propionic acid, 3-ethoxy-, ethyl ester; (ethyl-3-ethoxypropionate) vp: 2-heptanone; (methyl n-amyl ketone) vp: 2.14 @ 0c ld50: (oral, rat) 1.7 2,4-pentanedione vp: 13 @ 0c volatile organic compounds, material: 7.21 lb/gal supdat: & fatg). can cause gi irrit, abdom pain, naus, vomit & ing 5: &/or sanding dust over period of yrs may cause diseases of ing 6:following efts in lab animals &/or humans:nervous sys dmg, ing 7: sys. rpts have assoc rptd & prlng occup overexp to solv w/perm ing 8: misuse by delib conc & inhaling contents may be harmful/fatal. first aid proc: assistance immed. if brthg ceases, restore using apprvd spill proc: completed. stop spill @ source, cntn area of spill to pvnt ing 11:remaining liq may be absorbed w/inert matl such as sand, clay, ing 12:w/non-spk tools. pvnt run-off to sewers, streams/other bodies of ing 13: auth as reqd that a spill has occurred. other prec: blended as the combination may cntn haz of each component. ing 15: trained pers using proper equip. not intended for sale to or use
U.S. PAINT CORP -- AWLGRIP HIGH SOLIDS ACTIVATOR A0001
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BTZRT
MSDS NAME: AWLGRIP HIGH SOLIDS ACTIVATOR A0001
Responsible Party
Name: U.S. PAINT CORP
Address: 831 S 21ST ST
City: ST LOUIS MO 63103
Info Phone: 314-621-0525
Emergency Phone Number: 314-621-0525;800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: U.S. PAINT CORP
Address: 831 S 21ST ST
City: ST LOUIS MO 63103
Phone: 314-621-0525
Name: US PAINT CORPORATION
Address: 831 SOUTH 21ST STREET
City: ST LOUIS MO 63103-3092
Phone: 314-621-0525
=======================================================
Ingredients
=======================================================
Cas: 763-69-9
RTECS #: UF3325000
Name: PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER; (ETHYL-3-ETHOXYPROPIONATE) VP:
1.50 @ 0C LD50: (ORAL, RAT) 5 G/KG
% Wt: 10-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 110-43-0
RTECS #: MJ5075000
Name: 2-HEPTANONE; (METHYL N-AMYL KETONE) VP: 2.14 @ 0C LD50: (ORAL, RAT) 1.7
G/KG
% Wt: 50-70
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM
------------------------------
Cas: 123-54-6
RTECS #: SA1925000
Name: 2,4-PENTANEDIONE VP: 13 @ 0C
% Wt: <15
OSHA PEL: 20 PPM (MFR)
ACGIH TLV: 20 PPM (MFR)
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS, MATERIAL: 7.21 LB/GAL
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: & FATG). CAN CAUSE GI IRRIT, ABDOM PAIN, NAUS, VOMIT &
DIARR. CHRONIC: PRLNG & RPTD BRTHG OF SPRAY MIST
-----------------------------
Name: ING 5: &/OR SANDING DUST OVER PERIOD OF YRS MAY CAUSE DISEASES OF
LUNGS. OVEREXP TO MATL/COMPONENTS MAY CAUSE
-----------------------------
Name: ING 6:FOLLOWING EFTS IN LAB ANIMALS &/OR HUMANS:NERVOUS SYS DMG,
IMMUNE SYS DMG & DMG TO RED BLOOD CELL FORMING
-----------------------------
Name: ING 7: SYS. RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLV W/PERM
BRAIN & NERVOUS SYS DMG. INTENTIONAL
-----------------------------
Name: ING 8: MISUSE BY DELIB CONC & INHALING CONTENTS MAY BE HARMFUL/FATAL.
-----------------------------
Name: FIRST AID PROC: ASSISTANCE IMMED. IF BRTHG CEASES, RESTORE USING APPRVD
CPR TECHNIQUES & SUMMON MED HELP IMMED.
-----------------------------
Name: SPILL PROC: COMPLETED. STOP SPILL @ SOURCE, CNTN AREA OF SPILL TO PVNT
SPREADING, PUMP LIQ TO SALVAGE TANK.
