EXXON COMPANY USA -- UNIREX N2, 415172-05172
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Material Safety Data Sheet
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MSDS Num: CJRBW
MSDS NAME: UNIREX N2, 415172-05172
Responsible Party
Name: EXXON COMPANY USA
Box: 2180
City: HOUSTON TX 77252-2810
Info Phone: 800-443-9966
Emergency Phone Number: 713-656-3424
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: EXXON MOBIL LUBRICANTS AND PETROLEUM SPECIALTIES CO.
Address: 3225 GALLOWS RD
City: FAIRFAX VA 22037
Phone: 703-846-4240
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Item Description Information
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL, RAT) 5 G/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: HEALTH STUDIES HAVE SHOWN THAT MANY PETROLEUM HYDROCARBONS
& SYNTHETIC LUBRICANTS POSE POTNTL HUMAN HEALTH RISKS WHICH MAY VARY FROM
PERSON TO PERSON. AS PREC, EXPOS TO LIQS, VAPS, MISTS OR FUMES SHOU LD BE
MINIMIZED. PRLNGD/RPTD SKIN CNTCT MAY CAUSE SKIN IRRIT. RPTD & PRLNGD
OVEREXP TO OIL MISTS MAY RSLT IN DROPLET DEPOSITION, OIL GRANULOMA FORM,
INFLAM & INCREASED INCIDENCE OF INFECTION. I/A/W CU RRENT OSHA HAZ
COMMUNICATION STANDARD CRITERIA, THIS PROD DOES NOT REQ CANCER HAZ WARNING.
THIS IS BECAUSE PROD IS FORMULATED FROM BASE STOCKS WHICH ARE SEVERELY
HYDROTREATED, SEVERELY SOLVENT EXTRACT ED &/OR PROCESSED (EFTS OF
OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZS: BY MILD HYDROTREATMENT &
EXTRACTION. ALTERNATIVELY, IT MAY CONSIST OF COMPONENTS NOT OTHERWISE
AFFECTED BY IARC CRITERIA SUCH AS ATMOSPHERIC DISTILLATES OR SYNTHETICALLY
DERIVED MATLS, & AS SUCH IS NOT CHARACTERIZED BY CURRENT IARC
CLASSIFICATION CRITERIA. PRLNGD/RPTD SKIN CNTCT W/PROD TENDS TO REMOVE SKIN
OILS, POSS LEADING TO IRRIT & DERM; HOWEVER, BASED ON HUMAN EXPERIENCE
& AVAIL TO XICOLOGICAL DATA, THIS PROD IS JUDGED NEITHER "CORR" NOR
"IRRITANT" BY OSHA CRITERIA. PROD CONTACTING EYES MAY CAUSE IRRIT. PROD HAS
LOW ORDER OF ACUTE ORAL & DERMAL TOX, BUT MINUTE AMTS ASPIRATED INT O
LUNGS DURING (TOXICOLOGICAL INFO)
Medical Cond Aggravated By Exposure: NONE RECOGNIZED.
First Aid: EYE:IF LUBRICANT GETS INTO EYES, FLUSH W/CLEAR WATER FOR AT LST 15
MIN OR UNTIL IRRIT SUBSIDES. IF IRRIT PERSISTS, CALL MD. SKIN: IN CASE OF
CNTCT, REMOVE ANY CONTAM CLTHG & WASH SKIN W/SOAP & WATER.
LAUNDER/DRY-CLEAN CLTHG BEFORE REUSE. IF PROD INJECTED INTO OR UNDER SKIN OR
INTO ANY PART OF BODY, REGARDLESS OF APPEAR OF WOUND OR ITS SIZE, INDIVIDUAL
SHOULD BE EVALUATED IMMED BY MD AS SURGICAL EM ER. EVEN THOUGH INITIAL SYMPS
FROM HIGH PRESS INJECTION MAY BE MINIMAL/ABSENT, EARLY SURGICAL TREATMENT
W/IN FIRST FEW HRS MAY SIGNIFICANTLY REDUCE ULTIMATE EXTENT OF INJURY. INHAL:
VAP PRESS VERY LOW . VAP INHAL UNDER (TOXICOLOGICAL INFO)
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Handling and Disposal
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Spill Release Procedures: RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER
SUITABLE ABSORBENT TO SPILL AREA. MINIMIZE SKIN CONTACT. KEEP PRODUCT OUT OF
SEWERS AND WATERCOURSES BY DIKING OR IMPOUNDING. ADVISE AUTHORITIES IF PRODU
CT HAS ENTERED OR MAY ENTER SEWERS, WATERCOURSES OR EXTENSIVE LAND AREAS.
ASSURE CONFORMITY WITH APPLICABLE GOVERNMENTAL REGULATIONS.
Waste Disposal Methods: DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS (FP N).
