HERCULES INCORPORATED -- STAYBELITE PARTIALLY HYDROGENATED ROSIN, MOLT
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Material Safety Data Sheet
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MSDS Num: CKFLX
MSDS NAME: STAYBELITE PARTIALLY HYDROGENATED ROSIN, MOLTEN
Responsible Party
Name: HERCULES INCORPORATED
Address: HERCULES PLAZA
City: WILMINGTON DE 19894
Info Phone: 302-594-5000
Emergency Phone Number: 302-594-5000
Resp. Party Other MSDS No.: 853 2155 0100-04
Published: Y
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Contractor Summary
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Name: HERCULES INCORPORATED
Address: HERCULES PLAZA
City: WILMINGTON DE 19894
Phone: 302-594-5000
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Ingredients
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Cas: 65997-06-0
Name: HYDROGENATED ROSIN (PARTIALLY HYDROGENATED WOOD ROSIN)
Percent by Wt: 100.
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: DANGER! MOLTEN RESIN. CAUSES SEVERE BURNS ON CONTACT.
SIGNS AND SYMPTOMS OF OVEREXPOSURE IN THE WORKPLACE: EYES: BURNS CAN CAUSE
IRREVERSIBLE EYE INJURY AND BLINDNESS. SMOKE OR FUMES FROM ROSIN PRODU CTS
MAY CAUSE EYE IRRITATION WITH REDNESS, TEARING AND DISCOMFORT. SKIN: SERIOUS
BURNS WILL RESULT FROM CONTACT WITH MOLTEN PRODUCT. REPEATED OR PROLONGED
CONTACT MAY CAUSE ALLERGIC SKIN REACTION (SE NSITIZATION) IN SUSCEPTIBLE
INDIVIDUALS. SEE MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. INHALATION:
BREATHING SMOKE OR FUMES FROM MOLTEN ROSIN PRODUCTS MAY PRODUCE BREATHING
DISCOMFORT, COUGHING AND SORE THROAT. INGESTION: NONE KNOWN.
Explanation Of Carcinogenicity: NONE OF THE COMPONENTS OF THIS PRODUCT ARE
LISTED AS CARCINOGENS BY THE NATIONAL TOXICOLOGY PROGRAM (NTP). THEY ARE NOT
REGULATED AS CARCINOGENS BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(O SHA) AND HAVE NOT BEEN EVALUATED BY THE INTERNATIONAL AGENCY FOR RESEARCH
ON CANCER (IARC).
Signs And Symptions Of Overexposure: MED COND (CONT): AFTER REPEATED OR
PROLONGED SKIN CONTACT. HERCULES INCORPORATED IS UNAWARE OF ANY ALLERGIC
REACTIONS CAUSED BY INDUSTRIAL EXPOSURE TO THIS PRODUCT OR SIMILAR MATERIALS.
A THOROUGH SEA RCH OF HECULES MEDICAL RECORDS HAS DISCLOSED NO CASE OF SKIN
SENSITIZATION TO ROSIN OR ITS DERIVITIVES FROM INDUSTRIAL EXPOSURE IN OUR
WORKERS. NONE HAVE BEEN REPORTED BY OUR CUSTOMERS. REPORTED HUMA N EFFECTS:
PROLONGED EXPOSURE TO SMOKE OR FUMES GENERATED BY HEATING THIS PRODUCT MAY
CAUSE RESPIRATORY IRRITATION WITH THROAT DISCOMFORT, COUGHING OR BREATHING
DIFFICULTY. REPEATED EXPOSURE MAY LEAD TO RESPIRATORY SENSITIZATION
(ASTHMA).
