antimony (sara 313) (cercla) iron manganese (sara 313) aluminum (sara 313) tin nickel (sara 313) (cercla) phosphorous (yellow) (sara 302/313) (cercla) silicon sulfur (sara 302).(mfr's invalid cas#: 7404-39-9) tellurium (sara 302) lead (sara 313) (cercla) copper (sara 313) (cercla) zinc (sara 313) (cercla) supp data: information and safe handling and exposure information(fp n). explan of carcin: rpt on carcins, 1994: antic to be carcin. human: lungs,
HENRY VALVE INC -- BRASS/BRONZE
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BWYWJ
MSDS NAME: BRASS/BRONZE
Responsible Party
Name: HENRY VALVE CO INC
Address: 3215 N AVE
City: MELROSE PK IL 60160
Info Phone: 708-344-1100
Emergency Phone Number: 708-344-1100
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: HENRY VALVE CO INC
Address: 3215 N AVE
City: MELROSE PK IL 60160
Phone: 708-344-1100
Name: HENRY VALVE COMPANY
Address: 3215 NORTH AVE
City: MELROSE PARK IL 60160
Phone: 312-344-1100
=======================================================
Ingredients
=======================================================
Cas: 7440-36-0
RTECS #: CC4025000
Name: ANTIMONY (SARA 313) (CERCLA)
% Wt: 0-0.25
OSHA PEL: 0.5 MG/M3
ACGIH TLV: 0.5 MG (SB)/M3
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 7439-89-6
RTECS #: NO4565500
Name: IRON
% Wt: 0-6
OSHA PEL: 5 MG/M3 DUST, C
ACGIH TLV: 5 MG/M3 DUST
------------------------------
Cas: 7439-96-5
RTECS #: OO9275000
Name: MANGANESE (SARA 313)
% Wt: 0-5
OSHA PEL: 5 MG/M3 DUST, C
ACGIH TLV: 5 MG/M3 DUST
------------------------------
Cas: 7429-90-5
RTECS #: BD0330000
Name: ALUMINUM (SARA 313)
% Wt: 0-8
OSHA PEL: 15 MG/M3 DUST
ACGIH TLV: 10 MG/M3 DUST
------------------------------
Cas: 7440-31-5
RTECS #: XP7320000
Name: TIN
% Wt: 0-2
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
------------------------------
Cas: 7440-02-0
RTECS #: QR5950000
Name: NICKEL (SARA 313) (CERCLA)
% Wt: 0-12
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
-----------------------------
Cas: 7723-14-0
RTECS #: TH3500000
Name: PHOSPHOROUS (YELLOW) (SARA 302/313) (CERCLA)
% Wt: 0-0.5
OSHA PEL: 0.1 MG/M3
ACGIH TLV: 0.02 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 7440-21-3
RTECS #: VW0400000
Name: SILICON
% Wt: 0-4.5
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 7704-34-9
RTECS #: WS4250000
Name: SULFUR (SARA 302).(MFR'S INVALID CAS#: 7404-39-9)
% Wt: 0-0.5
OSHA PEL: 5 PPM
ACGIH TLV: 2 PPM/5 STEL
------------------------------
Cas: 13494-80-9
RTECS #: WY2625000
Name: TELLURIUM (SARA 302)
% Wt: 0-0.7
OSHA PEL: 0.1 MG/M3
ACGIH TLV: 0.1 MG/M3
------------------------------
Cas: 7439-92-1
RTECS #: OF7525000
Name: LEAD (SARA 313) (CERCLA)
% Wt: 0-4.6
OSHA PEL: SEE 1910.1025
ACGIH TLV: 0.15MG/M3 DUST
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER (SARA 313) (CERCLA)
% Wt: 45-99
OSHA PEL: 0.1MG/M3 FUME/1 DUST
ACGIH TLV: 0.2 MG/M3 FUME
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 7440-66-6
RTECS #: ZG8600000
Name: ZINC (SARA 313) (CERCLA)
% Wt: 0-43
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: SUPP DATA: INFORMATION AND SAFE HANDLING AND EXPOSURE INFORMATION(FP N).
-----------------------------
Name: EXPLAN OF CARCIN: RPT ON CARCINS, 1994: ANTIC TO BE CARCIN. HUMAN: LUNGS,
NASAL CAVITIES.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: DUST/FUME MAY CAUSE IRRIT TO EYES, NOSE/THROAT;
LEAVES METALLIC TASTE IN MOUTH; RSLT IN METAL FUME FEVER/PDCE FLU-LIKE SYMPS.