-----------------------------
Name: ING 11:REMAINING LIQ MAY BE ABSORBED W/INERT MATL SUCH AS SAND, CLAY,
EARTH/FLOOR ABSORB & SHOVELED INTO CNTNRS
-----------------------------
Name: ING 12:W/NON-SPK TOOLS. PVNT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF
WATER. IF RUN-OFF OCCURS, NOTIFY PROPER
-----------------------------
Name: ING 13: AUTH AS REQD THAT A SPILL HAS OCCURRED.
-----------------------------
Name: OTHER PREC: BLENDED AS THE COMBINATION MAY CNTN HAZ OF EACH COMPONENT.
FOR INDUSTRIAL USE ONLY BY PROFESSIONAL,
-----------------------------
Name: ING 15: TRAINED PERS USING PROPER EQUIP. NOT INTENDED FOR SALE TO OR USE
BY GENERAL PUBLIC.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES: CAN CAUSE SEV IRRIT, REDNESS,TEARING &
BLURRED VISION. SKIN: PRLNG/RPTD CNTCT CAN CAUSE MODERATE IRRIT, DEFAT &
DERM. CAN BE ABSORBED THRU SKIN. INHAL: EXCESS INHAL OF VAPORS CAN CAUSE NA
SAL & RESP IRRIT; CNS EFTS INCL DIZZ, WEAK, FATG, NAUS, HDCH & POSS
UNCON. DISAGREEABLE ODOR FROM ONLY (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: FEW PPM OF ING 3 IN ATM CAN
CAUSE NAUS. EXPOS TO ABOUT 1000 PPM FOR 30 MIN/LONGER COULD RSLT IN INHAL OF
HARMFUL & POSS FATAL AMTS OF MATL. INGEST: HARMFUL IF SWALLOWED. SM AMTS
OF LIQ ASPIR INTO RESP SYS DURING INGEST/VOMIT MAY CAUSE BRONCHIOPNEUM/PULM
EDEMA. MAY CAUSE SIGNS OF NERVOUS SYS DEPRESS (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: SKIN: WASH AREA THORO W/SOAP & WATER. REMOVE SOILED CLTHG. GET
MED ASSISTANCE IF IRRIT PERSISTS. WASH CLTHG BEFORE REUSE. EYES: FLUSH W/LG
AMTS OF WATER FOR @ LEAST 15 MIN. GET MED ASSISTANCE. INGEST: GET MED ATTN
IMMED. DO NOT INDUCE VOMIT. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUM
WHICH CAN BE FATAL. INHAL: LEAVE AREA TO OBTAIN FRESH AIR. IF BRTHG DFCLTY
CONTINUES, SUMMON MED
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SM SPILL:ABSORB LIQ ON INERT MATL SUCH AS PAPER,
VERMICULITE, FLOOR ABSORB & TRANSFER TO HOOD. LG SPILL:ELIM ALL IGNIT
SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPK). EXCLUDE FROM SPILL AREA
PER S NOT WEARING PROT EQUIP UNTIL CLEAN-UP
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: ALLOW VOLATILE PORTION TO EVAP IN HOOD BEING SURE TO
ALLOW SUFFICIENT TIME FOR VAPS TO COMPLETELY CLEAR HOOD DUCT WORK. DISPOSE
OF CONTAMD ABSORB, CNTNR & UNUSED CONTENTS I/A/W LOCAL, STATE &
FEDERAL REGS. DO NOT INCINERATE CLOSED CONTAINERS.
Handling And Storage Precautions: KEEP CLOSURE TIGHT & UPRIGHT TO PVNT
LEAK. KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT STORE > 120F. DO NOT
TRANSFER CONTENTS TO BOTTLES/UNLABELED CNTNRS.
Other Precautions: CNTNRS OF MATL MAY BE HAZ WHEN EMPTIED SINCE THEY RETAIN
PROD RESIDUES(VAP, LIQ &/OR SOLID). ALL HAZ PREC MUST BE OBSERVED. THIS
PROD MUST BE BLENDED W/OTHER PRODS PRIOR TO USE. READ ALL WARNINGS & PR
EC ON LABELS OF ALL PRODS BEING
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 96.0F,35.6C
Lower Limits: 1%
Upper Limits: 11.4%
Extinguishing Media: DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA &FULL PROT EQUIP(FP N).