Medical Cond Aggravated By Exposure: THIS PRODUCT CONTAINS ROSIN OR A ROSIN
DERIVATIVE. ROSIN AND SOME OF ITS DERIVITIVES HAVE BEEN REPORTED TO CAUSE AN
ALLERGIC SKIN REACTION (SENSITIZATION) IN SUSCEPTIBLE INDIVIDUALS(SIGNS/SYMPS
OVEREXP)
First Aid: EYES: COOL BURNS WITH PLENTY OF LOW-PRESSURE WATER. GET MEDICAL
ATTENTION IMMEDIATELY. SKIN: IMMEDIATELY COOL BURN AREA WITH COLD WATER AND
COLD PACKS FOR AT LEAST 15 MINUTES. DO NOT PUT ICE DIRECTLY ON THE SKIN. DO
NOT ATTEMPT TO REMOVE SOLIDIFIED RESIN FROM THE SKIN AS SEVERE TISSUE DAMAGE
MAY RESULT. GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. TREAT
ANY IRRITATION SYMPTOMATICALLY. CALL A PHYSICIAN. NOTE TO PHYSICIAN:
MATERIAL SHOULD NOT BE FORCIBLY PULLED FROM THE SKIN. MINERAL OIL MAY BE USED
TO LOOSEN AND SOFTEN THE MATERIAL.
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Handling and Disposal
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Spill Release Procedures: IF MATERIAL IS NOT CONTAMINATED, SCOOP INTO CLEAN
CONTAINERS FOR USE. IF CONTAMINATED, SCOOP INTO CONTAINERS FOR DISPOSAL.
Waste Disposal Methods: INCINERATION OF WASTE MATERIAL IN A PERMITTED FACILITY
IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS IS THE RECOMMENDED
DISPOSAL METHOD. LANDFILLING IN A LICENSED FACILITY IS A SUITABLE ALTER
NATIVE.
Handling And Storage Precautions: IF ALLOWED TO SOLIDIFY TO SOLID OR FLAKE
FORM, THIS PRODUCT CAN EXHIBIT THE CHARACTERISTICS OF A SOLID OR FLAKE RESIN,
AND MAY FORM FLAMMABLE DUST-AIR MIXTURES. WATER CONTACT WITH HOT MOLTEN RESIN
MAY RESULT IN FOAMING OR SPATTERING WHICH CAN CAUSE BURNS UPON SKIN OR EYE
CONTACT.
Other Precautions: PROTECTIVE MEASURES DURING REPAIR AND MAINTENANCE: ELIMINATE
SOURCES OF IGNITION. COMPLETELY ISOLATE AND THOROUGHLY CLEAN ALL EQUIPMENT,
PIPING OR VESSELS BEFORE BEGINNING MAINTENANCE OR REPAIRS. KEEP AREA CLEAN.
PRODUCT WILL BURN.
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point: =203.C, 397.4F
Autoignition Temp Text: N/D
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: WATER SPRAY, DRY CHEMICAL, FOAM, CARBON DIOXIDE, OR HALON.
Fire Fighting Procedures: USE SELF-CONTAINED BREATHING APPARATUS. APPLY WATER
TO MOLTEN RESIN FIRES FROM A SAFE, PROTECTED LOCATION TO AVOID BODY CONTACT
WITH HOT RESIN.
Unusual Fire/Explosion Hazard: MAY FORM FLAMMABLE DUST-AIR MIXTURES. CAUTION!
PRODUCT MAY BURN IF IGNITED.
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Control Measures
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Respiratory Protection: APPROPRIATE RESPIRATORY PROTECTION REQUIRED WHEN
EXPOSURE TO AIRBORNE CONTAMINENT IS LIKELY TO EXCEED ACCEPTABLE LIMITS.
RESPIRATORS FHOULD BE SELECTED AND USED IN ACCORDANCE WITH OSHA, SUBPART I
(29 CFR 1910.134) AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation: ADEQUATE VENTILATION SHOULD BE PROVIDED TO KEEP DUST OR VAPOR
CONCENTRATIONS BELOW ACCEPTABLE EXPOSURE LIMITS. (SUP DAT)
Protective Gloves: LONG-CUFF LINED GLOVES.
Eye Protection: FACE SHIELD, SAFETY GLASSES (ANSI APPROVED - FP N).
