UNIMARK OIL LLC -- GARD ANTI RUST SAE 30
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Material Safety Data Sheet
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NIIN: 00-111-0209
MSDS Num: CLBRY
MSDS NAME: GARD ANTI RUST SAE 30
Responsible Party
Name: UNIMARK OIL CO LLC
Address: 2727 ROE LANE
City: KANSAS CITY KS 66103-1543
Info Phone: 913-236-5000 FAX/913-432-8309
Emergency Phone Number: 800-451-8346
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Item Description Information
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Item Manager: S9G
Item Name: LUBRICATING OIL,ENGINE
Specification Number: MIL-L-21260
Type/Grade/Class: 11 TYPE,30 GRADE
Unit of Issue: CN
Quantitative Expression: 00000000005GL
UI Container Qty: 1
Type of Container: CAN
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: ORAL TOXICITY:NOT DETERMINED.
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE CONTACT: CAN CAUSE MILD IRRITATION. SKIN CONTACT: MAY
CAUSE IRRITATION. PROLONGED OR REPEATED CONTACT MAY RESULT IN DERMATITIS.
INHALATION: OVEREXPOSURE OF HOT MATERIAL MAY CAUSE NONSPECIFIC DISCO MFORT.
INGESTION: DO NOT INGEST. DUE TO CONCENTRATION OF OIL (70-100%) INGESTION IS
EXPECTED TO BE RELATIVELY NON-TOXIC UNLESS LUNG ASPIRATION OCCURS WHICH MAY
LEAD TO CHEMICAL PNEUMONITIS; CHARACTERI ZED BY PULMONARY EDEMA AND
HEMORRHAGE AND MAY BE FATAL.GASTROINTESTINAL DISCOMFORT MAY DEVELOP, FOLLOWED
BY VOMITING WITH A FURTHER RISK OF ASPIRATION.. THIS PRODUCT HAS LAXITIVE
PROPERTIES AND MAY RE SULT IN ABDOMINAL CRAMPS AND DIARRHEA.
Explanation Of Carcinogenicity: CARCINOGENICITY: NOT DETERMINED. NONE OF THE
OILS IN THIS PRODUCT REQUIRE A CANCER WARNING UNDER OSHA (29 CFR 1910.1200).
THESE OILS HAVE NOT BEEN LISTED IN NATIONAL TOXICOLOGY PROGRAM (NTP) ANNUAL
RE PORT NOR CLASSIFIED BY IARC AS: CARCINOGENIC TO HUMANS (GROUP 1), PROBABLY
CARCINOGENIC TO HUMANS (GROUP 2A), OR POSSIBLY CARCINOGENIC TO HUMANS (GROUP
2B).
Signs And Symptions Of Overexposure: EYE CONTACT; MILD IRRITATION, DISCOMFORT,
TEARING, BLURRED VISION. SKIN CONTACT: IRRITATION, DERMITITIS, DRYNESS,
CHAPPING, REDDENING. INHALATION: NAUSEA, HEADACHE, WEAKNESS. INGESTION:
RELATIVELY NON -TOXIC. ASPIRATION: MAY LEAD TO CHEMICAL PNEUMONITIS,
PULMONARY EDEMA, HEMORRHAGE, MAY BE FATAL; SIGNS OF LUNG INVOLVMENT INCLUDE
INCREASED RESPIRATORY RATE, INCREASED HEART RATE, BLUISH DICOLORATION OF
SKIN, COUGHING, CHOKING, GAGGING. GASTROINTESTINAL DISCOMFORT FOLLOWED BY
VOMITING. PRODUCT HAS LAXITIVE PROPERTIES AND MAY RESULT IN ABDOMINAL CRAMPS
AND DIARRHEA.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER. CONTINUE FLUSHING
UNTIL IRRITATION SUBSIDES. IF IRRITATION PERSISTS CALL DOCTOR. IF MATERIAL IS
HOT TREAT FOR THERMAL BURNS; TAKE TO HOSPITAL. SKIN: REM OVE CONTAMIATED
CLOTHING. WASH EXPOSED SKIN WITH SOAP AND WATER. IF REDNESS OR IRRITATION
OCCURS GET MEDICAL ATTENTION. IF MATERIAL IS HOT SUBMERGE EXPOSED AREA IN
COLD WATER. IF SEVERELY BURNED, TAKE TO HOSPITAL. INHALATION: MOVE TO FRESH
AIR. IF DIFFICULT BREATHING, GIVE OXYGEN. IF BREATHING STOPPED, GIVE
ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. (CONTD. SEE "OTHER INFORMATION")
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Handling and Disposal
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Spill Release Procedures: TURN OFF IGNITION SOURCES. VENTILATE. PERSONNEL
WEARING PROTECTIVE EQUIPMENT SHOULD CONTAIN SPILL WITH INERT MATERIALS BY
FORMING DIKES THAT PREVENTS ENTERING SEWERS AND WATERWAYS. PICK UP LARGE
SPILL WITH EXPLOSION-PROOF, NON-SPARKING VACUUM PUMPS, SHOVELS, BUCKETS AND
DEPOSIT IN DISPOSAL CONTAINERS. REMOVE WATER SPILLS BY SKIMMING SURFACE OR
WITH ADSORBENTS. NOTIFY AUTHORITIES OF LARGE SPILLS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: PLACE USED, CONTAMINATED, OR EXCESS MATERIAL INTO
DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH LOCAL AND
STATE REGULATIONS. CONTACT LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR AP
PROFED DISPOSAL . MOST USED OIL IS RECLAIMED OR INCINERATED. UNDER RCRA IT IS
THE RESPONSIBILITY OF THE USER TO DETERMINE (CONTD. SEE "ECOLOGICAL")
Handling And Storage Precautions: KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO
NOT TRANSFER TO UNMARKED CONTAINERS. FIRE EXTINGUISHERS SHOULD BE KEPT
READILY AVAILABLE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE WHICH MAY EXHIBIT
HAZARDS O F MATERIAL, DO NOT PRESSURIZE, CUT, GLAZE, WELD, OR USE FOR ANY
OTHER PURPOSE.
Other Precautions: RETURN DRUMS TO RECLAMATION CENTERS FOR PROPER CLEANING AND
REUSE. STORE CONTAINERS AWAY FROM HEAT, SPARKS, OPEN FLAMES, OR OXIDIZING
MATERIALS.
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point: =220.C, 428.F
Autoignition Temp Text: N/DETR
Lower Limits: NOT DETERMIN
Upper Limits: NOT DETERMIN
Extinguishing Media: USE DRY CHEMICAL, FOAM, WATER FOG, OR CARBON DIOXIDE.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE BUT CAN BE USED TO COOL
CONTAINERS EXPOSED TO HEAT OR FLAME. CAUTION SHOULD BE EXERCISED WHEN USING
WATER OR FOAM AS FROTHING MAY OCCUR, ESPECIALLY IF SPRAYED INTO HOT, BURNI NG
LIQUID.
Unusual Fire/Explosion Hazard: DENSE SMOKE MAY BE GENERATED WHILE BURNING.
TOXIC FUMES/GAS/VAPOR MAY EVOLVE ON BURNING. HEAVY FLAMMABLE VAPORS MAY
SETTLE ALONG GROUND LEVEL AND LOW SPOTS TO CREATE INVISIBLE FIRE HAZARD.
VAPORS MAY EXTEND TO SOURCES OF IGNITION AND FLASH BACK. CARE SHOULD ALWAYS
BE EXERCISED IN DUST/MIST AREAS.
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Control Measures
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Respiratory Protection: NONE REQURIED IF AIRBORNE CONCENTRATIONS ARE MAINTAINED
BELOW TLV. OHTERWISE RESPIRATORY PROTECTION PROGRAM MEETING OSHA 1910.134
AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED. IF MISTING OCCURS WEAR
MSHA/NIOSH APPROVED (OR EQUIVALENT) HALF-MASK FORM DUST/MIST AIR PURIFYING
RESPIRATOR.
Ventilation: USE ADEQUATE VENTILATION WHEN WORKING WITH MATERIAL IN ENCLOSED
AREA. MECHANICAL METHODS SUCH AS FUME HOODS OR AREA FANS MAY BE USED (CONTD.
SEE "SUPPLEMENTAL")
Protective Gloves: NEOPRENE, NITRILE RUBBER (IMPERVIOUS).