Handling And Storage Precautions: USE PRODUCT WITH CAUTION AROUND HEAT, SPARKS,
PILOT LIGHTS, STATIC ELECTRICITY AND OPEN FLAME. KEEP CONTAINERS CLOSED WHEN
NOT IN USE. DO NOT STORE NEAR HEAT, SPARKS, FLAME OR STRONG OXIDANTS. IN ORDE
R TO PREVENT FIRE/EXPLOSION HAZARDS, USE APPROPRIATE EQUIPMENT.
Other Precautions: TO PVNT FIRE OR EXPLO RISK FROM STATIC ACCUM &
DISCHARGE, EFTIVELY BOND &/OR GROUND PROD TRANSFER SYS I/A/W NFPA
PUBLICATIONS. INFO ON ELEC EQUIP APPROP FOR USE W/PROD MAY BE FOUND IN LATEST
EDITION O F NATL ELECTRICAL CODE (NFPA-70). THIS DOCUMENT IS AVAIL FROM NFPA,
BATTERYMARCH PARK, QUINCY, MA 02 269.
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point: =246.1C, 475.F
Autoignition Temp: >260.C, 500.F
Lower Limits: 0.9%
Upper Limits: 7%
Extinguishing Media: FOAM, WATER SPRAY (FOG), DRY CHEM, CARBON DIOXIDE &
VAPORIZING LIQ TYPE EXTING AGENTS MAY ALL BE SUITABLE FOR EXTING FIRES
INVOLVING THIS TYPE PROD, DEPENDING ON (ECOLOGICAL INFO)
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
FOLLOWING PROCEDURES FOR THIS TYPE OF PROD ARE BASED ON RECOMS IN NFPA'S
"FIRE PROT GUIDE ON HAZ MATLS," 10TH EDITION (1991); USE WATER SPRAY, DRY
CHEM, FOAM OR CARBON DIOXIDE TO EXTING FIRE. USE WATER TO KEEP FIRE-EXPOS
CNTNRS COOL. IF LEAK OR SPILL (ECOLOGICAL INFO)
Unusual Fire/Explosion Hazard: NFPA HAZ IDENTIFICATION: HLTH-1; FLAM-1;
REACTIVITY-0; BASIS-RECOM BY EXXON. DECOMP PRODS UNDER FIRE CNDTNS:FUMES,
SMOKE, CARBON MONOXIDE, SULFUR OXIDES, NITROGEN OXIDES, METAL OXIDES,
ALDEHYDES & OTH ER DECOMP PRODS, IN CASE OF INCOMPLETE COMBUST. "EMPTY"
CNTNRS RETAIN RESIDUE (LIQ &/OR VAP) & CAN (TRANSPORT INFO)
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Control Measures
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Respiratory Protection: USE NIOSH APPROVED SUPPLIED-AIR RESPIRATORY PROTECTION
IN CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation: USE LOC EXHST TO CAPTURE VAP, MISTS/FUMES, IF NEC. PROVIDE VENT
SUFFICIENT TO PVNT EXCEEDING RECOM EXPOS LIMIT OR BUILDUP OF EXPLO CONCS OF
VAP (STATE REG INFO)
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). USE
CHEMICAL-RESISTANT APRON OR OTHER IMPERVIOUS CLOTHING, IF NEEDED, TO AVOID
CONTAMINATING REGULAR CLOTHING, WHICH COULD RSLT IN PRLNGD/RPTD SKIN CNTCT.
Work Hygienic Practices: MINIMIZE BRTHG VAP, MIST/FUMES. AVOID PRLNGD/RPTD
CNTCT W/SKIN. REMOVE CONTAM CLTHG; LAUNDER/DRY-CLEAN BEFORE REUSE. REMOVE
CONTAM SHOES & THOROUGHLY CLEAN BEFORE REUSE; DISCARD IF (STATE REG INFO)
Supplemental Safety and Health: PHYSICAL DATA: DATA GIVEN ARE APPROX/TYPICAL
VALUES & SHOULD NOT BE USED FOR PRECISE DESIGN PURPOSES. MW: NOT DETERM.
VISCOSITY: 280 WORKED PENETRATION, MM/10, @ 25C, ASTM 217. EVAP RATE: <1 @
1 ATM & 25C(77F) (N-BUTYL ACETATE=1). % VOLAT BY VOL: NEGLIG FROM OPEN
CNTNR IN 4 HRS @ 38C(100F).
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Physical/Chemical Properties
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Boiling Point: =388.C, 730.4F
B.P. Text: IBP
Melt/Freeze Pt: >304.C, 579.2F
M.P/F.P Text: DROPPING PT BY ASTM D2265
Vapor Pres: <0.01 MM HG @ 20C
Vapor Density: >5 (AIR=1)
Spec Gravity: 0.93 (15.6C/15.6C)
PH: ESSNTLY NEUT
Viscosity: SUPDAT
Evaporation Rate & Reference: SUPDAT
Solubility in Water: NEGLIG;
Appearance and Odor: SMOOTH DARK GREEN GREASE; MILD, BLAND ODOR.