Other Protective Equipment: HARD HAT. LONG-SLEEVE PROTECTIVE SHIRT, LONG PANTS
AND WORK SHOES. LINED RAIN SUIT WITH PROTECTIVE HOOD OR SHOULDER SHROUD OR
FULL ALUMINIZED OR THERMAL SUIT WITH HOOD. PROTECTIVE CLOTHING (SUP DATA)
Work Hygienic Practices: AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID
BREATHING DUST OR VAPOR. WASH THOROUGHLY AFTER HANDLING, AND BEFORE EATING,
DRINKING OR SMOKING.
Supplemental Safety and Health: VENTILATION (CONT): DISCHARGE FROM THE
VENTILATION SYSTEM SHOULD COMPLY W/ APPLICABLE AIR POLLUTION REGS. OTHER
PROT EQUIP (CONT): SHOULD BE MADE OF SIX-OUNCE (6 OZ) OR GREATER FABRIC;
POLYESTER SHOU LD BE AVOIDED. EYEWASH FOUNTAINS & SAFETY SHOWERS
(MEETING ANSI DESIGN CRITERIA - FP N) SHOULD BE EASILY ACCESSIBLE.
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Physical/Chemical Properties
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M.P/F.P Text: SOFTENING POINT 65C, 149F
Vapor Pres: NEGLIGIBLE
Spec Gravity: 1.05
Evaporation Rate & Reference: SLOWER THAN BUTYL ACETATE
Solubility in Water: NEGLIGIBLE
Appearance and Odor: VERY PALE, VISCOUS LIQUID AT 150-210C (302-410F); LOW ODOR
Percent Volatiles by Volume: NEGLIGIBLE
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: STABLE.
Materials To Avoid: NONE.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE AND SMOKE.
DEPENDING ON THE CONDITIONS, SOME ALIPHATIC ALDEHYDES AND CARBOXYLIC ACIDS
MAY ALSO BE FORMED.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: AS HERCULES INTERPRETS THE U.S. OCCUPATIONAL SAFETY
AND HEALTH ACT AND REGULATIONS, INCLUDING THE HAZARD COMMUNICATION STANDARD
29 CFR 1910.1200 DATED AUGUST 24, 1987, THIS PRODUCT SHOULD NOT BE CONSI
DERED A HEALTH HAZARD. IF THIS PRODUCT IS USED IN A MANNER THAT COULD
GENERATE PARTICULATES (DUST), HERCULES RECOMMENDS THAT THE DUST BE TREATED AS
A NUISANCE PARTICULATE (PARTICLES NOT OTHERWISE CLA SSIFIED) AS DEFINED BY
THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH) OR
(PARTICULATES NOT OTHERWISE REGULATED) AS DEFINED BY OSHA. RECOMMENDED
AIRBORNE LEVELS (1992-1993): PAR TICULATES NOT OTHERWISE (ECOLOGICAL)
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Ecological Information
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Ecological: TOX INFO (CONT): CLASSIFIED/REGULATED: OSHA TWA: 15 MG/MS TOTAL, 5
MG/M3 RESPIRABLE FRACTION. TLV-TWA: 10 MG/M3. IF THIS PRODUCT IS HEATED TO
TEMPERATURES SUFFICIENT TO PRODUCE SMOKE OR FUMES, THE TL V-TWA OF 0.1 MG/M3
(AS FORMALDEHYDE), FOR ROSIN CORE SOLDER PYROLYSIS SHOULD BE OBSERVED.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: THE FOLLOWING ENVIRONMENTAL AND REGULATORY DATA ARE
PROVIDED TO ASSIST USERS OF THIS PRODUCT IN DEFINING THEIR REGULATORY
ENVIRONMENTAL COMPLIANCE OBLIGATIONS: PRODUCT COMPOSITION: PRODUCT (P) OR
COMP ONENT NO.: P; TRADE NAME OR CHEMICAL COMPONENT: STAYBELITE PARTIALLY
HYDROGENATED ROSIN; CASRN: 65997-06-0; WT. PERCENT: 100. SARA TITLE III:
COMPONENT NO.: P; SEC. 304 EHS RG (LBS): N/A, THIS CHEMIC AL IS NOT AN EHS.
