INTEGRA CHEMICAL COMPANY -- HYDROGEN PEROXIDE, 50%, H772.50
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Material Safety Data Sheet
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MSDS Num: CJQVR
MSDS NAME: HYDROGEN PEROXIDE, 50%, H772.50
Responsible Party
Name: INTEGRA CHEMICAL COMPANY
Address: 710 THOMAS AVE SW
City: RENTON WA 98055
Info Phone: 425-277-9244
Emergency Phone Number: 800-451-8346
Resp. Party Other MSDS No.: H772 REV. 002
Review Ind: Y
Published: Y
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Contractor Summary
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Name: INTEGRA CHEMICAL COMPANY
Address: 710 THOMAS AVE SW
City: RENTON WA 98055
Phone: 425-277-9244
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Item Description Information
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Ingredients
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
Percent by Wt: 50.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 7722-84-1
RTECS #: MX0899000
Name: HYDROGEN PEROXIDE
Percent by Wt: 50.
Other REC Limits: N/K (FP N)
OSHA PEL: 1.4 MG/M3;1 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 1.4 MG/M3;1 PPM
ACGIH STEL: N/K (FP N)
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Health Hazards Data
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LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: SKIN: BRIEF EXPOSURE WILL IRRITATE AND BLEACH SKIN.
LONGER EXPOSURE CAUSES SEVERE IRRITATION, BLISTERS AND BURNS. EYES: VAPORS
WILL IRRITATE EYES. LIQUID AND MISTS WILL IRRITATE AND MAY BURN EY ES. THIS
PRODUCT IS CORROSIVE TO EYES AND ITS EFFECTS MAY BE DELAYED. DIRECT LIQUID
CONTACT ON EYES MAY CAUSE IRREVERSIBLE DAMAGE OR BLINDNESS. INGESTION: THE
LIQUID IS SEVERELY IRRITATING TO MOUTH AN D THROAT. SWALLOWING LIQUID MAY
CAUSE SUDDEN EVOLUTION OF OXYGEN, WHICH CAN CAUSE INJURY BY DISTENSION OF
ESOPHAGUS OR STOMACH. LOCAL INTERNAL BLEEDING MAY RESULT. GROSS OVEREXPOSURE
BY INGESTION MAY BE FATAL. (EFFECTS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: NONE IDENTIFIED.
Signs And Symptions Of Overexposure: HEALTH HAZARDS: INHALATION: VAPORS AND
MISTS SEVERELY IRRITATE THE NOSE AND THROAT. SYMPTOMS MAY INCLUDE CHEST
DISCOMFORT, COUGH, DIFFICULTY IN BREATHING AND SHORTNESS OF BREATH. CHRONIC:
NONE IDENTIF IED. TARGET ORGANS: NONE IDENTIFIED.
Medical Cond Aggravated By Exposure: SKIN AND RESPIRATORY CONDITIONS.
First Aid: SKIN: IMMED REMOVE CONTAMINATED CLOTHING. FLUSH SKIN W/WATER FOR AT
LEAST 15 MINS. SEEK IMMED MED ATTN. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS.
SEEK IMMED MED ATTN. INHAL: REMOVE TO FRESH AIR. IF NO T BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. SEEK
MED ATTN. INGEST: DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSC IOUS PERSON. SEEK IMMED MED ATTN. ADDITIONAL
FIRST AID & TREATMENT NOTES: IF SWALLOWED, LARGE AMOUNTS OF OXYGEN MAY BE
RELEASED QUICKLY. DISTENTION OF STOMACH/ESOPHAGUS MAY BE INJURIOUS. INSERTION
OF GASTRIC LAVAGE TUBE MAY BE ADVISABLE.
