (LBS): NONE. SARA 302 TPQ (LBS): NONE.
SARA 313: NONE.
Federal Regulatory Information: PRODUCT STATUS RELATIVE TO THE U S EPA TOXIC
SUBSTANCES ACT: ALL CHEMICAL SUBSTANCES IN THIS PRODUCT ARE LISTED ON THE U S
TSCA INVENTORY OR ARE OTHERWISE APPROVED FOR UNRESTRICTED COMMERICAL USE UNDE
R TSCA.
State Regulatory Information: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
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Other Information
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Other Information: SUPDAT: SOURCES OF IGNITION (I.E., PILOT LIGHTS, ELECTRIC
MOTORS, STATIC ELECTRICITY). IRIVISIBLE VAPORS CAN TRAVEL TO SOURCE OF IGNIT
& FLASH BACK. DO NOT SMOKE WHILE USING THIS PROD. KEEP CNTNRS TIG HTLY
CLOSED WHEN NOT IN USE. CLOSED CONTAINERS MAY EXPLODE WHEN OVERHEATED. DO NOT
APPLY TO HOT SURFACES. TOXIC GASES MAY FORM WHEN THIS PRODUCT COMES IN CTNCT
W/EXTREME HEAT (SEE SECTION 10 OF THIS M SDS). VENT: STATED LIMIT, & TO
REMOVE DECOMPOSITION PRODS DURING WELDING/FLAME CUTTING. OTHER PROT EQUIP:
INFREQUENT CONTACT W/THIS PROD. FOR FREQUENT CONTACT/TOTAL IMMERSION, CONTACT
MFR OF PROT CLOT HING FOR APPROP CHEM IMPERVIOUS EQUIP.
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HAZCOM Label
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MSDS NAME: ALKYD FLAT INTERIOR MIDTO, 6-66
Company: PPG INDUSTRIES INC
Street: ONE PPG PLACE
City: PITTSBURGH PA
Zipcode: 15272
Health Emergency Phone: 304-843-1300
Label Required IND: Y
Date Of Label Review: 09/09/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: INGEST: MAY BE HARMFUL IF
SWALLOWED. EYE: CAUSES IRRIT. SKIN: MAY CAUSE SLIGHT IRRIT. INHAL: VAP
&/SPRAY MISTS MAY BE HARMFUL. VAP IRRIT EYES, NOSE & THROAT. SANDING
& GRINDING DUS TS MAY BE HARMFUL. CHRONIC: CANCER HAZARD. CONTAINS
CRYSTALLINE SILICA QUARTZ AND CRISTOBALITE WHICH ARE LISTED AS HUMAN LUNG
CARCINOGENS (FP N). RPTD EXPOS TO HIGH VAP CONCS MAY CAUSE IRRIT OF RESP S YS
& PERMANENT BRAIN & NERVOUS SYS DMG. LONG-TERM EXPOS TO CRYSTALLINE
SILICA/QUARTZ MAY ALSO LEAD TO A DISABILING INJURY KNOWN AS SILICOSIS.
OVEREXP TO METHYL ETHYL KETOXIME CAN CAUSE ADVERSE EFTS IN SPLEEN &
KIDNEY, LIVER CANCER & CATARACTS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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