===================== Product Identification =====================
MSDS NAME:OXALIC ACID
NIIN:00-132-4020
MSDS Number: BJXFW
=== Responsible Party ===
Company:GENERAL CHEMICAL CORP
Address:90 E HALSEY RD
Box:395
City:PARSIPPANY
State:NJ
ZIP:07054
Country:US
Info Phone Num:800-631-8050, 201-455-5630
Emergency Phone Num:201-455-3700
CAGE:0AU44
=== Contractor Identification ===
Company:GENERAL CHEMICAL CORPORATION
Address:90 EAST HALSEY ROAD
Box:City:PARSIPPANY
State:NJ
ZIP:07054
Country:US
Phone:973-515-1840
CAGE:0AU44
============= Composition/Information on Ingredients =============
Name:OXALIC ACID
CAS:144-62-7
RTECS #:RO2450000
OSHA PEL:1 MG/M3/2 STEL
ACGIH TLV:1 MG/M3/2 STEL; 9192
Name:MATLS TO AVOID: MATLS, CHLORITES & HYPOCHLORITES. REACTS
W/WATER-REACTIVE MATLS, SUCH AS OLEUM-POSSIBLY W/VIOLENCE.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP:CHRONIC:RPTD INHAL EXPOS CAN CAUSE RENAL
DMG. FIRST AID PROC:IF A QUALIFIED OPERATOR IS PRESENT. (ING 4)
RTECS #:9999999ZZ
Name:INGEST:DO NOT INDUCE VOMIT.IF CONSCIOUS,GIVE IMMED BY MOUTH
A DILUTE SOLN OF CALCIUM LACTATE (USP GRADE),OR (ING 5)
RTECS #:9999999ZZ
Name:CALCIUM GLUCONATE (USP GRADE) OR MILK.FOR ALL ROUTES:GET
PROMPT MD ATTN.SPILL PROC:TO NEUTRALIZE ANY RESIDUE.THE (ING 6)
RTECS #:9999999ZZ
Name:RESULTNG NEUTRALIZED SOLN IS ALSO TOX & SHOULD BE HANDLED
ACCORDGLY.ATTEMPT TO KEEP SOLN OUT OF SEWER.ANY RELEASE(ING 7)
RTECS #:9999999ZZ
Name:TO THE ENVIRONMENT OF THIS MATERIAL MAY BE SUBJECT TO FED
AND/OR STATE REPORTING REQUIREMENTS. CHECK W/APPROP AGENCIES.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 375 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: INHAL OF DUSTS/MISTS CAN CAUSE
IRRIT OR CORR LOCAL BURNS TO MUC MEMB IN UPPER RESP SYSTEM, INCL
NOSE, MOUTH & THROAT. CAN ALSO IRRITATE LUNGS. INGEST: CAN CAUSE
IRRIT & CORR BURNS TO MOUTH, THR OAT AND STOMACH, IF SWALLOWED.
OXALIC ACID IS CONSIDERED A STRONG POISON WHEN TAKEN INTERNALLY.
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: A SYSTEMIC POISON, IT AFFECTS CNS &
KIDNEY FUNC AND OTHER ORGANS. AS LITTLE AS 5 GM HAVE PROVEN FATAL.
CAN CAUSE HYPOCALCEMIA. SKIN: DEPENDING UPON LENGTH OF CONT, CONT
CAN CAUSE IRRIT/CORR BURNS. DILUTE SOLNS (5-10%) CAN BE IRRIT ON
PRLNGD EXPOS. EYES: SEV IRRIT, CORNEAL BURNS & CONJ. (SEE INGRED 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: PROMPTLY FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN,
LIFTING LIDS OCCASIONALLY TO ASSIST IRRIGATION. SKIN: PROMPTLY WASH
W/SOAP & WATER, THEN FLUSH W/WATER FOR AT LEAST 15 MIN OR UNTIL ALL
CHEM IS REMOVED. REMOVE CONTAM CLTHG & WASHBEFORE REUSE. INHAL:
REMOVE PROMPTLY TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREF
MOUTH-TO- MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN (SEE INGRED 3)
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL TYPE FOAM, OR
CARBON DIOXIDE.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA TO PROT AGAINST FORMIC
ACID & CARBON MONOXIDE & OTHER TOXIC GASES WHICH MAY BE PRESENT.
(SEE SUPP DATA)
Unusual Fire/Explosion Hazard:BECOMES A COMB SOL <102C (215F). PARTIAL
DECOMP OCCURS AT 150C. DECOMP PROD, INCL CO & FORMIC ACID, ARE BOTH
TOX & FLAM. CAN REACT VIOLENTLY W/STRONG OXIDIZERS.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP SPILL IMMED W/A MINIMUM OF DUSTING
WHILE KEEPING AWAY FROM HEAT OR FLAME. COLLECT IN CNTNRS (E.G.,
FIBERBOARD) ; CLOSE AND LABEL "POISON" AND STORE. ALKALI SOLN MAY
BE USED, WITH THE USUAL PR ECAUTIONS FOR RELEASE OF CO2, (SEE
INGRED 5)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA OF LOW FIRE
RISK, AWAY FROM FOOD, FOOD CHEM & STRONG OXIDIZERS. KEEP CNTNR
CLOSED & PROT FROM PHYSICAL DMG.