=======================================================
Handling and Disposal
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Spill Release Procedures: PREVENT SPREAD OF SPILL. ELIMINATE POTENTIAL SOURCES
OF IGNITION AND CONTAMINATION. WEAR FULL PROTECTIVE EQUIPMENT. FLOOD AREA
WITH WATER AND DRAIN TO AN APPROVED CHEMICAL SEWER OR WASTEWATER TREATMEN T
SYSTEM. MAY BE DESTROYED WITH SODIUM METABISULFITE OR SODIUM SULFITE (1.9 LBS
SO*2 EQUIVALENT PER LB OF PEROXIDE) AFTER DILUTING TO 5-10% PEROXIDE.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL DRY, WELL-VENTILATED AREA
DEDICATED TO OXIDIZER STORAGE. KEEP WELL AWAY FROM INCOMPATIBILITIES AND
POTENTIAL SOURCES OF CONTAMINATION. KEEP OUT OF LIGHT. KEEP CONTAINERS
TIGHTLY CLOSED WHEN NOT IN USE. REGULARLY VENT CONTAINERS TO PREVENT
DANGEROUS BUILD-UP OF OXYGEN GAS.
Other Precautions: STORAGE AREA: OXIDIZER. DANGER! STRONG OXIDIZER. CONTACT
WITH FLAMMABLE OR COMBUSTIBLE MATERIALS MAY CAUSE FIRE OR EXPLOSION. CAUSES
SEVERE IRRITATION OR BURNS. DO NOT ALLOW CONTACT WITH SKIN, EYES AN D
CLOTHING. USE ONLY WITH ADEQUATE PROTECTIVE EQUIPMENT. HARMFUL IF SWALLOWED
OR INHALED.
=======================================================
Fire and Explosion Hazard Information
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Extinguishing Media: USE ONLY WATER.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). USE WATER TO COOL NEARBY CONTAINERS AND STRUCTURES.
Unusual Fire/Explosion Hazard: THIS CHEMICAL MAY CAUSE A FIRE IF IT DRYS ON
CLOTHING, WOOD, OR OTHER COMBUSTIBLES. CONTACT WTH FLAMMABLE LIQUIDS OR
VAPORS MAY CAUSE IMMEDIATE FIRE OR EXPLOSION. DECOMPOSITION WILL RELEASE
OXYGEN WHI CH WILL INCREASE THE EXPLOSIVE LIMITS AND BURNING RATE OF VAPORS.
=======================================================
Control Measures
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Respiratory Protection: NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS
EXIST. IF AIRBORNE CONCENTRATION EXCEEDS THE PEL OR TLV, A NIOSH APPROVED
DUST/MIST RESPIRATOR IF RECOMMENDED.
Ventilation: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV AND PEL
REQUIREMENTS.
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD (FP N).
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N). PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE. NATURAL
RUBBER, NITRILE, OR POLYVINYLCHLORIDE AFFORD ADEQUATE PROTECTION.
Work Hygienic Practices: DO NOT WEAR LEATHER GLOVES OR LEATHER SHOES BECAUSE
THEY CAN IGNITE FOLLOWING CONTACT WITH PEROXIDE.
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Physical/Chemical Properties
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Boiling Point: =114.C, 237.2F
Melt/Freeze Pt: =-52.2C, -61.1F
Vapor Pres: 13.5 MM HG @ 20C
Spec Gravity: 1.19 (WATER=1)
Solubility in Water: MISCIBLE
Appearance and Odor: CLEAR, COLORLESS LIQUID WITH A SLIGHTLY IRRITATING,
PUNGENT ODOR.
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Reactivity Data
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Stability Indicator: NO
Stability Condition To Avoid: EXCESSIVE HEAT, LIGHT OR CONTAMINATION OF ANY
KIND.
Materials To Avoid: REDUCING AGENTS, COMBUSTIBLES, METALS, CYANIDES, HEXAVALENT
CHROME COMPOUNDS, NITRIC ACID.
Hazardous Decomposition Products: CONTAMINATION OR HEAT MAY CAUSE A
SELF-ACCELERATING EXOTHERMIC DECOMPOSITION WITH OXYGEN GAS AND STEAM RELEASE
THAT CAN CAUSE DANGEROUS PRESSURE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: TOXICITY DATA: WATER: NO INFORMATION AVAILABLE.
