UNITED TITANIUM, INC -- TITANIUM/TITANIUM ALLOY, TITANIUM CP, TITANIU
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CLPVB
MSDS NAME: TITANIUM/TITANIUM ALLOY, TITANIUM CP, TITANIUM 6A1-4V, ETC
Responsible Party
Name: UNITED TITANIUM, INC
Address: 3450 OLD AIRPORT ROAD
Box: 951
City: WOOSTER OH 44691
Info Phone: 216-264-2411
Emergency Phone Number: 216-264-2411
Resp. Party Other MSDS No.: FORM NO.43678
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: UNITED TITANIUM, INC
Address: 3450 OLD AIRPORT ROAD
Box: 951
City: WOOSTER OH 44691
Phone: 216-264-2411
=======================================================
Ingredients
=======================================================
Cas: 7440-32-6
RTECS #: XR1700000
Name: TITANIUM
% low Wt: 46.
% high Wt: 99.
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 7429-90-5
RTECS #: BD0330000
Name: ALUMINIUM (AL)
% low Wt: 0.
% high Wt: 7.
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 7440-47-3
RTECS #: GB4200000
Name: CHROMIUM (CR)
% low Wt: 0.
% high Wt: 11.
OSHA PEL: 1 MG/M3
ACGIH TLV: 0.5 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 1309-37-1
RTECS #: NO7400000
Name: IRON (FE)
% low Wt: 0.
% high Wt: 2.
OSHA PEL: 10 MG/M3
ACGIH TLV: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 7439-98-7
RTECS #: QA4680000
Name: MOLYBDENUM MO)
% low Wt: 0.
% high Wt: 10.
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 7440-02-0
RTECS #: QR5950000
Name: NICKEL
% low Wt: 0.
% high Wt: .8
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 7440-31-5
RTECS #: XP7320000
Name: TIN (SN)
% low Wt: 0.
% high Wt: 5.
ACGIH TLV: 2 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 1314-62-1
RTECS #: YW2450000
Name: VANADIUM(V)
% low Wt: 0.
% high Wt: 10.
OSHA PEL: C0.5 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 7440-67-7
RTECS #: ZH7070000
Name: ZIRCONIUM (ZR)
% low Wt: 0.
% high Wt: 6.
ACGIH TLV: 5 MG/M3
ACGIH STEL: 10 MG/M3
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Carcinogenicity Inds - NTP: YES
Effects of Exposure: NO TOXIC EFFECTS WOULD BE EXPECTED FROM THE INERT SOLID
PRODUCT OR UNDER NORMAL USAGE. PROLONGED, REPEATED EXPOSURE TO FUMES
GENERATED DURING BURNING, GRINDING, OR WELDING MAY AFFECT HEALTH AS FOLLOWS
-TITANIUM DIOXIDE HAS BEEN FOUND TO BE RELATIVELY INERT. TITANIUM &
ZIRCONIUM FUMES OR DUST ARE CONSIDERED TO BE IN THE NUISANCE CATEGORY.
ALUMINUM & MOLYBDENUM DUST ARE LOW HEALTH RISKS. VANADIUM FU MES OR DUST
ARE IRRITANTS TO THE RESPIRATORY TRACT. IRON FUMES/DUST MAY CAUSE SIDEROSIS
(NO FIBROSIS). NICKEL FUMES/DUSTS CAN PRODUCE RESPIRATORY IRRITATION &
PNEUMONIA. TIN FUMES & DUST HAVE CAUSED A RELATIVELY BEHIGN
PNEUMOCONIOSIS.
Explanation Of Carcinogenicity: CHROMIUM AND NICKEL AND THEIR COMPOUNDS ARE
LISTED IN THE THIRD ANNUAL REPORT ON CARCINOGENS, PREPARED BY THE NATIONAL
TOXICOLOGY PROGRAM. SOME INSOLUBLE CHROMATES & DICHROMATES ARE SUSPECTED
CARCINOG ENS. SEVERAL NICKEL COMPOUNDS, INCLUDING THE OXIDE, ARE SUSPECTED
CARCINOGENS.
Signs And Symptions Of Overexposure: ALUMINUM AND MOLYBDENUM- DUST MAY CAUSE
IRRITATION OF THE NOSE AND THROAT, WEIGHT LOSS, AND DIGESTIVE DISTURBANCE.
VANADIUM-SYMPTOMS INCLUDE PALLOR, GREENISH-BLACK DISCOLORATION OF THE TONGUE,
COUGH, PAIN IN THE CHEST, RALES, & CONJUNCTIVITIS. CHROMIUM-CHROMIUM
FUMES MAY CAUSE SKIN ULCER, USUALLY ON HANDS, OR PEFORATED NASAL SEPTUM.
First Aid: INHALATION: IF EXPOSED TO EXCESSIVE LEVELS OF METAL FUMES, MOVE
PERSON FROM CONTAMINATED AREA TO FRESH AIR. SEEK MEDICAL ATTENTION
IMMEDIATELY. SKIN: IF IRRITATION DEVELOPS, REMOVE CONTAMINATED CLOTHI NG,
WASH SKIN WITH SOAP OR MILD DETERGENT AND WATER FOR FIVE MINUTES. IF
IRRITATION PERISISTS, SEEK MEDICAL ATTENTION. EYES: IF IRRITATION DEVELOPS,
FLUSH WITH WATER FOR 15 MINUTES. INGESTION: AVOID H AND-TO-MOUTH CONTACT WITH
POWDERED RESIDUE. IF INGESTED, SEEK MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Handling And Storage Precautions: STORE AS A COMBUSTIBLE MATERIAL NOT EASILY
IGNITED, BUT VERY DIFFICULT TO EXTINGUISH. THE SMALLER THE PARTICLE, THE
GREATER THE HAZARD.