Eye Protection: ALWAYS RECOMMENDED;SAFETY GLASSES WITH SIDE SHIELDS OR VENTED
SPLSH GOGGLES
Other Protective Equipment: APRON, OVERBOOTS OF IMPERVIOUS MATERIALS (NEOPRENE
OR NITRILE RUBBER) RECOMMENDED. USE INSULATED EQUIPMENT FOR HANDLING HOT
MATERIAL. PROVIDE EYEWASH STATIONS AND SHOWERS IN WORK OR STORAGE AREAS.
Work Hygienic Practices: CONSUMPTION OF FOOD AND DRINK SHOULD BE AVOIDED IN
WORK AREAS WHERE PRODUCT IS PRESENT. ALWAYS WASH HANDS AND FACE WITH SOAP AND
WATER BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING.
Supplemental Safety and Health: (CONTD. FROM "VENTILATION") TO REDUCE LOCALIZED
VAPOR/MIST AREAS. IF VAPOR OR MIST IS GENERATED WHEN THE MATERIAL IS HEATED
OR HANDLED, ADEQUATE VENTILATION IN ACCORDANCE WITH GOOD ENGINEERING PRACTIC
E MUST BE PROVIDED TO MAINTAIN CONCENTRATIONS BELOW THE SPECIFIED EXPOSURE.
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Physical/Chemical Properties
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HCC: V6
Boiling Point: >260.C, 500.F
B.P. Text: ESTMATED
Melt/Freeze Pt: =-17.6C, 0.F
M.P/F.P Text: POUR POINT
Vapor Pres: NEGLIGIBLE AT 25C, 1 ATM.
Vapor Density: >1@STP
Spec Gravity: 0.89 @15.6C (7.45 LB/GAL)
Viscosity: 11.50CST@100C
Evaporation Rate & Reference: NEGLIGIBLE, (N-BUAC =1)
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: DARK BROWN, CLEAR FLUIID, MILD PETROLEUM HYDROCARBON ODOR.
Percent Volatiles by Volume: NEGLIGIBLE
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: MATERIAL IS STABLE AT ROOM TEMPERATURE AND
PRESSURE. AVOID HIGH TEMPERATURES AND PRODUCT CONTAMINATION.
Materials To Avoid: AVOID CONTACT WITH ACIDS AND OXIDIZING MATERIALS.
Hazardous Decomposition Products: SMOKE, CARBON MONOXIDE, CARBON DIOXIDE, OTHER
ALDEHYDE OF INCOMPLETE COMBUSTION. OXIDES OF C, ZN, CA, P, S. HYDROGEN
SULFIDE, ALKYL MERCAPTANS AND OTHER SULFIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: ORAL, DERMAL TOXICITY : NOT DETERMINED. INHALATION:
ON RARE OCCASIONS, PROLONGED AND REPEATED EXPPOSURE TO OIL MIST POSES A RISK
OF PULMONARY DISEASE SUCH AS CHRONIC LUNG INFLAMMATION. THIS CONDITION IS
USUALLY ASYMPTOTIC AS A RESULT OF REPEATED SMALL ASPIRATIONS. SHORTNESS OF
BREATH AND COUGH ARE COMMON SYMPTOMS. DERMAL SENSITIZATION: PROLONGED OR
TRPEATED CONTSCT MAY MAKE SKIN MORE SENSITIVE TO OTHER SENSITIZERS. CHRONIC
TOXICITY, CARCINOGENICITY, REPRODUCTIVE TOXICITY, TERATOGENICITY: NOT
DETERMINED. MUTAGENICITY: PRODUCT CONTAINS ZINC ALKYL DITHIOPHOSPHATES (ZDP)
(CONTD. SEE "STATE REG.")
