UNION CARBIDE CORP LINDE DIV -- ISOPROPANOL ANHYDROUS, USP
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Material Safety Data Sheet
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MSDS Num: CKDRF
MSDS NAME: ISOPROPANOL ANHYDROUS, USP
Responsible Party
Name: UNION CARBIDE CORP LINDE DIV
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Info Phone: 800-822-4357; 304-744-3487
Emergency Phone Number: 800-UCC-HELP/304-744-3487
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Ingredients
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Cas: 67-63-0
RTECS #: NT8050000
Name: ISOPROPYL ALCOHOL (SARA 313)
Percent by Wt: 100.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM/500STEL;9596
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Health Hazards Data
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LD50 LC50 Mixture: PERORAL RAT LD50: 6.48 ML/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION: HIGH CONCENTRATIONS OF VAPOR MAY CAUSE CENTRAL
NERVOUS SYSTEM. VAPOR CAUSES IRRITATION OF THE RESPIRATORY TRACT, WITH
COUGHING & CHEST DISCOMFORT. EYE CONTACT: CAUSES IRRITATION. CORNEAL I
NJURY MAY OCCUR. SKIN CONTACT: MAY CAUSE MINOR IRRITATION. PROLONGED OR
REPEATED CONTACT MAY CAUSE DEFATTING & DRYING OF THE SKIN. SKIN
ABSORPTION: EXPOSURE TO SMALL QUANTITIES IS NOT EXPECTED TO CAUS E ADVERSE
EFFECTS. WIDESPREAD OR PROLONGED EXPOSURE EXPOSURE MAY RESULT IN ABSORPTION
OF HARMFUL AMOUNTS OF MATERIAL. SWALLOWING: SLIGHTLY TOXIC. CHRONIC:
PROLONGED OR REPEATED OVEREXPOSURE MAY CAUSE DEFATTING OF THE SKIN.
Explanation Of Carcinogenicity: NO EVIDENCE SUGGESTIVE OF CARCINOGENIC ACTIVITY
WAS NOTED IN CHRONIC VAPOR INHALATION STUDIES WITH ISOPROPANOL IN RATS AND
MICE.
Signs And Symptions Of Overexposure: INHALATION: WEAKNESS, DROWSINESS, LOSS OF
CONSCIOUSNESS, COUGHING & CHEST DISCOMFORT. EYES: STINGING, DISCOMFORT,
PAIN. SKIN: ITCHING, REDNESS. SKIN ABSORPTION: SAME AS SWALLOWING.
SWALLOWING: DIZZINE SS, FAINTNESS, DROWSINESS, DECREASE AWARENESS &
RESPONSIVENESS, LACK OF COORDINATION, ABDOMINAL, NAUSEA, VOMITING &
DIARRHEA.
Medical Cond Aggravated By Exposure: SKIN CONTACT MAY AGGRAVATE AN EXISTING
DERMATITIS.
First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT
BREATHING. IF BREATHING IS DIFFICULT, OXYGEN MAY BE BE GIVEN BY QUALIFIED
PERSONNEL. OBTAIN MEDICAL ATTENTION. EYE CONTACT: IMMEDIAT ELY FLUSH WITH
WATER & CONTINUE WASHING FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
WORN. OBTAIN MEDICAL ATTENTION. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP & WATER. IF IRRITATION PERSISTS OR IF CONTACT PROLONGED,
OBTAIN MEDICAL ATTENTION. SWALLOWED: IF CONSCIOUS, GIVE 2 GLASSES WATER.
INDUCE VOMITING. THIS SHOULD DONE ONLY BY MEDICAL PERSONNEL. OBTAIN MEDICAL
ATTENTION.
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Handling and Disposal
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Spill Release Procedures: EXTINGUISH & DO NOT TURON ON IGNITION SOURCES
UNTIL FIRE HAZARD FREE. SMALL SPILLS CAN BE FLUSHED WITH LARGE AMOUNTS OF
WATER. LARGER SPILLS SHOULD BE COLLECTED FOR DISPOSAL. PERSONAL PRECAUTIONS:
AVO ID CONTACT WITH EYES. WEAR SUITABLE PROTECTIVE CLOTHING.
