LUCAS-MILHAUPT INC -- SILVER-COPPER-CADMIUM-ZINC BRAZING ALLOYS
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Material Safety Data Sheet
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MSDS Num: CLRLK
MSDS NAME: SILVER-COPPER-CADMIUM-ZINC BRAZING ALLOYS
Responsible Party
Name: LUCAS-MILHAUPT INC
Address: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI 53110
Info Phone: 414-769-6000
Emergency Phone Number: (800)424-9300
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Address: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI 53110
Phone: 414-769-6000
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Ingredients
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Cas: 7440-22-4
RTECS #: VW3500000
Name: SILVER
% low Wt: 20.
% high Wt: 50.
OSHA PEL: 0.01 MG/M3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 7440-43-9
RTECS #: EU9800000
Name: CADMIUM
% low Wt: 5.
% high Wt: 25.
OSHA PEL: 5 UG/M3
ACGIH TLV: 0.01 MG/M3
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 7440-66-6
RTECS #: ZG8600000
Name: ZINC
% low Wt: 16.
% high Wt: 30.
OSHA PEL: 0.1 MG/M3
ACGIH TLV: 0.2 MG/M3
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER
% low Wt: 15.
% high Wt: 45.
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Health Hazards Data
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Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: EYES: EYE CONTACT WITH THESE PRODUCTS IN FINELY-DIVIDED
FORMS MAY CAUSE IRRITATION, ARGYRIA, CONJUNCTIVITIS, AND/OR ULCERATION OF THE
CORNEA. SKIN: SLIN CONTACT WITH THESE PRODUCTS, PRATICULARLY IN F
INELY-DIVIDED FORMS, MAY CAUSE IRRITATION, ARGYRIA, DISCOLORATION, AND/OR
CONTACT DERMATITIS. INGESTION: INGESTION OF THESE PRODUCT IN FINELY-DIVIDED
FORMS MAY CAUSE NAUSEA, VOMITING, AND GASTROINTEST INAL IRRITATION. LONG-TERM
CHRONIC INGESTION MAY DAMAGE THE LIVER, KIDNEYS, MUSCULOSKELETAL SYSTEM.
INHALATION: IS NOT KNOWN TO PRESENT A SIGNIFICANT RISK TO HEALTH WHEN USED
ACCORDING TO INSTRUCTIONS & WITH APPROPIATE PROTECTIVE MEASURES.
Explanation Of Carcinogenicity: CADMIUM IS CLASSIFIED AS A POTENTIAL HUMAN
CARCINOGEN BY THE FOLLOWING ORGANIZATIONS: (1) IARC (GROUP 1); (2) NTP (GROUP
2A, 2B). IT IS ALSO REGULATED AS A CARCINOGEN BY OSHA. NONE OF THE OTHER
COMPON ENTS OF THESE PRODUCTS ARE CLASSIFIED AS POTENTIAL OR DEMOSTRATED
CARCINOGENS BY IARC, NTP OR OSHA.
Signs And Symptions Of Overexposure: INHALATION OF COMPONENT ELEMENTS HAS BEEN
REPORTED TO CAUSE ONE OR MORE OF THE FOLLOWING SYMPTOMS & EFFECTS UPON
EXCESSIVELY HIGH OR PROLONGED EXPOSURE: CADMIUM-MAY CAUSE GASTROINTESTINAL
SYMPTOMS, AN EMIA, RHINITIS, DISCOLORATION OF TEETH, KIDNEY DISEASE,
MICROFRACTURES, & CANCER. COPPER-MAY CAUSE RESPIRATORY TRACT IRRITATION,
FEVER, MUCLE ACHE, CHILLS, COUGH, WEAKNESS, & A METALLIC TASE. SILVER-M
AY PRODUCE ARGYRIA, A PERMANENT BLUE-GRAY DISCOLORATION OF THE SKIN, EYES,
MUCOUS MEMBRANES, & RESPIRATORY TRACT. ZINC-MAY CAUSE RESPIRATORY TRACT
IRRITATION & "METAL FUME FEVER", CHARACTERIZED BY MET ALLIC TASTE, DRY
THROAT, COUGH, CHILLS.
Medical Cond Aggravated By Exposure: PREEXISTING PULMONARY DISEASES
(BRONCHITIS, ASTHMA) MAY BE AGGRAVATED BY INHALATION, AS FUME. CHRONIC
EXPOSURE BY INHALATION/INGESTION MAY AGGRAVATE LIVER, KIDNEYS, GI SYSTEM, MS
& NERVOUS SYSTEM.