THEREFORE, THERE IS NO REPORTABLE QUANTITY (RQ); SEC. 302 EHS TPQ (LBS): N/A,
THIS CHEMICAL IS NOT AN EHS. THEREFORE THERE IS NO THRESHOLD PLANNING
QUANTITY (TPQ); SEC. 311/312 HAZAR D CATEGORY, (STATE REGS)
Federal Regulatory Information: CERCLA (40 CFR 302.4 HAZARDOUS SUBSTANCE &
REPORTABLE QUANTITIES): THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS
SUBSTANCES LISTED IN 40 CFR 302.4. RCRA INFORMATION: THIS PRODUCT IS NOT
LISTED IN FEDER AL HAZARDOUS WASTE REGULATION 40 CFR 261.33, PARAGRAPH (E) OR
(F) - I.E., CHEMICAL PRODUCTS THAT ARE CONSIDERED HAZARDOUS IF THEY BECOME
WASTES. IT DOES NOT EXHIBIT ANY OF THE HAZARDOUS CHARACTERISTIC S LISTED IN
40 CFR 261, SUBPART C. STATE OR LOCAL HAZARDOUS REGULATIONS MAY APPLY IF THEY
ARE DIFFER ENT FROM THE FEDERAL REGULATION. TSCA STATUS: THE COMPONENTS OF
THIS PRODUCT AR INCLUDED IN THE EPA TSCA CHEMICAL SUBSTANCE INVENTORY.
State Regulatory Information: SARA (CONT): 40 CFR 370 HAZARDOUS CHEMICAL
REPORTING REQUIREMENTS "HAZARD CATEGORIES": NHH - HOT A HEALTH HAZARD, HC-3
(DUST) - FIRE HAZARD. SEC.313 TOXIC CHEMICAL (YES, NO): NO - THIS COMPONENT
IS N OT SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF
THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372
TOXIC CHEMICAL REPORTING REQUIREMENTS.
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Other Information
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Other Information: RATING: HEALTH HAZARD: 0 MINIMAL, FLAMMABILITY HAZARD: 1
SLIGHT, REACTIVITY HAZARD: 0 MINIMAL. "STAYBELITE" IS A REGISTERED TRADEMARK
OF HERCULES INCORPORATED. DOC. NO. 2308S. SUPERCEDES MSDS #: 853 2155
0100-03.
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HAZCOM Label
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MSDS NAME: STAYBELITE PARTIALLY HYDROGENATED ROSIN, MOLTEN
Company: HERCULES INCORPORATED
Street: HERCULES PLAZA
City: WILMINGTON DE
Zipcode: 19894
Health Emergency Phone: 302-594-5000
Label Required IND: Y
Date Of Label Review: 03/27/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: DANGER! MOLTEN RESIN. CAUSES SEVERE BURNS ON CONTACT.
ACUTE: EYES: BURNS CAN CAUSE IRREVERSIBLE EYE INJURY AND BLINDNESS. SMOKE OR
FUMES FROM ROSIN PRODUCTS MAY CAUSE EYE IRRITATION WITH REDNESS, TEA RING AND
DISCOMFORT. SKIN: SERIOUS BURNS WILL RESULT FROM CONTACT WITH MOLTEN
PRODUCT. INHALATION: BREATHING SMOKE OR FUMES FROM MOLTEN ROSIN PRODUCTS MAY
PRODUCE RESPIRATORY IRRITATION, BREATHING D ISCOMFORT, COUGHING AND SORE
THROAT. INGESTION: NONE KNOWN. CHRONIC: REPEATED OR PROLONGED SKIN CONTACT
MAY CAUSE AN ALLERGIC SKIN REACTION (SENSITIZATION). REPEATED EXPOSURE TO
SMOKE OR FUMES MAY LE AD TO RESPIRATORY SENSITIZATION (ASTHMA).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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