Percent Volatiles by Volume: SUPDAT
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THIS PRODUCT IS STABLE AND WILL NOT REACT
VIOLENTLY WITH WATER.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDANTS SUCH AS LIQUID CHLORINE,
CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE, CALCIUM HYPOCHLORITE, ETC, AS THIS
PRESENTS A SERIOUS EXPLOSION HAZARD.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: N/P. EFTS OF OVEREXP: INGEST OR VOMIT MAY CAUSE MILD
TO SEV PULM INJURY & POSSIBLY DEATH. PROD IS JUDGED TO HAVE ACUTE DERMAL
LD50 (RABBIT) GREATER THAN 3.16 G/KG OF BODY WT. FIRST AID PROC: AMBIENT C
NDTNS IS NORMALLY NOT A PROBLEM. IF OVERCOME BY VAP FROM HOT PROD, IMMED
REMOVE FROM EXPOS & CALL MD. IF BRTHG IS IRREGULAR OR HAS STOPPED, START
RESUSCITATION; ADMINISTER OXYGEN, IF AVAILABLE. IF OVE REXPOSED TO OIL MIST,
REMOVE FROM FURTHER EXPOS UNTIL EXCESSIVE OIL MIST CONDITION SUBSIDES.
INGEST: IF INGESTED, DO NOT INDUCE VOMITING; CALL MD IMMED.
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Ecological Information
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Ecological: THIS PROD MAY BE CLASSIFIED AS OIL UNDER SECTION 311 OF CLEAN WATER
ACT & UNDER OIL POLLUTION ACT. DISCHARGES OR SPILLS INTO OR LEADING TO
SURF WATERS THAT CAUSE SHEEN MUST BE REPORTED TO NRC (1-800-4 24-8802).
EXTING MEDIA: SIZE OR POTNTL SIZE OF FIRE & CIRCUMSTANCES RELATED TO
SITUATION. PLAN FIRE PROT & RESPONSE STRATEGY THRU CONSULTATION W/LOCAL
FIRE PROT AUTHS OR APPROP SPECIALISTS. FIRE FIGHT PROCS: HAS NOT IGNITED,
USE WATER SPRAY TO DISPERSE VAPS & TO PROVIDE PROT FOR PERS ATTEMPTING TO
STOP LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOSURES.
MINIMIZE BRTHG OF GASES, VAP, FUMES OR DECOMP (TRANSPORT INFO)
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MSDS Transport Information
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Transport Information: TRANSPORTATION INCIDENT INFO: FOR FURTHER INFO RELATIVE
TO SPILLS RSLTG FROM TRANSPORTATION INCIDENTS, REFER TO LATEST DOT EMER
RESPONSE GUIDEBOOK FOR HAZ MATLS INCIDENTS. US DOT HAZ MATLS SHIPPING DE
SCRIPTION: NOT REGULATED. ECOLOGICAL INFO: PRODS. USE NIOSH APPRVD
SUPPLIED-AIR BRTHG EQUIP FOR ENCLSD/CONFINED SPACES/AS OTHERWISE NEEDED.
EXPLO HAZ: BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE , SOLDER, DRILL,
GRIND/EXPOSE SUCH CNTNRS TO HEAT, FLAME, SPKS, STATIC ELEC/OTHER IGNIT
SOURCES; THEY MAY EXPLODE & CAUSE INJURY/DEATH. DO NOT ATTEMPT TO
REFILL/CLEAN CNTNRS SINCE RESIDUE IS DFCLT TO REMOVE. "EMPTY" DRUMS (SARA
REG INFO)
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Regulatory Information
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Sara Title III Information: THRESHOLD PLANNING QTY (TPQ), EPA REG 40 CFR 355
(SARA SECTIONS 301-304): NO TPQ FOR PROD OR ANY CONSTITUENT >1% OR 0.1%
(CARCIN). TOX CHEM RELS REPORTING, EPA REG 40 CFR 372 (SARA SECTION 313): NO
TO X CHEM IS PRESENT >1% OR 0.1% (CARCIN). HAZ CHEM REPORTING, EPA REG 40
CFR 370 (SARA SECTIONS 311-312): EPA HAZ CLASSIFICATION CODE: NOT APPLIC.