SUMMON PROFESSIONAL FIREFIGHTERS. DURING FIRE, TOX GASES & SMOKE ARE
IRRITS PRESENT FROM DECOMP/COMBUST. (SUPDAT)
Unusual Fire/Explosion Hazard: KEEP AWAY FROM HEAT, SPK & FLAME. DO NOT
SMOKE. EXTING ALL PILOT LIGHTS & TURN OFF ALL IGNIT SOURCES INCL HEATERS,
FANS & OTHER NON-EXPLO-PROOF ELEC (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR APPROP, PROPERLY FITTED NIOSH/MSHA APPRVD RESP
DURING & AFTER APPLICATN UNLESS AIR MONITORING DEMONSTRATES VAP,MIST
& PARTICULATE LEVELS ARE BELOW APPLIC LIM. FOLLOW RESP MFR DIRECTIONS.
ENGINEER ING/ADMIN CTLS SHOULD BE IMPLEMENTED.
Ventilation: USE ONLY W/ADEQ VENT. MAINTAIN CONTINUOUS FLOW OF FRESH AIR.
PROVIDE SUFFICIENT MECH (GEN &/OR LOC EXHST) VENT.
Protective Gloves: SOLVENT IMPERMEABLE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKER GOGGLES (FP N).
Other Protective Equipment: SOLVENT IMPERMEABLE CLOTHING & BOOTS ARE
RECOMMENDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRE FIGHT PROC: CLSD CNTNR MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. EXPLO HAZ: EQUIP, DURING USE & UNTIL ALL VAPS ARE
GONE. VAPS MAY IGNITE EXPLO. VAPS MAY SPREAD LONG DIST & BEYOND CLSD
DOORS. PVNT B UILD UP OF VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR.
EFTS OF OVEREXP: (E.G., DROW, DIZZ, INCOORDINATION
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >284F,>140C
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Spec Gravity: 0.87
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume: 100
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID HEAT, SPARK AND OPEN FLAME.
Materials To Avoid: CAN REACT VIGOROUSLY, EVEN VIOLENTLY, W/OXIDIZING MATLS.
ADDNL MATLS: CONCENTRATED NITRIC ACID OR PERCHLORIC ACID.
Hazardous Decomposition Products: CARBON DIOXIDE & CARBON MONOXIDE. VARIOUS
HYDROCARBONS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: AWLGRIP HIGH SOLIDS ACTIVATOR A0001
Assigned IND: Y
Company: U.S. PAINT CORP
Street: 831 S 21ST ST
City: ST LOUIS MO
Zipcode: 63103
Health Emergency Phone: 314-621-0525;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 07/28/1994
Status Code: C
Label Date: 07/28/1994
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: CAN REACT VIOLENTLY W/OXIDIZERS. ACUTE: EYES: SEV
IRRIT, REDNESS, TEARING & BLURRED VISION. SKIN: MOD IRRIT, DEFAT &
DERM. CAN BE ABSORBED. INHAL: CAN CAUSE NASAL & RESP IRRIT; DIZZ, WEAK,
FATG, NAUS, HDCH & POSS UNCON. DISAGREEABLE ODOR CAN CAUSE NAUS. COULD
RSLT IN INHAL OF HARMFUL & POSS FATAL AMTS OF MATL. INGEST: HARMFUL IF
SWALLOWED. ASPIR DURING INGEST/VOMIT MAY CAUSE BRONCHIOPNEUM/PULM EDE MA. GI
IRRIT, ABDOM PAIN, NAUS, VOMIT & DIARR. CHRONIC: BRTHG OF SPRAY MIST
&/OR SANDING DUST OVER PERIOD OF YRS MAY CAUSE DISEASES OF LUNGS. MAY
CAUSE BRAIN/NERVOUS SYS DMG, IMMUNE SYS DMG & DMG TO R ED BLOOD CELL
FORMING SYS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.