Waste Disposal Methods: INCINERATE IN A FURNACE WHERE PERMITTED UNDER FEDERAL,
STATE AND LOCAL REGULATIONS. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, PROVINCIAL AND LOCAL ENVIRONMENTAL REGULATIONS. EMPTY CONT
AINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT
FACILITY. DISPOSAL MET HOD IS FOR PRODUCT AS SOLD.
Handling And Storage Precautions: HANDLING: KEEP AWAY FROM IGNITION SOURCES AND
HEAT. AVOID CONTACT WITH EYES. KEEP CONTAINER CLOSED. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR INDUSTRIAL USE ONLY.
STORAGE: NO INFORMATION CURRENTLY AVAILABLE.
Other Precautions: VAPOR MAY SETTLE IN LOW OR CONFINED AREAS, OR TRAVEL A LONG
DISTANCE TO AN IGNITION SOURCE AND FLASH BACK EXPLOSIVELY.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =11.7C, 53.F
Lower Limits: 2.0
Upper Limits: 12.7
Extinguishing Media: APPLY ALCOHOL-TYPE OR ALL PURPOSE-TYPE FOAM BY
MANUFACTURER'S RECOMMENDED TECHNIQUES FOR LARGER FIRES. USE CARBON DIOXIDE OR
DRY CHEMICAL MEDIA FOR SMALL FIRES.
Fire Fighting Procedures: USE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS
AND PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND
STRUCTURES. USE WATER SPRAY TO DISPERSE VAPRS, RE-IGNITION IS POSSIBL E.
Unusual Fire/Explosion Hazard: VAPORVAPORS FROM THIS MATERIAL MAY SETTLE IN LOW
OR CONFINED AREASOR TRAVEL A LONG DISTANCE TO AN IGNITION SOURCE AND FLASH
BACK EXPLOSIVELY. STATIC IGNITION HAZARD CAN RESULT FROM HANDLING AND USE. T
HIS MATERIAL MAY PRODUCE A FLOATING HAZARD. FLAME MAY BE INVISIBLE. APPROACH
FIRE WITH CAUTION.
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Control Measures
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Respiratory Protection: USE SELF-CONTAINED BREATHING APPARATUS IN HIGH VAPOR
CONCENTRATIONS.
Ventilation: MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves: PLASTIC, RUBBER.
Eye Protection: MONOGOGGLES.
Other Protective Equipment: EYE BATH, SAFETY SHOWER.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: VAPOR FORMS FROM THIS PRODUCT AND MAY TRAVEL OR
BE MOVED BY AIR CURRENTS AND IGNITED BY PILOT LIGHTS, OTHER FLAMES, SMOKING,
SPARKS, HEATERS, ELECTRICAL EQUIPMENT, STATIC DISCHARGES OR OTHER IGNITION
SOURCES AT LOCATIONS DISTANT FROM HANDLING POINT AND MAY FLASHBACK
EXPLOSIVELY. HK KULHMAN PART NUMBER: 140252.
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Physical/Chemical Properties
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HCC: F2
NRC/State LIC No: N.R
Boiling Point: =82.2C, 180.F
Melt/Freeze Pt: =-88.3C, -127.F
Decomp Text: UNKNOWN
Vapor Pres: 33 @ 68F
Vapor Density: 2.1
Spec Gravity: 0.787
VOC Grams/Liter: 785
Evaporation Rate & Reference: 2.9 (BUTYL ACETATE=1)
Solubility in Water: COMPLETE (100%)
Appearance and Odor: CLEAR, COLORLESS LIQUID, SLIGHT ETHANOL/ACETONE-LIKE ODOR
Percent Volatiles by Volume: 100 (WT)
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: STRONG OXIDIZING AGENTS, HALOGENS, STRONG INORGANIC ACIDS,
ALDEHYDES, HALOGEN COMPOUNDS.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE. CARBON
MONOOXIDE IS HIGHLY TOXIC IF INHALKED. CARBON DIOXIDE CAN ACT AS AN ASHYXIANT
IN SUFFICIENT CONCENTRATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: ACUTE TOCIXICITY: PERORAL RAT LD50: 6.48 ML/KG.
