DUPONT E I DE NEMOURS AND INC, -- FREPON 22
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Material Safety Data Sheet
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MSDS Num: CLQHS
MSDS NAME: FREPON 22
Responsible Party
Name: DUPONT E I DE NEMOURS AND CO INC, POLYMER PRODUCT-TEFLON CO.
Address: 1007 MARKET ST
City: WILMINGTON DE 19898
Info Phone: 800-523-0372/346-4748
Emergency Phone Number: (800)441-3637 (MEDICAL)
Resp. Party Other MSDS No.: L00295
Preparer's Name: NOT PROVIDED
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DUPONT E I DE NEMOURS AND CO INC, POLYMER PRODUCT-TEFLON CO.
Address: 1007 MARKET ST
City: WILMINGTON DE 19898
Phone: 800-523-0372/346-4748
Name: E.I. DUPONT DE NEMOURS & CO
Address: 1007 MARKET STREET
City: WILMINGTON DE 19898
Phone: 800-441-7515;800-441-9442
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Ingredients
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Cas: 75-45-6
RTECS #: PA6390000
Name: METHANE, CHLORODIFLUORO- "FREON" 22
Percent by Wt: 100.
Other REC Limits: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
ACGIH TLV: 3540 MG/M3;1000 PPM
ACGIH STEL: NOT ESTABLISHED
Ozone Depleting Chemical: 2
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Health Hazards Data
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LD50 LC50 Mixture: LC50 (INH, RAT): 220,000 PPM/ 4 HOUR
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: POTENTIAL HEALTH EFFECTS: INHALATION OF HIGH
CONCENTRATIONS OF VAPOR IS HARMFUL AND MAY CAUSE HEART IRREGULARITIES,
UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE OR DELIBERATE INHALATION MAY
CAUSE DEAT H WITHOUT WARNING. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING
AND IS HEAVIER THAN AIR. LIQUID CONTACT CAN CAUSE FROSTBITE. OVEREXPOSURE MAY
CAUSE DEFATTING OF SKIN, EYE IRRITATION, DISCOMFORT, TEARI NG AND BLURRED
VISION, TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANESTHETIC EFFECTS SUCH AS
DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, UNCONSCIOUSNESS, IRREGULAR
PULSE, PALPITATIONS, INADEQUATE CI RCULATION.
Explanation Of Carcinogenicity: NONE OF THE COMPONENTS PRESENT IN THIS MATERIAL
AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED BY IARC, NTP, OSHA
OR ACGIH AS A CARCINOGEN.
Signs And Symptions Of Overexposure: INHALATION OF HIGH CONCENTRATIONS OF VAPOR
MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE
OR DELIBERATE INHALATION MAY CAUSE DEATH WITHOUT WARNING. LIQUID CONTACT CAN
CAU SE FROSTBITE. OVEREXPOSURE MAY CAUSE DEFATTING OF SKIN, EYE IRRITATION,
DISCOMFORT, TEARING AND BLURRED VISION, TEMPORARY NERVOUS SYSTEM DEPRESSION
WITH ANESTHETIC EFFECTS SUCH AS DIZZINESS, HEADACHE, CONFUSION,
INCOORDINATION, UNCONSCIOUSNESS, IRREGULAR PULSE, PALPITATIONS, INADEQUATE
CIRCULATION.
Medical Cond Aggravated By Exposure: INDIVIDUALS WITH PREEXISTING DISEASES OF
THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.
First Aid: INHALATION: IF INHALED, IMMEDIATELY REMOVE TO FRESH AIR. KEEP PERSON
CALM. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. SKIN: IN CASE OF CON TACT, FLUSH
SKIN WITH LUKEWARM WATER. DO NOT USE HOT WATER. IF FROSTBITE HAS OCCURRED,
CALL A PHYSICIAN. EYE: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES. C ALL A PHYSICIAN. INGESTION: INGESTION IS
NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
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Handling and Disposal
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Spill Release Procedures: VENTILATE AREA, ESPECIALLY LOW OR ENCLOSED PLACES
WHERE HEAVY VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE SELF-CONTAINED
BREATHING APPARATUS (SCBA) FOR LARGE SPILLS OR RELEASES.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: RECLAIM BY DISTILLATION OR REMOVE TO A PERMITTED WASTE
DISPOSAL FACILITY. COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: AVOID BREATHING VAPORS AND LIQUID CONTACT
WITH SKIN OR EYES. USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE EXPOSURE
BELOW RECOMMENDED LIMITS. STORAGE: CLEAN, DRY AREA. DO NOT HEAT ABOVE 125F
(52 C) .