First Aid: EYES: FLUSH AFFECTED AREAS WITH WATER FOR AT LEAST FIFTEEN MINUTES.
SEEK MEDICAL ASSITANCE IF NECESSARY. SKIN: REMOVE CONTAMINATED CLOTHING. WASH
AFFECTED AREA WITH LARGE QUANTITIES OF WATER FOR AT LE AST FIVE MINUTES. SEEK
MEDICAL ASSISTANCE IF NECESSARY. INGESTION: IF SUBJECT IS CONSCIOUS, INDUCE
VOMITING. IF UNCONSCIOUS OR CONVULSIVE, SEEK IMMEDIATE MEDICAL ASSISTANCE.
INHALATION: IF SIGNS AND S YMPTOMS OF TOXICITY ARE OBSERVED, REMOVE SUBJECT
FROM AREA, ADMINISTER OXYGEN, AND SEEK MEDICAL ATTENTION. KEEP THE SUBJECT
WARM AND AT REST. PERFORM ARTIFICIAL RESPRIRATION IF BREATHING HAS STOPPED.
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Handling and Disposal
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Spill Release Procedures: IF A FINELY-DIVIDED FORM OF PRODUCT IS SPILLED, CLEAN
UP SPILLAGE SO AS TO MINIMIZE DISPERSION OF DUST. WET SWEEPING OR VACUUMING
USING HEPA FILTATION ARE RECOMMENDED.
Waste Disposal Methods: CONSULT THE MANUFACTURER FOR DISPOSTION OF UNUSED OR
UNUSABLE PRODUCT.
Handling And Storage Precautions: DO NOT STORE IN PROXIMITY TO INCOMPATIBLE
MATERIALS.
Other Precautions: PRECAUTIONARY LABEL (OSHA): DANGER, CONTAIN CADMIUM. CANCER
HAZARD. AVOID CREATING DUST. CAN CAUSE LUNG AND KINEY DISEASE.
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Fire and Explosion Hazard Information
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Extinguishing Media: USE DRY POWDER, DO NOT USE WATER.
Fire Fighting Procedures: IN FIGHTING A FIRE IN WHICH THESE PRODUCTS ARE
PRESENT, WEAR A SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
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Control Measures
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Respiratory Protection: IF AN EXPOSURE LEVEL EXCEEDS AN OSHA PEL(S) OR OTHER
APPLICABLE STANDARD, USE A NIOSH-APPROVED RESPIRATOR HAVING A CONFIGURATION
(CLASS, TYPE OF FACEPIECE, FILTER MEDIA, ASSIGNED PROTECTION FACTOR, ET C.)
APPROPRIATE TO THE CONCENTRATION OF THE CONTAMINAT(S) GENERATED.
Ventilation: USE APPROPRIATE VENTILATION (E.G., DILUTION, LOCAL EXHAUST)
ADEQUATE TO MAINTAIN CONCENTRATION OF ALL COMPONENTS AND THEIR DECOMPOSTION
BYPRODUCTS.
Protective Gloves: WEAR APPROPRIATE PROTECTIVE GLOVES.
Eye Protection: WEAR EYE PROTECTION (SAFETY GLASSES, GOGGLES).
Other Protective Equipment: PLASTIC-FRAME SPECTACLES WITH SIDE SHIELDS AND
FILTER LENSES (SHADE #3 OR #4) ARE RECOMMENDED.
Work Hygienic Practices: TO AVOID INGESTION, WASH HANDS AND FACE BEFORE EATING,
DRINKING, OR USING COSMETICS OR TOBACCO.AVOID FLAMMABLE FABRICS.
Supplemental Safety and Health: THE IPRODUCT NAME: SILVER-COPPER-CADMIUM-ZINC
BRAZING ALLOYS. CHEMICAL FAMILY: BRAZING FILLER METAL; SILVER SOLDER.
CHEMICAL FAMILY: ALLOYS OF SILVER, COPPER, CADMIUM, & ZINC.
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Physical/Chemical Properties
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HCC: N1
Melt/Freeze Pt: =598.9C, ######F
M.P/F.P Text: 1110-1170
Spec Gravity: 8.79-9.53
Solubility in Water: INSOLUBLE
Appearance and Odor: ODORLESS LIGHT YELLOW METALS IN FORM OF WIRE, ROD, STRIP,
POWDER OR PERFORMED
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Reactivity Data
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Stability Indicator: YES TRATE; NITROBENZENE; FE(CO)5.
Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE. SILVER AND COPPER CAN
FORM UNSTABLE ACETYLIDES UPON CONTACT WITH ACETYLENE GAS.
Materials To Avoid: STRONG OXIDIZER; SE; TE; MG; CHLORATES; NH3; HN03; AZIDES,
ETHANOL, THYLENE IMINE; C1F3; INORGANIC/ORGANIC PEROXIDES; PEROXYFORMIX ACID;
CHLORINE & FLUORINE; PERMONOSULFURIC ACID; CR03; MN & CA CHLORIDES; CS2;
HYDRZINE MONO
Hazardous Decomposition Products: HEATING TO ELEVATED TEMERATURES MAY LIBERATE
METAL/METAL OXIDE FUMES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: GENETIC/REPODUCTIVE EFFECTS: IN EXPERIMENTAL
STUDIES, CADMIUM HAS BEEN FOUND TO CAUSE REPRODUCTIVE ABNORMALITIES,
INCLUDING REDUCED BIRTH DEFECTS, REDUCED VIABILITY, & BEHAVIORAL
ALTERATIONS, AMONG OF FSPRINGS OF FEMALE RODENTS. MALE RODENTS EXPOSED TO
CADMIUM HAVE BEEN FOUND TO HAVE TESTICULAR DAMAGE, REDUCTION IN SPERM COUNTS,
& REDUCED FERTILITY. CADMIUM HAS ALSO PRODUCED MUTAGENIC EFFECTS IN MA
MMALIAN CELL CULTURES.
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Ecological Information
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Ecological: NO DATA GIVEN.
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MSDS Transport Information
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Transport Information: HAZARD CLASS: SHIPMENT NOT CONTROLLED BY
USDOT/IATA/ICAO/IMO REGULATIONS.
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Regulatory Information
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Sara Title III Information: SARA TITLE III-HAZARD CLASSES: ACUTE HEALTH HAZARD.
CHRONIC HEALTH HAZARD. SARA TITLE III-SECTION 313 SUPPLIER NITIFICATION: THIS
PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE RPORTING
REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY
RIGHT-TO-KNOW ACT (RCRA) OF 1986 AND OF 40 CFR 372: 7440-22-4, SILVER,
20-50%; 7440-43-9, CADMIUM, 5-25%; 7440-66-6, ZINC, 16-30% A ND 7440-50-8,
COPPER, 15-45%. THIS INFORMATION MUST BE INCLUDED ON ALL MSDSS THAT ARE
COPIED AND DISTRIBUTED FOR THIS MATERIAL.
State Regulatory Information: WARNING! THESE PRODUCTS CONTAIN CHEMICALS KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
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Other Information
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Transportation Information
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Trans ID NO: 160111
MSDS NAME: SILVER-COPPER-CADMIUM-ZINC BRAZING ALLOYS
MSDS Prepared Date: 07/01/1998
Review Date: 12/02/2001
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CY
Type Of Container: CYLINDER
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: SILVER-COPPER-CADMIUM-ZINC BRAZING ALLOYS
Company: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Street: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI
Zipcode: 53110
Health Emergency Phone: (800)424-9300
Label Required IND: Y
Date Of Label Review: 12/02/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: EYES: EYE CONTACT WITH THESE PRODUCTS IN FINELY-DIVIDED
FORMS MAY CAUSE IRRITATION, ARGYRIA, CONJUNCTIVITIS, AND/OR ULCERATION OF THE
CORNEA. SKIN: SLIN CONTACT WITH THESE PRODUCTS, PRATICULARLY IN F
INELY-DIVIDED FORMS, MAY CAUSE IRRITATION, ARGYRIA, DISCOLORATION, AND/OR
CONTACT DERMATITIS. INGESTION: INGESTION OF THESE PRODUCT IN FINELY-DIVIDED
FORMS MAY CAUSE NAUSEA, VOMITING, AND GASTROINTEST INAL IRRITATION. LONG-TERM
CHRONIC INGESTION MAY DAMAGE THE LIVER, KIDNEYS, MUSCULOSKELETAL SYSTEM.
INHALATION: IS NOT KNOWN TO PRESENT A SIGNIFICANT RISK TO HEALTH WHEN USED
ACCORDING TO INSTRUCTIONS & WITH APPROPIATE PROTECTIVE MEASURES.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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