===================== Product Identification =====================
MSDS NAME:CONATHANE EN-1554 PART A
NIIN:00-862-5159
Kit Part:Y
MSDS Number: BJZFF
=== Responsible Party ===
Company:CONAP INC.
Address:1405 BUFFALO ST.
City:OLEAN
State:NY
ZIP:14760
Country:US
Info Phone Num:716-372-9650
Emergency Phone Num:716-372-9650
Preparer's Name:GEORGE C. KARPIN
CAGE:16245
=== Contractor Identification ===
Company:CONAP INC.,WHOLLY OWNED SUBSIDIARY OF CYTEC INDUSTRIES
INC.
Address:1405 BUFFALO STREET
Box:City:OLEAN
State:NY
ZIP:14760
Country:US
Phone:716-372-9650
CAGE:16245
============= Composition/Information on Ingredients =============
Name:TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)
CAS:584-84-9
RTECS #:CZ6300000
Fraction by Wt: 8%
Other REC Limits:NONE SPECIFIED
OSHA PEL:C,0.02 PPM/0.02 STEL
ACGIH TLV:0.005PPM/0.02STEL;93
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LC50 16-50PPM (RAT)/LD50>5800MG/KG(RATS)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:IRRIT MUCOUS MEMBRANE IN RSPRTRY TRACT
CAUSE RUNNY NOSE,SORE THROAT,COUGH,CHEST DISCOM,SHORT OF
BREATH/REDUCE LUNG FUNCTION,BRONCHITIS.BRONCHIAL SPASM/PULMONARY
EDEMA.CHEM/HYPERSENSITIVE PNEUMONITIS,W /FLU-LIKE SYMPTOMS.SYMPTOMS
DELAYED.IRRIT/CORRO ACT IN MOUTH, STOMACH TISSUE/DIGESTIVE
TRACT.ISOCYANATE CAUSE LUNG DAMAG
Explanation of Carcinogenicity:TDI CAUSED AN INCREASE IN THE NUMBER OF
TUMORS IN EXPOSED RATS OVER THOSE COUNTED IN NON-EXPOSED RATS.
Effects of Overexposure:INHALED:RUNNY NOSE,SORE THROAT,WHEEZING,
COUGH,CHEST DISCOMFORT,SHORTNESS OF BREATH/REDUCE LUNG FUNCTION,
HYPERSENSITIVITY PNEUMONITIS,W/FLU-LIKE SYMPTOMS.EYES:IRRIT,TEARS,
CONJUNCTIVITIS/CORNEAL INJU
RY.SKIN:DISCOLORATION,RED,SWELLING/BLISTERING, SKIN
SENSITIZATION.INGESTION:SORE THROAT,ABDOM PAIN,NAUSEA,VOMITING/
DIAR
Medical Cond Aggravated by Exposure:ASTHMA, OTHER RESPIRATORY DISORDERS
(BRONCHITIS, EMPHYSEMA, BRONCHIAL HYPERRACTIVITY), SKIN ALLERGIES,
ECZEMA.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/H20 FOR 15 MIN,OCCAS LIFT EYELIDS.GET MED
ATTN.SKIN:REMOVE CONTAM CLOTHES.WASH AREA W/SOAP OR TINCTURE OF
GREEN SOAP/H20.WASH CLOTHES BEFORE REUSE.SEVERE EXPO:SAFETY
SHOWER,REMOVE CLOTHES UNDER SHOWER.GET MED ATTN.INHALED:MOVE TO
FRESH AIR. GIVE OXYGEN/CPR AS NEEDED.GET MED ATTN.ASTHMATIC-TYPE
SYMPS MAY BE IMMED/ DELAYED.GET MED ATTN.INGESTED:DO NOT INDUCE
VOMIT.GIVE 12FL OZ OF MILK/H2
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>260F/127C
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMCIAL, CARBON DIOXIDE
Fire Fighting Procedures:FULL EMERGENCY EQUIPMENT WITH SCBA. NO SKIN
SURFACE SHOULD BE EXPOSED. USE COLD WATER TO COOL FIRE-EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:TDI VAPORS/OTHER IRRIT,HIGHLY TOXIC GASES
MAY BE GENER BY THERMAL DECOMP/COMBUSTION.AT TEMPS >THAN 350F TDI
FORMS CARBODIIMIDES W/THE RELEASE OF CO2.EXPLOSIVE.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER SPILL W/SAWDUST,VERMICULITE/OTHER ABSORB
MAT'L.POUR DECOMTAM SOL OVER SPILL/ALLOW TO REACT 10 MIN.COLLECT
MAT'L IN OPEN TOP CONTAINERS/ADD MORE DECONTAM.MOVE TO SAFE
PLACE,COVER LOOSE/ALLOW TO S TAND FOR 24/48HRS.WASH DOWN SPILL AREA
W/DECONTAM.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS TO
PREVENT MOISTURE CONTAMINATION. DO NOT RESEAL IF CONTAMINATION IS
SUSPECTED.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. DO NOT BREATHE THE
VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A POS PRESS AIR-SUPPLIED RESPIRATOR REQUIRED
WHENEVER TDI CONC EXCEED THE SHORT-TERM EXPO/CEILING LIMIT
OF.02PPM/8HR TIME/AVERAGE TLV OF 0.005PPM.NON-SPRAY,NEAR TLV:FULL
FACE,AIR PURIFYING RESPIRATOR EQUIPPED W/ORGANIC
CARTRIDGES/CANISTERS.
Ventilation:LOCAL EXHAUST SHOULD BE USED TO MAINTAIN LEVELS BELOW THE
TLV WHENEVER TDI CONTAINING MAT'L IS HANDLED,PROCESSED,SPRAYED
Protective Gloves:CHEM RESIS GLOVES(BUTYL RUBBER,NITRILE)
Eye Protection:LIQUID CHEM GOGGLES OR FULL FACE SHIELD
Other Protective Equipment:SAFETY SHOWERS & EYE WASH STATIONS SHOULD BE
AVAILABLE.COVER AS MUCH EXPOSED SKIN AS POSSIBLE WITH APPROPRIATE
CLOTHING.
Work Hygienic Practices:EDUCATE AND TRAIN EMPLOYEES IN SAFE USE OF
PRODUCT. FOLLOW ALL LABEL INSTRUCTIONS.
Supplemental Safety and Health
KEY1:T6. CONTACT LENSES SHOULD NOT BE WORN.
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:1.06
Solubility in Water:REACTS
Appearance and Odor:LIQUID;FOR TDI SHARP PUNGENT(ODOR THRESHOLD GREATER
THAN TLV).
Percent Volatiles by Volume:NEGLIG
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, SHORT CHAIN ALCOHOLS, AMINES.
Stability Condition to Avoid:TEMPERATURES HIGHER THAN RECOMMENDED IN
PRODUCT LITERATURE.
Hazardous Decomposition Products:BY FIRE AND HEAT: CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN AND TRACES OF HYDROGEN CYANIDE,
TDI.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE ACCORDING TO ANY LOCAL, STATE AND
FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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