Other Precautions: DYMEL 22 SHOULD NOT BE MIXED WITH AIR FOR LEAK TESTING. IN
GENERAL, IT SHOULD NOT BE USED OR ALLOWED TO BE PRESENT WITH HIGH
CONCENTRATIONS OF AIR ABOVE ATOMOSPHERIC PRESSURE.
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Fire and Explosion Hazard Information
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Flash Point Text: WILL NOT BURN
Autoignition Temp: =632.2C, 1170.F
Extinguishing Media: AS APPROPRIATE FOR COMBUSTIBLES IN AREA. EXTINGUISHANT FOR
OTHER BURNING MATERIAL IN AREA IS SUFFICIENT TO STOP BURNING.
Fire Fighting Procedures: USE WATER SPRAY OR FOG TO COOL CONTAINERS.
SELF-CONTAINED BRATHING APPARATUS (SCBA) IS REQUIRED IF CYLINDERS RUPTURE OR
CONTENTS ARE RELEASED UNDER FIRE CONDITIONS.
Unusual Fire/Explosion Hazard: CYLINDERS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSTION MAY OCCUR. IT IS COMBUSTIBLE AT AMBIENT TEMPERATURE AND 60 PSIG
WHEN MIXED WITH AIR AT CONCENTRATIONS OF 65 VOLUME % AIR.
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Control Measures
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Respiratory Protection: NORMAL VENTILATION FOR STANDARD PROCEDURES IS GENERALLY
ADEQUATE. UNDER NORMAL MANFUACTURING CONDITIONS, NO RESPIRATORY PROTECTION IS
REQUIRED WHEN USING THIS PRODUCT. SELF-CONTAINED BREATHING APPARAT US (SCBA)
IS REQUIRED IF A LARGE RELEASE OCCURS.
Ventilation: LOCAL EXHAUST SHOULD BE USED WHEN LARGE AMOUNTS ARE RELEASED.
MECHANICAL VENTILATION SHOULD BE USED IN LOW OR ENCLOSED PLACES.
Protective Gloves: IMPERVIOUS
Eye Protection: CHEMICAL SPLASH GOGGLES
Other Protective Equipment: NOT PROVIDED
Work Hygienic Practices: NOT PROVIDED
Supplemental Safety and Health: ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT
AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI = GASTROI
NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS.
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Physical/Chemical Properties
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HCC: G3
NRC/State LIC No: NOT RELEVANT
Boiling Point: =-40.6C, -41.4F
M.P/F.P Text: NOT PROVIDED
Decomp Text: NOT PROVIDED
Vapor Pres: 7821 @ 25C/77F
Vapor Density: 3.03 @ 25C
Spec Gravity: 1.194 G/CM3 @ 77F
Evaporation Rate & Reference: >1 (CCL4=1.0)
Solubility in Water: 0.3% @ 25C
Appearance and Odor: CLEAR, COLORLESS LIQUEFIED GAS, SLIGHT ETHERAL ODOR.
Percent Volatiles by Volume: 100 WT
Corrosion Rate: NOT PROVIDED
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Materials To Avoid: INCOMPATIBLE WITH ALKALI OR ALKALINE EARTH METALS-POWDERED
AL, ZN, BE, ETC.
Hazardous Decomposition Products: THIS MATERIAL CAN BE DECOMPOSED BY HIGH
TEMPERATURES (OPEN FLAMES, GLOWING METAL SURFACES, ETC.) FORMING HYDROCHLORIC
AND HYDROFLUORIC ACIDS, AND POSSIBLY CARBONYL HALIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
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Toxicological Information
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Toxicological Information: EFFECTS FROM SINGLE HIGH EXPOSURES INCLUDE CNS
DEPRESSION, ANESTHESIA, RAPID BREATHING, LUNG CONGESTION AND MICROSCOPIC
LIVER CHANGES. CARDIAC SENSITIZATION OCCURRED IN DOGS AT 50,000 PPM OR
GREATER F ROM THE ACTION OF EXOGENOUS EPINEPHRINE. NO TOXIC EFFECTS OCCURRED
IN RATS REPEATEDLY EXPOSED TO CONCENTRATIONS RANGING FROM 10,000 TO 50,000
PPM (V/V). LONG-TERM EXPOSURE TO 50,000 PPM (V/V) OF VAPOR S PRODUCED ORGAN
WEIGHT INCREASES AND A DECREASE IN BODY WEIGHT GAIN, BUT NO INCREASED
MORTALITY OR ADVERSE HEMATOLOGICAL EFFECTS.
