acetic acid, butyl ester; (n-butyl acetate) (cercla) vp: 10 @ 20c alcohol; (cda-19 alcohol) (mixture of ing 3-5) vp: 40 @ 19c ethyl alcohol; (ethanol) 95% of ing 2 2-pentanone, 4-methyl-; (methyl isobutyl ketone) (sara 313) (cercla) 4% heptane; (n-heptane) 1% of ing 2 butyl alcohol; (normal butyl alcohol) (1-butanol) vp: 5.5 @ 20c ethylcellulose; (black ethyl cellulose dispersion) (mix of ing 8-18) vp: ethyl alcohol; (ethanol) 15% of ing 7 toluene; (toluol) 61% of ing 7 pigment 24% of ing 7 cellulose solvent; (cellulose nitrate wet w/2-propanol) (mix ing 12-13) nitrocellulose 10% of ing 11 isopropyl alcohol (sara 313) 30% of ing 11 cellulose solvent; (cellulose nitrate dispersion flatting agent) (mixture ethyl alcohol; (ethanol) 2.7% of ing 14 acetic acid, ethyl ester; (ethyl acetate) (cercla) 23.1% of ing 14 toluene; (toluol) 23.2% of ing 14 butyl alcohol, tert-, potassium derivative 31% of ing 14 pigment 20% of ing 14 volatile organic compounds (coating & material): 6.37 lb/gl. other prec: vap vol & vap/air cont time, & are influenced by ing 21: typical elevated-temp process cndtn, especially in processes ing 22: sudden air ingress/outside process equip operating under press if ing 23: occurs. any proposed use of this product in elevated-temperature ing 24: to assure that safe operating conditions are established and
ITW FLUID PRODUCTS GROUP -- STL BLACK DXX-553 1 QUARTZ, 33/CASE-81624
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BWZBL
MSDS NAME: STL BLACK DXX-553 1 QUARTZ, 33/CASE-81624
Responsible Party
Name: ITW FLUID PRODUCTS GROUP
Address: 8501 DELPORT DRIVE
City: ST. LOUIS MO 63114
Info Phone: 314-423-0100
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ITW DYKEM/ DYMON
Address: 805 E OLD 56 HWY
City: OLATHE KS 66061
Phone: 800-443-9536
Name: ITW FLUID PRODUCTS GROUP
Address: 8501 DELPORT DRIVE
City: ST LOUIS MO 63114
Phone: 800-443-9536
=======================================================
Ingredients
=======================================================
Cas: 123-86-4
RTECS #: AF7350000
Name: ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) VP: 10 @ 20C
% Wt: 31-50
OSHA PEL: 150 PPM
ACGIH TLV: 150 PPM/200STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Name: ALCOHOL; (CDA-19 ALCOHOL) (MIXTURE OF ING 3-5) VP: 40 @ 19C
% Wt: 11-30
OSHA PEL: 150 PPM
ACGIH TLV: 150 PPM/200STEL
-----------------------------
Cas: 64-17-5
RTECS #: KQ6300000
Name: ETHYL ALCOHOL; (ETHANOL) 95% OF ING 2
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM
------------------------------
Cas: 108-10-1
RTECS #: SA9275000
Name: 2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA) 4%
OF ING 2
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM/75 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 142-82-5
RTECS #: MI7700000
Name: HEPTANE; (N-HEPTANE) 1% OF ING 2
OSHA PEL: 500 PPM
ACGIH TLV: 400 PPM/500STEL
------------------------------
Cas: 71-36-3
RTECS #: EO1400000
Name: BUTYL ALCOHOL; (NORMAL BUTYL ALCOHOL) (1-BUTANOL) VP: 5.5 @ 20C
% Wt: 11-30
OSHA PEL: 500 PPM
ACGIH TLV: 400 PPM/500STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Name: ETHYLCELLULOSE; (BLACK ETHYL CELLULOSE DISPERSION) (MIX OF ING 8-18) VP:
43
% Wt: 11-30
OSHA PEL: 500 PPM
ACGIH TLV: 400 PPM/500STEL
-----------------------------
Cas: 64-17-5
RTECS #: KQ6300000
Name: ETHYL ALCOHOL; (ETHANOL) 15% OF ING 7
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE; (TOLUOL) 61% OF ING 7
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: PIGMENT 24% OF ING 7
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: CELLULOSE SOLVENT; (CELLULOSE NITRATE WET W/2-PROPANOL) (MIX ING 12-13)
VP: 33 @ 20C
% Wt: 0-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 9004-70-0
RTECS #: QW0970000
Name: NITROCELLULOSE 10% OF ING 11
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 67-63-0
RTECS #: NT8050000
Name: ISOPROPYL ALCOHOL (SARA 313) 30% OF ING 11
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM/500STEL
------------------------------
Name: CELLULOSE SOLVENT; (CELLULOSE NITRATE DISPERSION FLATTING AGENT) (MIXTURE
OF ING 15-19) VP: 76
% Wt: 0-10
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM/500STEL
-----------------------------
Cas: 64-17-5
RTECS #: KQ6300000
Name: ETHYL ALCOHOL; (ETHANOL) 2.7% OF ING 14
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM
------------------------------
Cas: 141-78-6
RTECS #: AH5425000
Name: ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (CERCLA) 23.1% OF ING 14
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE; (TOLUOL) 23.2% OF ING 14
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 865-47-4
Name: BUTYL ALCOHOL, TERT-, POTASSIUM DERIVATIVE 31% OF ING 14
OSHA PEL: N/K (FP N)
ACGIH TLV: 100 PPM
------------------------------
Name: PIGMENT 20% OF ING 14
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS (COATING & MATERIAL): 6.37 LB/GL.