MAJOR SIGNS: UNSTEADY GAIT, PROSTRATION, HEAVY BREATHING. GROSS PATHOLOGY:
LUNGS & ABDOMINAL VISCERA DISCOLORED. PERCUTANEOUS RABBIT LD50 24 HR:
OCCLUDE D 8.0 ML/KG. GROSS PATHOLOGY: LUNGS, LIVER, STOMACH DISCOLORED.
INHALATION: STATIC GENERATION OF VAPOR, EXPOSURE TIME-2 HR: RABBIT: ROOM
TEMPERATURE, KILL RATE-4/6, MAJOR SIGNS-LACRYMATION, LOSS OF CO ORDINATION,
PROSTRATION. GROSS PATHOLOGY-LUNGS DISCOLORED. INHALATION: DYNAMIC GENERATION
OF VAPOR EXPOSRE TIME 4 HR, 1200 PPM RABBIT: KILL ARTE: 0/12. MAJOR SIGNS:
PROSTRATION. GROSS PATHOLOGY: LUNGS KIDNEY & LIVER DISCOLORED.
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Ecological Information
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Ecological: ENVIRONMENTAL FATE: BOD (%OXYGEN CONSUMPTION): DAY 5-28%; DAY
10-77%; DAY 15-NO DATA; DAY 20-78%; DAY 30-NO DATA. ECOTOXICITY: ECOTOXICITY
FOR MICRO-ORGANISMS: BACTERIA/NA IC50 5000 MG/L. ECOTOXICITY TO AQUATIC
INVERTABRATES: DAPHNIA LC50 48 H 7550 MG/L. ECOTOXICITY TO FISH: FATHEAD
MINNOW LC50 96 HR 8300 MG/L. FURTHER INFORMATION: THOD (MEASURED): 2.3 MG/MG.
THOD (CALCULATED): 2.4 MG/MG. OCTANOL/ WATER PARTITION COEFFICIENT -
MEASURED: 0.14.
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MSDS Transport Information
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Transport Information: US DOT NON BULK: PROPER SHIPPING NAME: ISOPROPANOL. ID
NUMBER: UN1219. HAZARD CLASS: 3. PACKING GROUP: PGII. BULK: PROPER SHIPPING
NAME: ISOPROPANOL. ID NUMBER: UN1219. HAZARD CLASS: 3. PACKING GROUP : PGII.
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Regulatory Information
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Sara Title III Information: THE FOLLOWING COMPONENTS OF THIS PRODUCT ARE LISTED
AS EXTREMELY HAZARDOUS SUBSTANCES IN 40 CFR 355 AND ARE PRESENT AT LEVELS
WHICH COULD REQUIRE REPORTING AND EMERGENCY PLANNING. NONE. THE FOLLOWING
COMPONENTS OF THIS PRODUCT ARE LISTED AS TOXIC CHEMICALS IN 40 CFR 372.65 AND
ARE PRESENT AT LEVELS WHICH COULD REQUIRE REPORTING AND CUSTOMER NOTIFICATION
UNDER SECTION 313 AND 40 CFR 372: NONE. SUPE RFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 (SARA) TITLE III SECTIONS 311/312: DELAYED
HAZARD: YES; FIRE-YES; IMMEDIATE-YES; REACTIVE-NO; SUDDEN RELEASE OF
PRESSURE-NO.
Federal Regulatory Information: TOXIC SUBSTANCES CONTROLS ACT (TSCA): ALL
COMPONENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY OR ARE EXEMPT FROM TSCA
INVENTORY REQUIREMENTS. CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE,
COMPENSATIO N AND LIABILITY ACT OF 1980 SECTION 103): THE FOLLOWING
COMPONENTS OF THIS PRODUCT ARE SPECIFICALLY LISTED AS HAZARDOUS SUBSTANCES IN
40 302.4 (UNLISTED HAZARDOUS SUBSTANCES ARE NOT IDENTIFIED) AND AR E PRESENT
AT LEVELS WHICH COULD REQUIRE REPORTING: NONE.