OVEREXP TO COPPER & LEAD MAY RSLT IN SKIN & HAIR DISCOLORATION. CHR
ONIC: ING 2: SIDEROSIS. ING 3: BRONCH, PNEUM, LACK OF COOR. ING 4:MAY
INITIATE FIBROTIC CHANGES TO LUNG(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NICKEL: IARC MONOGRAPHS ON EVAL OF CARCIN RISK
OR CHEMS TO MAN, VOL 49, PG 257, 1990: GROUP 2B. NTP 7TH ANNUAL
Signs And Symptions Of Overexposure: HLTH HAZ: TISS. ING 4:IRRIT OF SKIN/MUC
MEMBS & MAY RSLT IN BENIGN PNEUM(STANNOSIS). ING 6: INFLAMM OF RESP
TRACT, PNEUM. SKIN SENSITIZER. CERTAIN NICKEL CMPDS CAN CAUSE CANCER. ING 7:
NECROSIS OF MAN DIBLE. ING 9: EDEMA OF LUNGS. ING 10: GARLIC ODOR OF BREATH
& PERSPIRATION, METALLIC TASTE IN MOUTH, DRYNESS(SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF
RESP)(FP N). EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MINUTES. CALL MD(FP
N). SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD(F PN). ING EST: CALL MD
IMMEDIATELY(FP N).
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: THIS MATERIAL MAY BE RECLAIMED FOR REUSE, IN ACCORDANCE
WITH LOCAL, STATE & FEDERAL REGULATIONS.
Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER.
Other Precautions: VALVES ARE GENLY NOT CONSIDERED HAZ IN FORM SHIPPED.
HOWEVER, IF PROCESS INVOLVES GRINDING, WELDING, BRAZING/ANY OTHER PROCESS
THAT CAUSES RELEASE OF DUST/FUME, HAZ LEVELS OF DUST/FUME OF CONSTITUENTS OF
ALLOYS COULD BE GENERATED.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: USE METHODS APPLICABLE TO SURROUNDING AREA.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT(FP N).
Unusual Fire/Explosion Hazard: NEVER USE WATER AS AN EXTING AGENT AROUND MOLTEN
METAL, WATER WILL REACT VIOLENTLY WITH ANY MOLTEN METAL.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF OPERATIONS ARE SUCH THAT ATMOSPHERIC LEVELS OF
CONTAMS EXCEED PRESCRIBED LIMITS, PROVIDE MECH EXHAUST VENT &/NIOSH/MSHA
APPROVED RESPIRATOR.
Ventilation: MECHANICAL EXHAUST.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES(FP N).
Other Protective Equipment: USE PROT CLTHG AS REQD. A WELDING HOOD SHOULD BE
WORN WHERE WELDING. ANSI APPRVD EYE WASH & DELUGE SHOWER(FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EFTS OF OVEREXP:OF MOUTH, INHIBITION OF SWEAT
FUNCTION, & ANOREXIA, NAUS. ING 11:ANEMIA, URINARY DYSFUNCTION, METALLIC
TASTE IN MOUTH, WEAKNESS, CONSTIPATION, NAUS, DISORDER. LEAD APPEARS ON THE
NAVY LISTING OF OCCUP CHEMICAL REPRO HAZS. SEEK CONSULT FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZARD LIST
=======================================================
Physical/Chemical Properties
=======================================================
M.P/F.P Text: >1500F,>816
Spec Gravity: 7.5-9(H*2O=1)
Solubility in Water: INSOLUBLE
Appearance and Odor: YELOW SOLID AT ROOM TEMPERATURE AND EXHIBITS NO ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES.
Materials To Avoid: MAY BE INCOMPATIBLE WITH ACID, BASES & OXIDIZERS.
Hazardous Decomposition Products: MAY LIBERATE METAL OXIDES OR OTHER OXIDES IF
EXPOSED TO ELEVATED TEMPERATURES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: BRASS/BRONZE
Assigned IND: Y
Company: HENRY VALVE CO INC
Street: 3215 N AVE
City: MELROSE PK IL
Zipcode: 60160
Health Emergency Phone: 708-344-1100
Label Required IND: Y
Date Of Label Review: 03/07/1995
Status Code: C
Label Date: 03/07/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: DUST/FUME MAY CAUSE IRRIT TO EYES, NOSE/THROAT;
LEAVES METALLIC TASTE IN MOUTH; RSLT IN METAL FUME FEVER/PDCE FLU-LIKE SYMPS.
OVEREXP TO COPPER & LEAD MAY RSLT IN SKIN & HAIR DISCOLORATION. CHR
ONIC: CANCER HAZARD. CONTAINS NICKEL WHICH IS LISTED AS A HUMAN LUNG AND
NASAL CARCINOGEN(FP N). SIDEROSIS. BRONCH, PNEUM, LACK OF COOR. MAY INITIATE
FIBROTIC CHANGES TO LUNG TISSUE. ANEMIA, URINARY D YSFUNCTION, WEAKNESS,
NERVOUS DISORDER. LEAD APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS LIST(FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.