TRANSPORT INFO: SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY
RETURNED TO DRUM RECONDITIONER. ALL OTHER CNTNRS SHOULD BE DISPOSED OF IN
ENVIRONMENTALLY SAFE MANNER & I/A/W FED, STATE & LOCAL GOVT REGS. FOR
WORK ON TANKS REFER TO OSHA REGS, ANSI Z49.1 & OTHER GOVT & (FED REG
INFO)
Federal Regulatory Information: TOX SUBSTANCE CTL ACT: PROD CNTNS FOLLOWING
TSCA 12B REPORTABLE CHEM SUBSTANCE: ISOPROPANOL (IPA) CAS #67-63-0. OSHA REQD
LABEL INFO: IN COMPLIANCE W/HAZ & RIGHT-TO-KNOW REQS, WHEE APPLIC OSHA
HAZ WAR NINGS MAY BE FOUND ON LABEL, BILL OF LADING OR INVOICE ACCOMPANYING
SHIPMENT. NOTE: PROD LABEL MAY CNTN NON-OSHA RELATED INFO ALSO. ALL
COMPONENTS OF PROD ARE LISTED ON US TSCA INVENTORY. SARA REG INF O: INDUS
REFERENCES PERTAINING TO CLEANING, REPAIRING OR OTHER CONTEMPLATED
OPERATIONS. "EMPTY" DRUM LINERS RETAIN RESIDUE (SOLID, LIQ &/OR VAP)
THAT WILL BURN & CAN BE DANGEROUS. KEEP AWAY FROM HEAT, SPKS, FLAMES,
STATIC (STATE REG INFO)
State Regulatory Information: N/P. FED REG INFO: ELEC/OTHER IGNIT SOURCES. DO
NOT REUSE LINERS FOR ANY PURPOSE WHATSOEVER. LINERS SHOULD BE EMPTIED OF
CONTENTS TO MAX EXTENT PRACTICAL, THEN SEGREGATED FROM LINERS CONTAINING
OTHER PRODS. DISPOSE OF "EMPTY" LINERS IN ENVIRONMENTALLY SAFE MANNER &
I/A/W FED, STATE & LOC REGS. VENT: IN AIR. NO SMOKING OR USE OF FLAME OR
OTHER IGNIT SOURCES. HYGIENE PRACTS: OIL-SOAKED. CLEANSE SKIN THOROUGHLY
AFTER CNTCT, BEFORE BREAKS MEALS & AT END OF WORK PERIOD. PROD IS
READILY REMOVED FROM SKIN BY WATERLESS HAND CLEANERS FOLLOWED BY WASHING
THOROUGHLY W/SOAP & WATER.
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Other Information
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Other Information: PROD CATEGORY: PETRO LUBRICATING GREASE. THIS PROD, AS
MANUFACTURED BY EXXON, DOES NOT CNTN POLYCHLORINATED BIPHENYLS (PCB'S). :
HLTH-1; FLAM-1; REACTIVITY-0; BASIS: RECOM BY EXXON. EXPOS LIM FOR TOTOAL
PROD: 5 MG/M3 FOR OIL MIST (AEROSOL) FOR 8-HR WORKDAY; BASIS: OSHA REG 29 CFR
1910.1000 & RECOM BY ACGIH. ACGIH STATES AIR IS TO BE SAMPLED BY METH
THAT DOES NOT COLLECT VAP; IN ADDN, IT LISTS 10 MG/M3 STEL. HLTH & SFTY
INFO PRESENTED MUST BE USED IN CONJUNCTION W/PERTINENT STDS FOR TRAINING,
WORK PRACTS & FACILITIES DESIGN ESTABLISHED BY OSHA, NIOSH, NFPA, API,
NEC, NSC, UNDERWRITERS, BURE AU OF MINES & SIMILAR ORGANIZATIONS.
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HAZCOM Label
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MSDS NAME: UNIREX N2, 415172-05172
Company: EXXON MOBIL LUBRICANTS AND PETROLEUM SPECIALTIES CO.
Street: 3225 GALLOWS RD
City: FAIRFAX VA
Zipcode: 22037
Health Emergency Phone: 713-656-3424
Label Required IND: Y
Date Of Label Review: 10/27/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN: MAY CAUSE IRRIT. PRODUCT CONTACTING EYES
MAY CAUSE IRRITATION. ACUTE ORAL & DERMAL TOX, BUT MINUTE AMTS ASPIRATED
INTO LUNGS DURING INGEST OR VOMIT MAY CAUSE MILD TO SEV PULM INJURY & P
OSS DEATH. CHRONIC:SKIN: RPTD/PRLNGD OVEREXP TO OIL MISTS MAY RSLT IN
DROPLET DEPOSITION, OIL GRANULOMA FORM, INFLAM & INCREASED INCIDENCE OF
INFECTION. PROLONGED & REPEATED SKIN CONTACT WITH PRODUC T TENDS TO
REMOVE SKIN OILS, POSS LEADING TO IRRIT & DERM, ALTHOUGH THIS PRODUCT IS
JUDGED NEITHER CORROSIVE NOR IRRITANT BY OSHA CRITERIA.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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