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: OTHER PREC: VAP VOL & VAP/AIR CONT TIME, & ARE INFLUENCED BY
PRESS CHANGES. IGNIT OF ORG CHEM VAPS MAY OCCUR AT
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: ING 21: TYPICAL ELEVATED-TEMP PROCESS CNDTN, ESPECIALLY IN PROCESSES
OPERATING UNDER VACUUM & SUBJECTED TO
Other REC Limits: YN/KNONE RECOMMENDED
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: ING 22: SUDDEN AIR INGRESS/OUTSIDE PROCESS EQUIP OPERATING UNDER PRESS IF
SUDDEN ESCAPE OF VAP/MIST TO THE ATM
Other REC Limits: YN/KNONE RECOMMENDED
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: ING 23: OCCURS. ANY PROPOSED USE OF THIS PRODUCT IN ELEVATED-TEMPERATURE
PROCESSES SHOULD BE THORO EVALUATED
Other REC Limits: YN/KNONE RECOMMENDED
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: ING 24: TO ASSURE THAT SAFE OPERATING CONDITIONS ARE ESTABLISHED AND
MAINTAINED.
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES/SKIN: MOD IRRIT. INHAL: HIGH VAP CONC MAY
PRODUCE IRRIT OF RESP TRACT, HDCH, DIZZ & NAUS. INGEST: SIMILAR TO INHAL.
NAUS & VOMIT. CHRONIC: PLNGD/RPTD OVEREXPOS TO PROD MAY LEAD TO SKIN IRR
IT/DERM. NOTE: TOLUENE APPEARS ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS. SEEK (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: CONSULTATION FROM APPROPRIATE
HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE
HANDLING AND EXPOSURE INFORMATION (FP N).
Medical Cond Aggravated By Exposure: SKIN DISORDERS, RESPIRATORY DISORDERS.
First Aid: EYES: FLUSH WELL W/WATER FOR AT LEAST 15 MIN. CONT MD IF IRRIT
PERSISTS. SKIN: WASH W/SOAP & WATER. INHAL: REMOVE PATIENT TO FRESH AIR.
IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. INGEST: DO NOT IND UCE VOMIT.
CONT MD. IF VOMIT OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF
LIQUID INTO LUNGS.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: PREVENT SKIN & EYE CONT. USE NON-COMBUSTIBLE MATL
TO CONFINE &/ABSORB. ELIMINATE IGNITION SOURCES. VENTILATE AREA.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: REMOVE TO A WASTE DISPOSAL FACILITY OPERATING IN
COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: EMPTY CONTRS RETAIN RESIDUE (LIQUID
&/VAP) & CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND, OR EXPOSE SUCH (SUP DAT)
Other Precautions: WARNING! MANY HOT ORG CHEM VAP/MIST ARE SUSCEPTIBLE TO
SUDDEN SPONT COMBUST WHEN MIXED W/AIR. IGNIT MAY OCCUR AT TEMP BELOW THOSE
PUBLISHED IN LITERATURE AS "AUTOIGNIT"/"IGNIT" TEMPS. IGNIT TEMPS DECR EASE
W/INCREASING VAP VOLUME &
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: CC
Flash Point Text: 53.6F,12.0C
Lower Limits: 1.2
Upper Limits: 19
Extinguishing Media: USE CO*2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT(FP N).
Unusual Fire/Explosion Hazard: VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG GROUND, OR BE MOVED BY VENTILATION & BE IGNITED BY IGNITION SOURCE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN(FP N).
Ventilation: LOCAL EXHAUST IS RECOMMENDED FOR CONFINED AREAS. GENERAL
MECHANICAL VENT IS ADEQUATE FOR NORMAL USE.
Protective Gloves: CHEM RESIST RUB GLOVES SUCH AS (SUP DAT)
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N)
Other Protective Equipment: EYEBATH AND SAFETY SHOWER MEETING ANSI DESIGN
CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: HNDLG/STOR PREC: CONTRS TO HEAT, SPARKS,
FLAMES, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. USE W/ADEQUATE
VENT. PROT GLOVES: POLYVINYL CHLORIDE-COATED, & OTHER PROT GEAR IS
REQUIRED TO MINIMIZ E SKIN CONTACT.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >163F,>73C
Vapor Pres: SEE INGS
Vapor Density: >1
Spec Gravity: 0.87
Evaporation Rate & Reference: >1
Solubility in Water: APPRECIABLE
Appearance and Odor: BLACK OPAQUE LOW VISCOSITY LIQUID WITH SWEET SOLVENT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: OXIDES OF CARBON.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: STL BLACK DXX-553 1 QUARTZ, 33/CASE-81624
Company: ITW FLUID PRODUCTS GROUP
Street: 8501 DELPORT DRIVE
City: ST LOUIS MO
Zipcode: 63114
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 03/13/1995
Status Code: C
Label Date: 03/13/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE: EYES/SKIN: MOD IRRIT.
INHAL: HIGH VAP CONC MAY PRODUCE IRRIT OF RESP TRACT, HDCH, DIZZ & NAUS.
INGEST: SIMILAR TO INHAL. NAUS & VOMIT. CHRONIC: TOLUENE APPEARS ON THE
NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N). PLNGD/RPTD
OVEREXPOS TO PROD MAY LEAD TO SKIN IRRIT/DERM.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.