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Ecological Information
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Ecological: NOT PROVIDED
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MSDS Transport Information
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Transport Information: SHIPPING INFORMATION: DOT/IMO PROPER SHIPPING NAME:
CHLORODIFLUOROMETHANE. HAZARD CLASS: 2.2. UN NO.: 1018. DOT/IMO LABEL:
NONFLAMMABLE GAS.
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Regulatory Information
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Sara Title III Information: TITLE III HAZARD CLASSIFICATION SECTION 31, 312:
ACUTE: YES. CHRONIC: NO. FIRE: NO. REACTIVITY: NO. PRESSURE: YES. HAZARDOUS
CHEMICAL LISTS: SARA EXTREMELY HAZARDOUS SUBSTANCE: NO. CERCLA HAZARDOUS SU
BSTANCE: NO. TOXIC CHEMICALS: YES
Federal Regulatory Information: NOT PROVIDED
State Regulatory Information: NOT PROVIDED
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Other Information
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Other Information: NOTE TO PHYSICIAN: BECAUSE OF A POSSIBLE DISTURBANCE OF
CARDIAC RHYTHM, CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE SHOULD BE CONSIDERED
ONLY AS A LAST RESORT IN LIFE-THREATENING EMERGENCIES.
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Transportation Information
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Trans ID NO: 159826
MSDS NAME: FREPON 22
MSDS Prepared Date: 06/27/1991
Review Date: 11/10/2001
Multiple KIT Number: 0
Unit Of Issue: CY
Type Of Container: CYLINDER
Additional Data: PROPER SHIPPING NAME, UN ID NUMBER, HAZARD CLASS, PER MSDS.
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Detail DOT Information
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DOT PSN Code: DHC
DOT Proper Shipping Name: CHLORODIFLUOROMETHANE, OR REFRIGERANT GAS R22
Hazard Class: 2.2
UN ID Num: UN1018
Label: NONFLAMMABLE GAS
Special Provision: B51
Non Bulk Pack: 304
Bulk Pack: 314,315
Max Qty Pass: 75 KG
Max Qty Cargo: 150 KG
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: EDB
IMO Proper Shipping Name: CHLORODIFLUOROMETHANE
IMDG Page Number: 2118
UN Number: 1018
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-09
MED First Aid Guide NUM: 350
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Detail IATA Information
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IATA PSN Code: GHQ
IATA UN ID Num: 1018
IATA Proper Shipping Name: CHLORODIFLUOROMETHANE
IATA PSN Modifier: (R22)
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 200
Max Quant Pass: 75KG
Max Quant Cargo: 150KG
Packaging Note Cargo: 200
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Detail AFI Information
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AFI PSN Code: GHQ
AFI Proper Shipping Name: CHLORODIFLUOROMETHANE
AFI Hazard Class: 2.2
AFI UN ID NUM: UN1018
Special Provisions: P5
Back Pack Reference: A6.3, A6.5
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HAZCOM Label
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MSDS NAME: FREPON 22
Company: DUPONT E I DE NEMOURS AND CO INC, POLYMER PRODUCT-TEFLON CO.
Street: 1007 MARKET ST
City: WILMINGTON DE
Zipcode: 19898
Health Emergency Phone: (800)441-3637 (MEDICAL)
Label Required IND: Y
Date Of Label Review: 11/10/2001
Status Code: A
MFG Label NO: NOT PROVIDED
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: NO
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: NOT PROVIDED. VAPOR IS HARMFUL AND MAY
CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS, DEATH, FROSTBITE. FIRST AID:
INHALATION: IF INHALED, IMMEDIATELY REMOVE TO FRESH AIR. KEEP PERSON CAL M.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. CALL A PHYSICIAN. SKIN: IN CASE OF CONTACT, FLUSH SKIN WITH
LUKEWARM WATER. DO NOT USE HOT WATER. IF FROSTBITE HAS OCCURRED, CALL A
PHYSICIAN. EYE: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF
WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. INGESTION: INGESTION IS NOT
CONSIDERED A POTENTIAL ROUT E OF EXPOSURE. READ MSDS BEFORE USING.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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