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MSDS  : ZIRCONIUM (IV) CHLORIDE, 99.5+%, 22188-0
CAS  : 10026-11-6
NAME  : zirconium tetrachloride (sara iii)
supp data: adjust ph from 10.0 to 6.0, stopping when
===================== Product Identification =====================

MSDS NAME:ZIRCONIUM (IV) CHLORIDE, 99.5+%, 22188-0
NIIN:00N014951
MSDS Number: BKMQP
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO INC./SUB OF SIGMA-ALDRICH CORP
Address:1001 W. ST. PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Country:US
Info Phone Num:414-273-3850/FAX -4979
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928

============= Composition/Information on Ingredients =============

Name:ZIRCONIUM TETRACHLORIDE (SARA III)
CAS:10026-11-6
RTECS #:ZH7175000
Fraction by Wt: 99.5%+
OSHA PEL:5 MG ZR/M3;STEL 10
ACGIH TLV:5 MG ZR/M3; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Name:SUPP DATA: ADJUST PH FROM 10.0 TO 6.0, STOPPING WHEN
PRECIPITATION OCCURS. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.
RTECS #:9999999ZZ

===================== Hazards Identification =====================

LD50 LC50 Mixture:SEE SUPP DATA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO
TISSUE OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES
AND SKIN. INHALATION MAY BE FATAL AS A RESULT OF SPASM,
INFLAMMATION AND EDEMA OF THE LARYNX AND BRONCHI, CHEMICAL
PNEUMONITIS AND PULMONARY EDEMA.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING. MAY CAUSE ALLERGIC REACTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

======================= First Aid Measures =======================

First Aid:IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLOTHING AND SHOES.
ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING EYELIDS WITH
FINGERS. IF INHAL ED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
ARTF RESP. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. WASH
CONTAM CLOTHING BEFORE REUSE. DISCARD CONTAM SHOES. INGEST: CALL MD
IMMEDIATELY .

===================== Fire Fighting Measures =====================

Flash Point:NONE
Extinguishing Media:NONCOMBUSTIBLE. DO NOT USE WATER. WATER HYDROLYZES
MATL LIBERATING ACIDIC GAS WHICH IN CNTCT WITH METAL (SEE SUPP
DATA)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

================== Accidental Release Measures ==================

Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS
AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR
WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL
SITE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

====================== Handling and Storage ======================

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. MOISTURE
SENSITIVE. PACKAGED UNDER ARGON. STORE IN A COOL, DRY PLACE.
Other Precautions:DO NOT BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON
CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. CORROSIVE. TOXIC.
POSSIBLE SENSITIZER. INCOMPATIBLE WITH ESTERS AND KETONES.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXTING MEDIA: SURFACES CAN GENERATE FLAMMABLE AND/OR EXPLOSIVE HYDROGEN
GAS. LD50-LC50 MIX: LD50: (ORL, RAT)=1688 MG/KG, (ORL, MUS)=489
MG/KG. WASTE DISP METH: AMMONIUM HYDROXIDE TO A PH OF 10.0. FILT ER
OFF ANY PRECIPITATION FOR DISPOSAL IN A CHEMICAL LANDFILL. IF NO
PRECIPITATION OCCURS, GRADUALLY (SEE INGRED 02)

================== Physical/Chemical Properties ==================

HCC:C1
Spec Gravity:2.803
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

================= Stability and Reactivity Data =================

AMINES, ALCOHOLS, ACIDS.
Stability Condition to Avoid:MAY DECOMPOSE ON EXPOSURE TO MOIST AIR OR
WATER.
Hazardous Decomposition Products:HCL GAS.

==================== Disposal Considerations ====================

Waste Disposal Methods:CAUTIOUSLY MAKE A 5% SOLN OF MATL IN WATER OR
DILUTE ACID. THERE MAY BE A VIGOROUS, EXOTHERMIC RXN & FUMES MAY BE
GENERATED DUE TO THE HYDROLYSIS OF MATL. CONTROL ANY RXN BY COOLING
& BY THE RATE OF A DDN OF MATL. GRADUALLY ADD DILUTE (SEE SUPP
DATA)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

*** END OF RECORD ***
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NICKLE BASED ALLOY STEEL 7440-65-5
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TETRABUTYLAMMONIUM HYDROXIDE, 40 WT % (SEE 2052-49-5
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CAUSTIC, CAUSTIC SODA, LYE 1310-73-2
FLAKE BEAD & SOLID CAUSTIC SODA 1310-73-2
CAST-RITE #70 64743-05-1
RED COPP 97N 7440-50-8
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TINCTURE OF BENZOIN 64-17-5
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