Other Precautions: IF IGNITABLE WASTE IS GENERATED, USE THE FOLLOWING
PROCEDURES: 1. KEEP WORK AREAS FREE OF THE WASTE. STORE AWAY FROM HEAT AND
OPEN FLAME. MAINTAIN HUMIDITY ABOVE 50% TO PREVENT ELECTROSATIC BUILD-UP. 3.
DO NOT SMOKE IN WASTE STORAGE AREA. 4. USE NON-SPARKING METAL EQUIPMENT WITH
AND NEAR IGNITABLE WASTE.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: DRY SALT OR POWDER EXTINGUISHER, OR INERT GAS (ARGON OR
HELIUM) FOR METAL FIRE.
Fire Fighting Procedures: REMOVE UNINVOLVED MATERIAL AND ALLOW FIRE TO BURN
OUT. COVER INVOLVED MATERIAL WITH SALT OR POWDER FROM EXTINGUISHER. IF FIRE
IS IN A CONTAINER, SMOTHER WITH INERT GAS. NOTE: THIS PRODUCT DOES NOT BUR N
EXCEPT IN VERY HIGH SURFACE AREA/VOLUME RATIOS (SUCH AS MACHINING, CHIPS OR
GRINDING DUST).
Unusual Fire/Explosion Hazard: DO NOT USE WATER OR OTHER LIQUID EXTINGUSHER AS
HYDROGEN MAY BE GENERATED, NITROGEN AND CARBON DIOXIDE ARE INEFFECTIVE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR A PROPERLY FITTED NIOSH-APPROVED DUST/FUME
RESPIRATOR DURING WELDING OR BURNING WHEN AIR CONTAMINANTS EXCEED OHSA
PERMISSIBLE EXPOSURE LEVELS OR ACGIH THESHOLD LIMIT VALUES.
Ventilation: USE LOCAL EXHAUST VENTILATION WHEN WELDING, BURNING, SAWING, OR
GIRNDING TITANIUM AND ITS ALLOYS.
Protective Gloves: WEAR APPROPRIATE WELDER'S GLOVES.
Eye Protection: WEAR SAFETY GLASSES OR GOGGLES AS REQURED BY EXPOSURE.
Other Protective Equipment: WEAR APPROPRIATE CLOTHING (SUCH AS WELDER'S HELMET,
GLOVES, AND APRON) WHEN WELDING OR BURNING.
Supplemental Safety and Health: NOTE: EXPOSURE TO HIGH CONCENTRATIONS OF FUMES
OR DUST CAN CAUSE SENSITIZATION DERMATITIS, INFLAMMATION OR ULCERATION OF
UPPER RESPIRATORY TRACT, AND POSSIBLE LUNG OR NASAL CANCER. RECENT STUDIES OF
W ORKERS MELTING & WORKING ALLOYS CONTAINING NICKLE/CHROMIUM HAVE NOT
FOUND INCREASED RISK OF CANCER.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: N1
M.P/F.P Text: 2850-3350F
Spec Gravity: 4.5
Appearance and Odor: SOLID, GRAY METALLIC, NO ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID OPEN FLAMES AND EXCESSIVE HEAT. NOTE THAT
MOLTEN METAL WILL REACT VIOLENTLY WITH WATER.
Materials To Avoid: AVOID STRONG OXIDIZING AND REDUCING AGENTS. RED FUMING
NITRIC OXIDE CAN REACT EXPLOSIVELY WITH TITANIUM ALLOYS.
Hazardous Decomposition Products: METAL FUMES AND CERTAIN NOXIOUS GASES, SUCH
AS CO, MAY BE PRODUCED DURING WELDING OR BURNING.
=======================================================
Other Information
=======================================================
Other Information: NOTE: UNDER NORMAL CONDITIONS, THESE PRODUCTS DO NOT
REPRESENT AN INHALATION, CONTACT OR INGESTION HEALTH HAZARD.
=======================================================
Transportation Information
=======================================================
Trans ID NO: 159688
MSDS NAME: TITANIUM/TITANIUM ALLOY, TITANIUM CP, TITANIUM 6A1-4V, ETC
MSDS Prepared Date: 11/10/1992
Review Date: 11/03/2001
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CY
Type Of Container: CYLINDER
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: TITANIUM/TITANIUM ALLOY, TITANIUM CP, TITANIUM 6A1-4V, ETC
Company: UNITED TITANIUM, INC
Street: 3450 OLD AIRPORT ROAD
PO Box: 951
City: WOOSTER OH
Zipcode: 44691
Health Emergency Phone: 216-264-2411
Label Required IND: Y
Date Of Label Review: 11/03/2001
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: NONE
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: NO TOXIC EFFECTS WOULD BE EXPECTED FROM THE INERT SOLID
PRODUCT OR UNDER NORMAL USAGE. PROLONGED, REPEATED EXPOSURE TO FUMES
GENERATED DURING BURNING, GRINDING, OR WELDING MAY AFFECT HEALTH AS FOLLOWS
-TITANIUM DIOXIDE HAS BEEN FOUND TO BE RELATIVELY INERT. TITANIUM &
ZIRCONIUM FUMES OR DUST ARE CONSIDERED TO BE IN THE NUISANCE CATEGORY.
ALUMINUM & MOLYBDENUM DUST ARE LOW HEALTH RISKS. VANADIUM FU MES OR DUST
ARE IRRITANTS TO THE RESPIRATORY TRACT. IRON FUMES/DUST MAY CAUSE SIDEROSIS
(NO FIBROSIS). NICKEL FUMES/DUSTS CAN PRODUCE RESPIRATORY IRRITATION &
PNEUMONIA. TIN FUMES & DUST HAVE CAUSED A RELATIVELY BEHIGN
PNEUMOCONIOSIS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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