Other Precautions:DO NOT GET IN EYES, ON SKIN OR CLTHG. DO NOT BREATHE
DUST. KEEP AWAY FROM HEAT & OPEN FLAME. DO NOT ALLOW SMOKING/EATING
WHILE HANDLING. USE GOOD PERSONAL HYGIENE & HOUSEKEEPING PRACTICES.
CUSTOMARY P ROT EQUIP IS REQ FOR PERSONNEL HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR DUST/MIST CONC >TLV BUT UNDER 50 MG/M3 IN
AIR: HIGH EFFICIENCY PARTICULATE FILTER, SUPPLIED AIR OR SCBA
(NIOSH/MSHA APPROVED). THE LATTER TWO ARE ALSO EFFECTIVE FOR FUME.
ALL THREE TYPES SHOULD HA VE FULL FACEPIECE.
Ventilation:LOC VENT: DUSTY/MISTY CNDTNS/IF PROD IS HEATED TO PRODUCE
FUMES. NATL VENT: GEN ADEQ IN ABSENCE OF DUST, MIST/FUMES.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM WORKERS GOGG, FACESHLD OPTL .
Other Protective Equipment:COMPLETE PROT IMPERV CLOTHNG.NEUTRALIZATION
SUPPLIES & EQUIP ALONG W/WASH UP FACILITIES.EYEWASH STATIONS,
DELUGE SHOWER.
Work Hygienic Practices:WASH HAND FREQUENTLY AND THOROUGHLY DURING
CONTACT WITH MATERIAL AND AT END OF WORKDAY .
Supplemental Safety and Health
FIRE FIGHT PROC: IF APPARATUS HAS NO FACEPIECE, WEAR CHEM SAFETY
GOGGLES. WATER SPRAY MAY BE USED TO COOL/SOAK CNTNRS (IF OF
WATERPROOF CONSTRUCTION) AND TO KNOCK DOWN FUMES & PROT
FIREFIGHTING PERS. IF MATL IS IN MOLTEN STATE, WATER STREAM OR
FOAM MAY CAUSE FROTHING.
================== Physical/Chemical Properties ==================
HCC:C1
Melt/Freeze Pt:M.P/F.P Text:215F,102C
Vapor Pres:0.0003@30C
Spec Gravity:1.653
pH:1.3
Solubility in Water:APPROX 11.7% @ 20C
Appearance and Odor:COLORLESS CRYSTALS; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIES & SILVER CMPDS. INCOMP W/SILVER (FORMING EXPLOS SILVER
OXALATE). REACT W/STRONG OXIDIZING (SEE INGRED 2)
Stability Condition to Avoid:TEMPS 100C & ABOVE, MATL BEGINS TO SUBLIME
W/DECOMP, YIELDING TOX, FLAM & CORR GASES. EVOL BECOMES SIGNIFICANT
@ 150C.
Hazardous Decomposition Products:THERMAL DECOMP YIELDS AT LEAST FORMIC
ACID, CARBON MONOXIDE. COMBUSTION PROBABLY YIELDS THESE AND ALSO
CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE WASTE ACID IN A FLAM SOLVENT & BURN IN
APPRVD INCINERATOR W/AFTER BURNER. ALTERNATIVES INCL BURIAL IN CHEM
WASTES LANDFILL/DISSOLVING IN WATER & NEUTRALIZING W/ALKALI.