HYDROGEN PEROXIDE: LC50 (INHALATION, RAT) HYDROGEN PEROXIDE 90% >2000
PPM/8H. LD50 (SKIN, RAT) HYDROGEN PEROXIDE 35% >2000 MG/KG. LD50 (ORAL,
RAT) HYDRO GEN PEROXIDE 35% 1232 MG/KG. REPRODUCTIVE EFFECTS: NONE
IDENTIFIED.
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Ecological Information
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MSDS Transport Information
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Transport Information: REGULATED MATL DOMESTIC GROUND TRANSPORTATION
(REFERENCE: CFR TITLE 49, TRANSPORTATION): PROPER SHIPPING NAME: HYDROGEN
PEROXIDE, AQUEOUS SOLN. UN/NA IDENTIFICATION #: UN2014. HAZ CLASS &
LABEL: 5.1 O XIDIZER. PACKING GROUP: II. SUBSIDIARY RISK & LABEL: 8 CORR.
REGULATED MATL VIA AIR TRANSPORTATION (REFERENCE: ICAO TECHNICAL INSTRUCTIONS
FOR SAFE TRANSPORT OF DANGEROUS GOODS BY AIR): PROPER SHIPPIN G NAME:
HYDROGEN PEROXIDE, AQUEOUS SOLN. UN IDENTIFICATION #: UN2014. HAZ CLASS &
LABEL: 5.1 OXIDIZER. PACKING GROUP: II. SUBSIDIARY RISK & LABEL: 8 CORR.
(OTHER INFO)
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Regulatory Information
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Sara Title III Information: SARA HAZARD CATEGORIES: HYDROGEN PEROXIDE: ACUTE,
PRESSURE, REACTIVITY. SARA EHS TPQ: HYDROGEN PEROXIDE: 1000 LBS.
Federal Regulatory Information: HYDROGEN PEROXIDE LISTED IN TSCA INVENTORY.
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Other Information
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Other Information: TRANSPORTATION INFORMATION: PACKING INSTRUCTION: PASSENGER
AIRCRAFT/CARGO AIRCRAFT: FORBIDDEN. MAX NET QTY PER PACKAGE: PASSENGER
AIRCRAFT/CARGO AIRCRAFT: N/A. CHEMICAL FORMULA: H*2O*2. FORMULA WEIGHT :
34.01. CHEMICAL FAMILY: PEROXIDE. RATING: 3-0-3-F. NFPA RATING:2-0-1-OX.
MSDS REVISION HISTORY: 002 - CHANGED HEADER PHONE NUMBER.
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HAZCOM Label
=======================================================
MSDS NAME: HYDROGEN PEROXIDE, 50%, H772.50
Company: INTEGRA CHEMICAL COMPANY
Street: 710 THOMAS AVE SW
City: RENTON WA
Zipcode: 98055
Health Emergency Phone: 800-451-8346
Label Required IND: Y
Date Of Label Review: 09/21/1999
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN: WILL IRRIT & BLEACH SKIN.CAN CAUSE SEV
IRRIT, BLISTERS & BURNS. EYES: IRRIT & MAY BURN EYES. THIS PROD IS
CORR TO EYES & ITS EFTS MAY BE DELAYED. DIRECT LIQ CONT ON EYES MAY CAUSE
IRREVER SIBLE DMG/BLINDNESS. INGEST: LIQ IS SEV IRRIT TO MOUTH & THROAT.
SWALLOWING LIQUID MAY CAUSE SUDDEN EVOLUTION OF OXYG, WHICH CAN CAUSE INJURY
BY DISTENSION OF ESOPHAGUS/STOMACH. LOCAL INTERNAL BLEEDIN G MAY RSLT. GROSS
OVEREXP BY INGEST MAY BE FATAL. INHAL:VAPS & MIST SEV IRRIT NOSE &
THROAT. SYMPS MAY INCL CHEST DISCOMFORT, COUGH, DFCLTY BRTHG, & SHORT
BRTH. CHRONIC: NONE IDENTIFIED. TARGET ORGAN S: NONE IDENTIFIED.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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