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Ecological Information
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Ecological: ENVIRONMENTAL TOXICITY: THIS MATERIAL MAY BE TOXIC TO AQUATIC
ORGANISM AND SHOULD BE BE KEPT OUT OF SEWAGE AND DRAINAGE SYSTEMS AND ALL
BODIES OF WATER. ENVIRONMENTAL FATE: NO DATA AVAILABLE. (CONTD. FROM "WASTE
DISPOSAL") AT TIME OF DISPOSAL WHETHER PORDUCT MEETS RCRA CRITERIA FOR
HAZARDOUS WASTE. WASTE MANGEMENT SHOULD BE IN COMPLIANCE WITH FEDERAL, STATE,
AND LOCAL LAWS.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: SECTION 302/304 EXTREMELY HAZARDOUS SUBSTANCES:
NONE. SECTION 311, 312 HAZARD CATEGORTIZATION: ACUTE (IMMEDIATE HEALTH
EFFECTS): YES; CHRONIC(DELAYED HEALTH EFFECTS): NO; FIRE (HAZARD): NO;
REACTIVITY (HAZARD): NO; PRESSURE (SUDDEN RELEASE): NO. SECTION 313 TOXIC
CHEMICALS: ZINC < 0.20%.
State Regulatory Information: (CONTD> FROM "TOXICOLOGICAL") SEVERAL ZDPS
HAVE BEEN REPORTED TO HAVE WEAK MUTAGENIC ACTIVITY IN CULTURED MAMMALIAN
CELLS BUT ONLY IN CONCENTRATIONS THAT WERE TOXIC TO THE TEST CELLS.
MANUFACTURER DO ES NOT BELIEVE THERE IS ANY MUTAGENIC RISK TO WORKERS EXPOSED
TO THIS PRODUCT'S CONCENTRATION LEVEL OF ZDP.
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Other Information
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Other Information: NFPA 704: HEALTH: 1(SLIGHT); FIRE: 1 (SLIGHT); REACTIVITY: 0
(MINIMAL); SPECIFIC HAZARD: NONE; PROTECTIVE INDEX: N/A. NPCA-: HEALTH: I
(SLIGHT); FIRE: 1 (SLIGHT); REACTIVITY: 0 (MINIMAL); SPECIFIC HAZARD: N/A;
PROTECTIVE INDEX: B. PRECAUTIONARY LABELS: WARNING! MAY CAUSE EYE IRRITATION;
MAY CAUSE SKIN IRRITATION; HOT VAPORS MAY CAUSE RESPIRATORY IRRITATION.
(CONTD. FROM "FIRST AID") GIVE TW O GLASSES OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IF VOMITING OCCURS, LOWER HEAD BELOW KNEES TO
AVOID ASPIRATION. SEEK MEDICAL ATTENTION.
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Transportation Information
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Trans ID NO: 156646
MSDS NAME: GARD ANTI RUST SAE 30
MSDS Prepared Date: 06/30/2000
Review Date: 04/16/2001
Net Unit Weight: 37.2 LBS
Multiple KIT Number: 0
Unit Of Issue: CN
Container QTY: 1
Type Of Container: CAN
Additional Data: TRANSPORTATION DATA PER MANUFACTURER'S MSDS.
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: GARD ANTI RUST SAE 30
Company: UNIMARK OIL CO LLC
Street: 2727 ROE LANE
City: KANSAS CITY KS
Zipcode: 66103-1543
Health Emergency Phone: 800-451-8346
Label Required IND: Y
Date Of Label Review: 04/16/2001
Status Code: A
Label Date: 04/16/2001
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: EYE CONTACT: CAN CAUSE MILD IRRITATION. SKIN CONTACT:
MAY CAUSE IRRITATION. PROLONGED OR REPEATED CONTACT MAY RESULT IN DERMATITIS.
INHALATION: OVEREXPOSURE OF HOT MATERIAL MAY CAUSE NONSPECIFIC DISCO MFORT.
INGESTION: DO NOT INGEST. DUE TOCONCENTRATION OF OIL (70-100%) INGESTION IS
EXPECTED TO BE RELATIVELY NON-TOXIC UNLESS LUNG ASPIRATION OCCURS WHICH MAY
LEAD TO CHEMICAL PNEUMONITIS; CHARACTERIZ ED BY PULMONARY EDEMA AND
HEMORRHAGE AND MAY BE FATAL.GASTROINTESTINAL DISCOMFORT MAY DEVELOP, FOLLOWED
BY VOMITING WITH A FURTHER RISK OF ASPIRATION.. THIS PRODUCT HAS LAXITIVE
PROPERTIES AND MAY RES ULT IN ABDOMINAL CRAMPS AND DIARRHEA.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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