DISPOSE I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|
|
| ALL PAGES On Chemical Property IN THIS GROUP
| | NAME | CAS |
|
DOW CORNING (R) S-2260 PRIME COAT
| 8030-30-6
2768-02-7
682-01-9
5593-70-4
2157-45-1 |
|
PRO-SEAL 870, CLASS A, BASE
| 108-88-3
9003-35-4 |
|
PROSEAL 870 ALL CLASS & TYPES, ACCELERATOR
| 13423-61-5
102-06-7
1313-13-9 |
|
EASY FLO 3;AWS SPEC.AS 8,3AG-3
| 7440-22-4
7440-50-8
7440-66-6
7440-43-9
7440-02-0 |
|
ACTIVATOR BA-5
| 68187-11-1
112945-52-5 |
|
REMOVER FLOOR POLISH
| 6834-92-0 |
|
ETHYL ACETATE
| 141-78-6 |
|
MOLYLUBE 1200
| |
|
L-TEC TUNGSTEN ELECTRODES
| 7440-33-7
1314-20-1
7440-67-7 |
|
AMMONIA INHALANT SOLUTION,NDC 00839-0076-99,U 1-24
| 7664-41-7
64-17-5 |
|
AK-024 CARPET CLEANER
| |
|
SCOTCHGARD(TM) BRAND PROTECTOR FOR FABRICS
| 71-55-6
124-38-9
109-87-5
75-65-0
78-92-2 |
|
DOW CORNING(R)3145RTV ADHES SEALANT-CLEAR
| 68909-20-6
1185-55-3
13463-67-7 |
|
PETROLEUM BASED RUST PREVENTATIVE
| 124-38-9
8052-41-3
64742-53-6 |
|
OXALIC ACID
| 144-62-7 |
|
GSA TYPE I SWEEPING COMPOUND
| 8002-05-9
9004-34-6
112945-52-5 |
|
AA1550 WAX, LIQUID
| 8052-41-3 |
|
S-8 SOLVENT
| 108-88-3
108-65-6 |
|
SCOTCH-WELD(R)EPOXY ADHESIVE 2214 REGULAR
| 7429-90-5
63231-67-4
150-68-5
598-94-7 |
|
GLYPTAL AIR DRY ENAMEL 1201
| 1330-20-7
8030-30-6
64741-41-9 |
|
WAX, FLOOR, WATER-EMULSION TYPE
| 7732-18-5
68441-17-8
8002-26-4
90-43-7
128-37-0
100-37-8
78-51-3
1336-21-6 |
|
PRIMER COATING 724222 EPOXY POLYAMIDE
| 108-88-3
78-83-1
107-98-2
7789-06-2
13463-67-7
14807-96-6
14808-60-7
63231-67-4 |
|
SODIUM SULFITE, CRYSTAL 3888, 3922
| 7757-83-7 |
|
SCOTCH-WELD2216B/A PT A GRAY EPOXY ADHESIVE
| 1332-58-7
1333-86-4 |
|
SCOTCH-WELD(TM)2216 B/A PT B GRAY EPOXY ADH
| 25068-38-6
1318-74-7 |
|
PLASTIC PLASTISOL
| |
|
ADHESIVE-SCOTCH-WELD (R) 2216 A GRAY
| 1302-76-7
1333-86-4 |
|
ADHESIVE-SCOTCH-WELD (R) 2216 B GRAY
| 80-05-7
1302-76-7 |
|
RTV159, SILICONE SEALANT
| 4253-34-3 |
|
ECCOBOND 45 CLEAR
| |
|
CATALYST 15 CLEAR
| 112-24-3 |
|
PR-1431-G AND GT, PART A
| 13423-61-5
14307-33-6 |
|
PR-1431-G, TYPE I, PART B
| 9003-35-4
25068-38-6
108-88-3
13423-61-5 |
|
RTVS 51 WHITE, RS-0051-610000-A
| |
|
CAT 2, RC-0002-660000-B
| |
|
2-TON CLEAR EPOXY HARDENER
| 140-31-8
25154-52-3 |
|
2-TON CLEAR EPOXY RESIN
| 25068-38-6 |
|
12
| 7439-89-6
7439-96-5
13463-67-7
1312-76-1
1344-09-8 |
|
TT-V-71H, FLOOR AND TRIM VARNISH
| 64742-88-7 |
|
THERMOMETER,MERCURY
| 7439-97-6 |
|
AMYL ACETATE PRIMARY
| 628-63-7 |
|
CLEANING COMPOUND, SOLVENT DETERGENT
| 111-76-2
106-89-8 |
|
CLEANING COMPOUND SOLVENT DETERGENT
| 1310-58-3
111-76-2
6834-92-0
68412-54-4 |
|
CLEANER-DEGREASER DG1
| 67-56-1
9016-45-9
1303-96-4
533-96-0
25155-30-0
7732-18-5 |
|
SCOTCH-WELD(TM)1838-A EPOXY ADHESIVE(GREEN)
| 68410-23-1
1318-74-7
112-24-3
112945-52-5 |
|
SCOTCH-WELD 1838-B EPOXY ADHESIVE (GREEN)
| 25068-38-6
1332-58-7
68953-58-2
1317-65-3
13463-67-7 |
|
SCOTCH-WELD (R) EPOXY ADHESIVE 2214 REGULAR
| 7429-90-5
63231-67-4
150-68-5
598-94-7 |
|
GLYPTAL-G7526F
| 8030-30-6
110-80-5
1330-20-7
64741-41-9
138-86-3 |
|
THERMOFIT S-1009 ADHESIVE
| 25068-38-6
112945-52-5
68410-23-1
140-31-8 |
|
TT-E-529F, BROWN 20117,X9358
| 108-88-3
67-64-1
1330-20-7
74-98-6
75-28-5
106-97-8 |
|
|