State Regulatory Information: PENNSYLVANIA RIGHT-TO-KNOW (RTK): THIS PRODUCT IS
SUBJECT TO THE WORKER & COMMUNITY RTK ACT. THE FOLLOWING COMPONENTS OF
THIS PRODUCT ARE AT LEVELS WHICH COULD REQUIRE IDENTIFICATION IN THE MSDS:
ISOP ROPANOL, CAS# 67-63-0, 100%. MASSACHUSETTS (HAZARDOUS SUBSTANCES
DISCLOSURE BY EMPLOYERS): THE FOLLWING COMPONENTS OF THIS PRODUCT APPEAR ON
THE MASSACHUSETTS SUBSTANCE LIST AND ARE PRESENT AT LEVELS WHICH COULD
REQUIRE IDENTIFICATION IN THE MSDS: ISOPROPANOL, CAS# 67-63-0, 100%.
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Other Information
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Other Information: CALIFORNIA PROPOSITION 65 (SAFE DRINKING AND TOXIC
ENFORCEMENT ACT OF 1986): THIS PRODUCT CONTAINS NO LISTED SUBSTANCES KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODU CTIVE
HARM AT LEVELS WHICH WOULD REQUIRE A WARNING UNDER THE STATUTE.CALIFORNIA
SCAQMD RULE 443.1: VOC: 785 G/L; VAPOR PRESSURE: 33 MM HG @ 20 C.
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Transportation Information
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Trans ID NO: 151883
MSDS NAME: ISOPROPANOL ANHYDROUS, USP
MSDS Prepared Date: 08/10/1998
Review Date: 03/11/2000
Net Unit Weight: UNKNOWN
Multiple KIT Number: 0
Unit Of Issue: CY
Type Of Container: CYLINDER
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Detail DOT Information
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DOT PSN Code: HWY
DOT Proper Shipping Name: ISOPROPANOL OR ISOPROPYL ALCOHOL
Hazard Class: 3
UN ID Num: UN1219
DOT Packaging Group: II
Label: FLAMMABLE LIQUID
Special Provision: T1
Packaging Exception: 150
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
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Detail IMO Information
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IMO PSN Code: ITA
IMO Proper Shipping Name: ISOPROPANOL
IMDG Page Number: 3244
UN Number: 1219
UN Hazard Class: 3.2
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 3-06
MED First Aid Guide NUM: 305
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Detail IATA Information
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IATA PSN Code: ONH
IATA UN ID Num: 1219
IATA Proper Shipping Name: ISOPROPANOL
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: II
Packing Note Passenger: 305
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 307
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Detail AFI Information
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AFI PSN Code: ONH
AFI Proper Shipping Name: ISOPROPANOL
AFI Hazard Class: 3
AFI UN ID NUM: UN1219
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A7.3
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HAZCOM Label
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MSDS NAME: ISOPROPANOL ANHYDROUS, USP
Company: UNION CARBIDE CORP LINDE DIV
Street: 39 OLD RIDGEBURY RD
City: DANBURY CT
Zipcode: 06817-0001
Health Emergency Phone: 800-UCC-HELP/304-744-3487
Label Required IND: Y
Date Of Label Review: 03/11/2000
Status Code: A
Year Procured: 1999
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: INHALATION: HIGH CONCENTRATIONS OF VAPOR MAY CAUSE
CENTRAL NERVOUS SYSTEM. VAPOR CAUSES IRRITATION OF THE RESPIRATORY TRACT,
WITH COUGHING & CHEST DISCOMFORT. EYE CONTACT: CAUSES IRRITATION. CORNEAL
I NJURY MAY OCCUR. SKIN CONTACT: MAY CAUSEMINOR IRRITATION. PROLONGED OR
REPEATED CONTACT MAY CAUSE DEFATTING & DRYING OF THE SKIN. SKIN
ABSORPTION: WIDESPREAD OR PROLONGED EXPOSURE EXPOSURE MAY RESULT IN
ABSORPTION OF HARMFUL AMOUNTS OF MATERIAL. SWALLOWING: SLIGHTLY TOXIC.
CHRONIC: PROLONGED OR REPEATED OVEREXPOSURE MAY CAUSE DEFATTING OF THE SKIN.
TARGET ORGANS: NO DATA PROVIDED BY RESPONSIBLE P ARTY.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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